The invention belongs to the technical field of
environmental engineering materials and particularly relates to a structured iron-carbon micro-
electrolysis filling material and a preparation method thereof. The preparation method comprises the steps of treating fine
iron powder and
bituminous coal powder as raw materials, treating
paper mill sludge which is dried and pulverized as a pore-forming agent, treating
copper powder as a catalyst, adding a binding agent, mixing the ingredients uniformly, conducting compression formation,
drying the ingredients, obtaining a dry-
bulb filling material, generating
anode metal iron by conducting direct reduction on the fine
iron powder in the dry-
bulb filling material through high temperature
roasting, and obtaining the iron-carbon micro-
electrolysis filling material. The
granularity of the
anode metal iron of the iron-carbon micro-
electrolysis filling material is less than 10 micrometers. The structured iron-carbon micro-electrolysis filling material has the advantages that iron and carbon are integrated, the filling material is of a micropore framework type
alloy structure, the
porosity is high, the activity is high, the
current density is large, when the filling material is applied to
industrial waste water treatment, COD and
chromaticity of waste water can be effectively lowered, biodegradability of the waste water can be effectively improved, various heavy
metal ions can be removed, and the filling material is stable in operation and application effect.