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57 results about "Thenoyltrifluoroacetone" patented technology

Thenoyltrifluoroacetone, C₈H₅F₃O₂S, is a chemical compound used pharmacologically as a chelating agent. It is an inhibitor of cellular respiration by blocking the respiratory chain at complex II. Perhaps the first report of TTFA as an inhibitor of respiration was by A. L. Tappel in 1960. Tappel had the (erroneous) idea that inhibitors like antimycin and alkyl hydroxyquinoline-N-oxide might work by chelating iron in the hydrophobic milieu of respiratory membrane proteins, so he tested a series of hydrophobic chelating agents. TTFA was a potent inhibitor, but not because of its chelating ability. TTFA binds at the quinone reduction site in Complex II, preventing ubiquinone from binding. The first x-ray structure of Complex II showing how TTFA binds, 1ZP0, was published in 2005 .

Amino porphyrin- poly (N-isopropylacrylamide) europium coordination compound and preparation method thereof

The invention discloses amino porphyrin-poly (N-isopropylacrylamide) europium coordination compound and a preparation method of the amino porphyrin-poly (N-isopropylacrylamide) europium coordination compound. The preparation method of the amino porphyrin- poly (N-isopropylacrylamide) europium coordination compound is characterized in that (NH2)n-TPP is prepared into an ATRP initiator which is NH2-TPP-X, wherein the X is halogen. The NH2-TPP-X is adopted to initiate NIPAM to be polymerized to obtain polymer which is (NH2)n-TPP-PNIPAM. The europium with tervalence is coordinated with the polymer (NH2)n-TPP-PNIPAM to obtain coordination compound which is (NH2)n-TPP-PNIPAM-Eu(III)-TTA through the TTA, wherein the n meets an equation that is n=1,2,3. The amino porphyrin- poly (N-isopropylacrylamide) europium coordination compound is characterized in that a short form of the amino porphyrin- poly (N-isopropylacrylamide) europium coordination compound is (NH2)n-TPP-PNIPAM-Eu(III)-TTA, wherein the TPP is tetraphenylporphyrin, wherein the shortened form of the tetraphenylporphyrin is porphyrin, the PNIPAM is the poly (N-isopropylacrylamide), the Eu(III) is the europium with the tervalence, and the TTA is alpha- thenoyltrifluoroacetone.
Owner:CHANGCHUN UNIV OF SCI & TECH

Dinuclear europium complex luminescent material and preparation and application of dinuclear europium complex luminescent material

The invention relates to a dinuclear europium complex luminescent material and a preparation and application of the dinuclear europium complex luminescent material. The structural general formula of the dinuclear europium complex luminescent material is Eu2L16L22(CH3OH)2, wherein L1 is a p-aminobenzoic acid benzoyl thioureas derivatives; and L2 is one of 1,10-phenanthroline, 2,2-dipyridyl or 2-thenoyltrifluoroacetone. The dinuclear europium complex is a luminescent material with good thermal stability and high luminous efficiency; the molecular structure of the dinuclear europium complex is regular, and after a second auxiliary ligand is added in the dinuclear europium complex luminescent material, the fluorescence intensity and the quantum yield of the dinuclear europium complex luminescent material are improved quite obviously. The preparation method has the advantages of simplicity and convenience in process, simple used equipment, simple and easily obtained raw materials and low production cost.
Owner:NANCHANG UNIV

Dual-response magnetic nano particle with fluorescence and preparation method thereof

The invention discloses a dual-response magnetic nano particle with fluorescence and a preparation method thereof, belonging to the technical field of functional polymer materials. An existing response magnetic nano particle is smaller in response range and is incapable of tracing mark. A chemical expression formula of the magnetic nano particle is Fe3O4@M(III)-(PNIPAMm-b-PAzoMAn)-TTA (PNIPAM (Poly(N-isopropylacrylamide) and TTA (thenoyltrifluoroacetone), wherein M is Eu<3+>, Tb<3+>, Sm<3+> or Er<3+>, m is equal to 42-132, and n is equal to 5-20. AzoMA and NIPAM (N-isopropylacrylamide) are polymerized to an RAFT (Reversible Addition-Fragmentation chain Transfer) chain transfer agent through an RAFT free radical polymerization method, and M(III)-(PNIPAMm-b-PAzoMAn)-TTA is obtained through a coordination reaction, and then is modified to the surface of a ferriferrous oxide nano particle through an esterification reaction. The dual-response magnetic nano particle is capable of carrying out magnetic separation under the control of the temperature and the light, and has a potential application value in the aspects of biological marking, imaging, artificial muscle and the like.
Owner:CHANGCHUN UNIV OF SCI & TECH

