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Tetraheteropoly rare earth organic complex and preparation thereof

A technology of rare earth organic complexes, which is applied in the field of rare earth organic light-emitting materials, can solve the problems of quaternary rare earth organic complexes that have not been reported in the literature, and achieve the effects of simple and easy synthesis routes, good solubility, and excellent processing performance

Inactive Publication Date: 2008-11-12
BEIJING UNIV OF CHEM TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] There are no literature reports on the research on quaternary rare earth organic complexes

Method used

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  • Tetraheteropoly rare earth organic complex and preparation thereof
  • Tetraheteropoly rare earth organic complex and preparation thereof
  • Tetraheteropoly rare earth organic complex and preparation thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] A. Press Eu(TTA) 2 (N-HPA) Phen formula theoretical measurement, respectively take 0.2mol.L -1 EuCl 3 Ethanol solution 10ml, add 0.2mol.L under stirring -1 1,10-Phen ethanol solution in 10ml mixed solution, then slowly drop 0.2mol.L in a water bath at 60℃ under constant stirring -1 HTTA ethanol solution 20ml and 0.2mol.L -1 N-HPA ethanol solution 10ml.

[0030] B. Adjust the pH value to 7 with triethylamine to produce a white precipitate, let the above reactant stand at room temperature for 24 hours, let it mature, filter with suction, and wash the precipitate with absolute ethanol until there is no Cl - , dried in an oven at 70°C to obtain a white solid rare earth organic complex Eu(TTA) 2 (N-HPA)Phen.

Embodiment 2

[0032] A. Press Tb 0.25 Eu 0.75 (TTA) 2 (N-HPA)Phen formula theoretical measurement, respectively take 0.75mol.L -1 EuCl 3 and 0.25mol.L -1 TbCl 3 Mix 5ml of ethanol solution evenly, add 0.25mol.L under stirring -1 10ml of 1,10-Phen ethanol solution, then heated in a 62°C water bath, and slowly dripped 0.25mol.L of -1 HTTA ethanol solution 20ml, 0.25mol.L -1 N-HPA ethanol solution 10ml.

[0033] B. Adjust the pH value to 6.5 with triethylamine to produce a white precipitate. Let the above reactant stand at room temperature for 20 h, let it mature, filter it with suction, wash the precipitate with absolute ethanol until there is no Cl - , dried in an oven at 62°C to obtain a white solid rare earth organic complex Tb 0.25 Eu 0.75 (TTA) 2 (N-HPA)Phen.

Embodiment 3

[0035] A. Press Tb 0.5 Eu 0.5 (TTA) 2 (N-HPA) Phen formula theoretical measurement, respectively take 0.5mol.L -1 EuCl 3 and 0.5mol.L -1 TbCl 3 Mix 5ml of ethanol solution evenly, add 0.25mol.L under stirring -1 10ml of 1,10-Phen ethanol solution, then heated in a 65°C water bath, and slowly dripped 0.25mol.L of -1 HTTA ethanol solution 20ml, 0.25mol.L -1 N-HPA ethanol solution 10ml.

[0036] B. Adjust the pH value to 6.6 with triethylamine to produce a white precipitate. Let the above reactant stand at room temperature for 22 hours, let it mature, filter it with suction, and wash the precipitate with absolute ethanol until there is no Cl - , dried in an oven at 65°C to obtain a white solid rare earth organic complex Tb 0.5 Eu 0.5 (TTA) 2 (N-HPA)Phen.

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Abstract

The invention relates to quaternionic rare earth organic complexes as shown in general formula (I). The chemical name of the organic complexes is Eu-Tb thenoyltrifluoroacetone-N-phenylanthranilic acid-o-phenanthroline organic complexes. The chemical formula of the organic complexes is Tb1-xEux (TTA) 2 (N-HPA) Phen, wherein x is equal to 0-1. The invention also relates to a method for making the quaternionic rare earth organic complexes.

Description

technical field [0001] The invention relates to the technical field of rare earth organic luminescent materials, in particular to a quaternary rare earth organic complex and a synthesis method thereof. The quaternary rare earth organic complex has photoluminescence and electroluminescence properties. Background technique [0002] Rare earth luminescent materials can be divided into photoluminescence, cathodoluminescence, X-ray luminescence, and electroluminescence materials, etc., and have great application value in the fields of laser, photoluminescence, and electroluminescence complexes. [0003] According to the luminescence principle of rare earth complexes, the structure and properties of ligands are important factors affecting the luminescence efficiency of rare earth complexes, and it is very important to design and synthesize new ligands with high-efficiency sensitized luminescence. Bisβ-diketones containing polyaromatic rings can not only absorb ultraviolet light e...

Claims

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Application Information

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IPC IPC(8): C07F5/00C09K11/06
Inventor 张敬畅吕玉光曹维良
Owner BEIJING UNIV OF CHEM TECH
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