Organic rare earth europium light-emitting dacron and preparation method thereof

The invention discloses an organic rare earth europium light-emitting dacron and a preparation method thereof. The preparation method comprises the following steps: firstly preparing an o-phenanthroline neutral ligand which is combined with alpha-thenoyltrifluoroacetone and rare earth Eu (III) for coordination and preparing a rare earth europium coordination compound Eu(TTA)3DMPaPhen light-emitting material having a close nanoscale by virtue of an atmospheric titration and high-pressure reaction method. The material emits very strong pure red light in a 10<-5>mol / L CH2Cl2 solution at 615nm. A light-emitting fiber is prepared from the coordination compound as a light-emitting material and polyethylene terephthalate (PET) through composite melt spinning. When the content of the rare earth light-emitting material in the fiber is 0.05%, the rare earth light-emitting material emits very strong pure red light in a 10<-5>mol / L CH2Cl2 solution at a light-emitting position of 615nm. The light-emitting fiber has the advantages of high color purity and good spinnability.
Owner:湖州信倍连网络科技有限公司

Tetraheteropoly rare earth organic complex and preparation thereof

The invention relates to quaternionic rare earth organic complexes as shown in general formula (I). The chemical name of the organic complexes is Eu-Tb thenoyltrifluoroacetone-N-phenylanthranilic acid-o-phenanthroline organic complexes. The chemical formula of the organic complexes is Tb1-xEux (TTA) 2 (N-HPA) Phen, wherein x is equal to 0-1. The invention also relates to a method for making the quaternionic rare earth organic complexes.
Owner:BEIJING UNIV OF CHEM TECH +1

Organic rare earth europium luminescent polypropylene (PP) fiber and preparation method thereof

The invention discloses an organic rare earth europium luminescent polypropylene (PP) fiber and a preparation method thereof. The rare earth europium complex Eu(TTA)3DmPPhen luminescent material close to nanoscale is prepared by firstly preparing a phenanthroline neutral ligand and carrying out coordination on the phenanthroline neutral ligand and rare earth Eu (III) in combination with alpha-thenoyltrifluoroacetone and adopting a method of firstly carrying out titration under atmospheric pressure and secondly carrying out reaction under high pressure. The material emits strong pure red light at 615nm in a 10-5mol / L CH2Cl2 solution. The luminescent fiber is prepared by adopting the complex as a luminescent material and carrying out compound melt spinning on the complex and PP. When the content of the rare earth luminescent material in the fiber is 0.05%, the fiber emits stronger pure red light in a 10-5mol / L dimethyl formamide (DMF) solution and the luminescent position is still at 615nm. The luminescent fiber has the advantages of high color purity and better spinnability.
Owner:济南市佳新纤维有限公司

Preparation method of high-color-rendering white phosphor for 3D (three-dimensional) printing

The invention relates to a preparation method of high-color-rendering white phosphor for 3D (three-dimensional) printing, and aims to solve the problems of high color temperature, low color rendering index and poor film forming performance of the white phosphor. The method includes the steps: taking 2-thenoyltrifluoroacetone-phenanthroline-europium, 4-benzoyl benzoic acid-terbium, benzothiazole-zinc and polystyrene-methacrylic acid glycidyl ester as raw materials; performing physical blending, heating and melting, drying, grinding and screening on the raw materials to prepare the high-color-rendering white phosphor, the particle diameter of the white phosphor is smaller than or equal to 1 micrometer, the prepared white phosphor materials are high in accuracy and good in purity, the purity of the white phosphor materials reach 99.8%, color coordinates X=0.332, Y=0.337, white light is emitted, the preparation method is advanced in process, data are detailed and accurate, and the advanced preparation method is used for the high-color-rendering white phosphor for 3D printing.
Owner:TAIYUAN UNIV OF TECH

Organic rare earth europium luminescent nylon and preparation method thereof

The invention discloses organic rare earth europium luminescent nylon and a preparation method thereof. The rare earth europium complex Eu(TTA)3DmPPhen luminescent material close to nanoscale is prepared by firstly preparing a phenanthroline neutral ligand and carrying out coordination on the phenanthroline neutral ligand and rare earth Eu (III) in combination with alpha-thenoyltrifluoroacetone and adopting a method of firstly carrying out titration under atmospheric pressure and secondly carrying out reaction under high pressure. The material emits strong pure red light at 615nm in a 10-5mol / L CH2Cl2 solution. The luminescent fiber is prepared by adopting the complex as a luminescent material and carrying out compound melt spinning on the complex and PA6 (polyamide 6). When the content of the rare earth luminescent material in the fiber is 0.08%, the fiber emits stronger pure red light in a 10-5mol / L DMF (dimethyl formamide) solution and the luminescent position is still at 615nm. The luminescent fiber has the advantages of high colour purity and better spinnability.
Owner:湖州信倍连网络科技有限公司

Method for preparing conductive polymer-rare-earth complex composite electric catalyst

The invention provides a method for preparing a conductive polymer-rare-earth complex composite electric catalyst. The method comprises the following steps: firstly, by taking 2-thenoyltrifluoroacetone and a phenanthroline rare-earth metal salt as raw materials, preparing a rare-earth complex according to a precipitation method; by taking ferric trichloride and ammonium persulfate as oxidants, preparing a conductive polymer wrapped rare-earth complex according to a chemical oxidation polymerization method, centrifuging a polymerization product, washing, drying, and carbonizing at a high temperature in the presence of a nitrogen atmosphere, thereby obtaining the conductive polymer-rare-earth complex composite electric catalyst. Due to a large active surface and high conductivity, the catalyst can be applied to fuel battery oxidation reduction, oxygen separation and hydrogen separation reactions, has the characteristics of being high in catalytic activity, good in anti-toxicity property,good in stability, and the like, and is an ideal catalyst for fuel batteries.
Owner:NORTHWEST NORMAL UNIVERSITY

Preparation method of fluorescence-enhanced rear-earth metal oxide nanosheet sol with positive charges

The invention discloses a preparation method of fluorescence-enhanced rear-earth metal oxide nanosheet sol with positive charges. The method takes yttrium oxide, europium oxide, terbium oxide, ammonium bromide, sodium benzoate, HTTA (thenoyltrifluoroacetone) and the like as materials. The preparation method comprises the steps of firstly, roasting at a high temperature to obtain Y1.93Ln0.1O3 and Y0.95Ln0.05OBr layered materials; under microwave heating condition, intercalating for the layered materials by utilizing sodium benzoate liquor to obtain intercalated materials; and finally, carrying out ultrasonic treatment onto the intercalated materials and the HTTA in a n-butyl alcohol solvent to obtain the fluorescence-enhanced rear-earth metal oxide nanosheet sol with positive charges. The preparation method disclosed by the invention is simple in preparation process and environmental friendly.
Owner:EAST CHINA NORMAL UNIV

Raveearth multi-element compounding material light conversion agent with ecological and phycological characteristics and preparation process thereof

The present invention relates to a rare earth multi-component coordination compound light-converting agent with ecological and physiological characteristics, its mole ratio is as follows: rare earth 1, organic ligand 0-6, organosilicon surfactant (A) 0-6, and solvent 3-10, in which the rare earth ion is Eu(3+), which is provided by nitrate and hydrochloride of trivalent europium, and the chemicalstructure formula for its organosilicon surfactant is (RO)3SiR1N+R2R3R4X-. Its organic ligand is alpha-thenoyltrifluoroacetone (TTA), triphenyloxyphosphine (TPPO) or its two-component coordination compound. Its applicable liquid solvent is methylbenzene, dimethyl benzene, methyl alcohol, cyclohexane, ethyl alcohol, isopropanol, methyl-sulfoxide or their mixture, and its solid solvent is silicone.
Owner:NANJING NORMAL UNIVERSITY

Medicine carrier based on nano diamond, medicinal complex as well as preparation method and application thereof

The invention discloses a medicine carrier based on a nano diamond. The medicine carrier is a nano diamond medicine carrier with doped rare earth elements, namely europium and gadolinium. A preparation method of the medicine carrier comprises the following steps: performing silanization chemical modification on the surface of a nano diamond so as to obtain a surface silanizated nano diamond, namely ND-APTES (Nano Diamond-Aminopropyl Triethoxysilane); performing silanization modification on alpha-thenoyl trifluoroacetone so as to obtain silanizated alpha-thenoyl trifluoroacetone, namely TTA-Si;enabling the surface silanizated nano diamond and silanizated organic ligand to react with Eu<3+> and Gd<+3> in a solvent, thereby obtaining the medicine carrier ND-TTA:RE<+3> based on the nano diamond. The medicine carrier based on the nano diamond, which is disclosed by the invention, is capable of not only carrying doxorubicin hydrochloride, but also carrying other medicines, and is applicableto different diseases, and transmission of different medicines can be achieved.
Owner:ZHENGZHOU UNIV

Biodegradable light conversion film and preparation method thereof

The invention provides a biodegradable light conversion film which is prepared from the following components in parts by weight: 60-64.7 parts of poly (butyleneadipate-co-terephthalate), 35 parts of polylactic acid, 0.1-2 parts of a lubricant, 0.1-2 parts of an opening agent and 0.1-1 part of a light conversion agent; and the light conversion agent is an organic complex formed by rare-earth europium and alpha-thenoyltrifluoroacetone and triphenylphosphine oxide. The poly (butyleneadipate-co-terephthalate) and the polylactic acid are used as a polymer matrix, the light conversion agent is synthesized by using the rare earth europium and organic small molecule ligands, ultraviolet light can be effectively absorbed, red light can be emitted to meet the growth requirements of plants, meanwhile, the biodegradable light conversion film has biological degradation performance, and the accumulation of a mulching film in a soil tilling layer can be reduced. The biodegradable light conversion film disclosed by the invention is wide in application field, can replace traditional PE (polyethylene) mulching films and the like for crop cultivation, and has a wide market prospect. The invention further provides a preparation method of the biodegradable light conversion film.
Owner:CHANGCHUN INST OF APPLIED CHEMISTRY - CHINESE ACAD OF SCI

Preparation method and application of magnetic thenoyltrifluoroacetone TTAaFe3O4

The invention discloses a preparation method and application of magnetic thenoyltrifluoroacetone TTAaFe3O4. A magnetic TTAaFe3O4 adsorbent is synthesized from TTA and magnetic Fe3O4. The synthesized magnetic TTAaFe3O4 adsorbent is applied to adsorption of heavy metal ions Cu2+, the adsorption effect is good, the adsorption amount is large, the desorption conditions are mild, high reproducibility is achieved, and reutilization is achieved.
Owner:UNIV OF JINAN

Preparation method of red light emitting fluorescent powder

The invention relates to a preparation method of red light emitting fluorescent powder. By aiming at the conditions of difficult film forming of red light fluorescent powder and poor ultraviolet light resistant performance, 2-thenoyltrifluoroacetone-phenanthroline-methacrylic acid-europium and (4-vinyl phenyl) trimethoxy silane is used as raw materials to prepare the red light emitting fluorescent powder through solution preparation, polymerization reaction, washing, suction filtration, vacuum freeze drying, grinding and screening. The preparation method has the advantages that the process is advanced; the data is precise, full and accurate; the prepared powder body material has high precision and good purity; the purity reaches 9.2 percent; the powder body particle diameter is less than or equal to 800nm; the chromaticity coordinate X is 0.625; Y is 0.308; red light is emitted out; the materials can be matched with blue and green luminous materials to be prepared into white light emitting light emitting diodes; the preparation method belongs to an advanced red light emitting fluorescent powder preparation method.
Owner:TAIYUAN UNIV OF TECH

Red fluorescence nanofiber with piezoelectric function and preparation method of red fluorescence nanofiber with piezoelectric function

The invention discloses a red fluorescence nanofiber with a piezoelectric function and a preparation method of the red fluorescence nanofiber with the piezoelectric function. The method includes steps: dissolving a first component, 2-thenoyltrifluoroacetone and a second component into absolute ethyl alcohol, mixing, stirring for a period of time, and washing and drying a precipitate to obtain a red fluorescence rare earth complex; mixing polyvinylidene fluoride, a third component and acetone, and adding the red fluorescence rare earth complex to obtain electrospinning precursor solution; performing electrospinning by adopting the electrospinning precursor solution to obtain the red fluorescence nanofiber with the piezoelectric function. The nanofiber has an excellent fluorescence propertyand is capable of emitting red fluorescence, fluorescence intensity controllability is realized, beta crystal content of the nanofiber is at least 85% and reaches 97.76% maximally, excellent piezoelectric energy is achieved, and the preparation method is simple, feasible and available for batch production.
Owner:BEIJING INSTITUTE OF PETROCHEMICAL TECHNOLOGY

Visible light excited six-core tripolyphosphazene europium complex luminescent material and preparation method and application thereof

ActiveCN110003278ABroaden the excitation wavelength rangeSolve the problem of low luminous performanceGroup 5/15 element organic compoundsLuminescent compositionsPhotoluminescenceRare earth
The invention discloses an Eu(TTA)3-CTP-TPY complex luminescent material and a preparation method and application. A hexa(4-(terpyridyl)phenoxyl)cyclotripolyphosphazene ligand coordinates with six Eu<3+> luminescence centers simultaneously such that there exist up to six luminescence centers of rare earth complex in a luminescent molecule and 18 beta-diketone ligands (2-thenoyltrifluoroacetone) also exist in each luminescent molecule. Thus, the six-core tripolyphosphazene luminescent material has two ligands simultaneously, which greatly enhances energy transfer efficiency from the ligands tothe europium luminescence centers. And then, the material has more excellent luminescence property. When excited by visible light and ultraviolet light, the complex can produce red light, light response range of the rare earth luminescent material is expanded, and its application range is broadened. The preparation method of the invention has simple steps, is low-cost, has high efficiency, and isof great significance for development of a novel multi-core rare earth photoluminescence material.
Owner:CHONGQING UNIV OF TECH

Hydrogel composite material with porous structure as well as preparation and application thereof

The invention relates to the technical field of hydrogel composite materials, and discloses a hydrogel composite material with a porous structure as well as preparation and application thereof. The hydrogel composite material is CNF / CC / Eu / TTA, and a rare earth complex formed by TTA and Eu is connected with a three-dimensional network structure formed by CNF and CC in a covalent bond mode. The CNFis cellulose nanofibers, the CC is carboxylated chitosan, the Eu is rare earth europium ions, and the TTA is sodium salt obtained after deprotonation of 2-thiophene formyl trifluoroacetone. The cellulose nanofibers are combined with the carboxylated chitosan through hydrogen bonds. The rare earth europium ions are coordinated with carboxyl functional groups of the carboxylated chitosan, so that the rare earth europium ions are stably connected with a hydrogel network skeleton in a covalent bond mode, and the TTA is further coordinated with the rare earth europium ions to form an excellent redfluorescent hydrogel material which shows excellent compressive strain performance and can be used as an environment-friendly recognition material.
Owner:YUNNAN NORMAL UNIV

Preparation method of thenoyltrifluoroacetone (HTTA) modified rare earth hydroxide nano-sheet fluorescence reinforcing material

The invention discloses a preparation method of a thenoyltrifluoroacetone (HTTA) modified rare earth hydroxide nano-sheet fluorescence reinforcing material. The preparation method comprises the following steps of dissolving yttrium nitrate hexahydrate into deionized water firstly, then adding europium nitrate hexahydrate, and performing uniform mixing; dropwise adding dilute ammonia water, and regulating a pH value of the solution to 7.5; putting the solution in a microwave field, performing continuous microwave treatment for 20 min in the N2 protection atmosphere, performing air pump filtration, water washing and washing with ethanol on a product after microwave treatment, and then putting the product in a vacuum drying tank at the condition with the temperature being 35 DEG C for dryingand grinding to obtain a dry powdery rare earth hydroxide hydrate; and then performing ion exchange, ultrasonic treatment and modification on the dry powdery rare earth hydroxide hydrate to obtain theHTTA modified rare earth hydroxide nano-sheet fluorescence reinforcing material. According to the preparation method, by utilizing the antenna effect of a ligand, the energy absorbed by the ligand istransferred to rare earth ions, so that the fluorescence performance of a composite is improved by an order of magnitude.
Owner:FUYANG NORMAL UNIVERSITY

Method for repairing heavy metal contaminated soil

InactiveCN111036667AAchieve chelationTo achieve repairContaminated soil reclamationSoil scienceThenoyltrifluoroacetone
The invention discloses a method for repairing heavy metal contaminated soil. The method relates to the technical field of soil remediation, and comprises the following steps: (1) taking heavy metal mixed contaminated soil, putting the heavy metal mixed contaminated soil into a high-temperature and high-pressure reaction kettle, adding an organic solvent into the soil, introducing carbon dioxide gas, and heating and pressurizing the carbon dioxide gas to a supercritical state of carbon dioxide, and (2) spraying 2-thiophenyltrifluoroacetone into the high-temperature and high-pressure reaction kettle to leach the soil for a period of time. Through combined use of supercritical carbon dioxide and 2-thiophenyltrifluoroacetone (TTA), chelating of Cu, Zn, Ni and other heavy metal ions in soil isachieved, and the effect of soil remediation is achieved.
Owner:山东碧泉环境工程技术有限公司

Low-waveband ultraviolet absorption antibacterial light conversion film and preparation method thereof

ActiveCN111944221ABroaden the UV absorption bandReduce adverse effects on growthPlant protective coveringsPhenanthrolineUltraviolet lights
The invention discloses a low-waveband ultraviolet absorption antibacterial light conversion film and a preparation method thereof. The light conversion film comprises the following components: 89.97-99.99 parts of polymer resin, 0.001-0.003 part of a light conversion agent, 0-5 parts of an anti-aging agent, and 0-5 parts of an anti-fog drop agent. The general molecular formula of the light conversion agent is [Eu(TTA)xPhen(beta-T)(3-x)], wherein TTA is 2-thenoyltrifluoroacetone, Phen is 1,10-phenanthroline, and (beta-T) is Chamaecyparis pisifera oleyl alcohol. By introducing the novel light conversion agent into the light conversion film, the absorption capacity of the light conversion film to low-waveband ultraviolet light is enhanced, the waveband ultraviolet light is converted into redlight required by plant photosynthesis, growth of crops is facilitated, in addition, the light conversion film is remarkable in antibacterial effect, and growth of pathogenic microorganisms can be effectively inhibited.
Owner:INST OF ENVIRONMENT & SUSTAINABLE DEV IN AGRI CHINESE ACADEMY OF AGRI SCI

Rare earth ternary complexes, preparation and use thereof

The invention discloses a rare earth ternary complex with a chemical formula of RE(TTA)3 L question mark nH20, wherein, the RE refers to rare-earth ions, the TTA refers to thenoyl trifluoro acetone, the L refers to aromatic carboxylate, the chemical structural formula thereof are shown as right, and n equals to 0 to 7. The rare earth ternary complex has good chemical stability and thermal stability, endures high temperature of 320 DEG C and can be used, stored and transported at normal temperature; the bacteriostatic circle diameters of the rare earth ternary complex against colibacillus and Staphylococcus aureus are all equal to or larger than 20mn, and the minimal inhibitory concentration thereof is lower than 200mug question mark ml , especially the rare earth ternary complex with particle size ranging from 10nm to 300nm has stronger antibacterial action and more obvious antibacterial effect, and the antibacterial capacity in unit dosage of the rare earth ternary complex is better than that of any single ligand. Therefore, the rare earth ternary complex can be used for preparing novel antibacterial materials and is applied to the environmental purification field. In addition, the rare earth ternary complex is characterized by simple preparation method, mild reaction condition and small environmental pollution caused by manufacturing links.
Owner:SHANGHAI NORMAL UNIVERSITY

Rare earth europium composite fluorescent material using sodium acetate as matrix, and preparation method thereof

PendingCN110734760AEasy to prepareHigh fluorescence excitation intensityLuminescent compositionsSodium acetateQuantum yield
The invention provides a rare earth europium composite fluorescent material using sodium acetate as a matrix, and a preparation method thereof, wherein the europium coordination compound composite fluorescent material is prepared by using europium ions as a luminous body, using triphenyl phosphine oxide (TPPO) and 2-thenoyltrifluoroacetone (TTA) as organic ligands and using sodium acetate as a matrix through a reaction under set conditions, and is characterized. According to the invention, the cost of the luminescent material is reduced, and the prepared material is long in service life, highin quantum yield, high in fluorescence intensity and good in fluorescence performance.
Owner:FUYANG NORMAL UNIVERSITY

Raveearth multi-element compounding material light conversion agent with ecological and phycological characteristics and preparation process thereof

The present invention relates to a rare earth multi-component coordination compound light-converting agent with ecological and physiological characteristics, its mole ratio is as follows: rare earth 1, organic ligand 0-6, organosilicon surfactant (A) 0-6, and solvent 3-10, in which the rare earth ion is Eu(3+), which is provided by nitrate and hydrochloride of trivalent europium, and the chemical structure formula for its organosilicon surfactant is (RO)3SiR1N+R2R3R4X-. Its organic ligand is alpha-thenoyltrifluoroacetone (TTA), triphenyloxyphosphine (TPPO) or its two-component coordination compound. Its applicable liquid solvent is methylbenzene, dimethyl benzene, methyl alcohol, cyclohexane, ethyl alcohol, isopropanol, methyl-sulfoxide or their mixture, and its solid solvent is silicone.
Owner:NANJING NORMAL UNIVERSITY

Rare earth composite fluorescent material taking carbonate as matrix and preparation method thereof

InactiveCN110655916AEasy to prepareHigh fluorescence excitation intensityLuminescent compositionsQuantum yieldThenoyltrifluoroacetone
The invention provides a rare earth composite fluorescent material taking carbonate as a matrix and a preparation method of the rare earth composite fluorescent material. According to the preparationmethod, europium ions are used as a luminous body; triphenyl phosphine oxide (TPPO) and 2-thiophenyltrifluoroacetone (TTA) are taken as organic ligands; calcium carbonate is taken as a matrix; an europium complex composite fluorescent material is prepared under set conditions, and the obtained composite fluorescent material is characterized. The cost of the fluorescent material is reduced, and theprepared material is long in service life, high in quantum yield, high in fluorescence intensity and good in fluorescence performance.
Owner:FUYANG NORMAL UNIVERSITY

Novel cage type low polysilsesquioxane and rare earth light-emitting material thereof

The invention discloses a cage type low polysilsesquioxane and a rare earth ion light-emitting material. 1,3,5,7,9,11,14-heptaisobutyltricyclo[7.3.3.15,11]heptasiloxane-endo-3,7,14-triol is used as a matrix, and an alpha-thenoyltrifluoroacetone silanization derivative, a dipyridyl silanization derivative and a terpyridyl silanization derivative are used as angle complementing bodies, and the complementing bodies react with the matrix in an angle complementing manner to form the complete novel cage type low polysilsesquioxane; and the novel cage type low polysilsesquioxane is combined with a rare earth element to form a cage type low polysilsesquioxane (POSS) / rare earth ion light-emitting material. The rare earth compound / low polysilsesquioxane material is rich in light-emitting colors, is high in color purity, long in fluorescence lifetime (0.5-1.5ms), high in quantum efficiency (20), and strong in heat stability (350 DEG C) and light stability, is a valuable optical material, and can be applied to the fields of display and development, new light sources, X ray intensifying screens and the like.
Owner:HEBEI UNIV OF TECH

Organic rare earth europium luminescent polyester and preparation method thereof

The invention discloses an organic rare earth europium light-emitting dacron and a preparation method thereof. The preparation method comprises the following steps: firstly preparing an o-phenanthroline neutral ligand which is combined with alpha-thenoyltrifluoroacetone and rare earth Eu (III) for coordination and preparing a rare earth europium coordination compound Eu(TTA)3DMPaPhen light-emitting material having a close nanoscale by virtue of an atmospheric titration and high-pressure reaction method. The material emits very strong pure red light in a 10<-5>mol / L CH2Cl2 solution at 615nm. A light-emitting fiber is prepared from the coordination compound as a light-emitting material and polyethylene terephthalate (PET) through composite melt spinning. When the content of the rare earth light-emitting material in the fiber is 0.05%, the rare earth light-emitting material emits very strong pure red light in a 10<-5>mol / L CH2Cl2 solution at a light-emitting position of 615nm. The light-emitting fiber has the advantages of high color purity and good spinnability.
Owner:湖州信倍连网络科技有限公司
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