The invention relates to the field of
fine chemical engineering materials and specifically relates to a reactive type
intumescent flame retardant for water-based
polyurethane, which simultaneously contains a
carbon source, an acid source, a gas source and active amino groups, and a preparation method of the reactive type
intumescent flame retardant. The
chemical structure of the reactive type
intumescent flame retardant disclosed by the invention is as shown in formula I, the obtained flame retardant does not contain
halogen, has relatively high content of
phosphorus and
nitrogen flame retardant components and shows an aromatic heterocyclic structure, thereby having good stability at high temperature, high
char yield, significant intumescence and excellent flame retardance. Two active primary amino
hydrogen ions contained in the structure can react with
isocyanate to prepare flame-retardant water-based
polyurethane, thereby not only effectively solving the problems of poor compatibility, easiness in migration,
precipitation and
permeation and the like of a traditional complex additive type flame retardant in a water-based
polyurethane system, but also overcoming the defect that the physical and mechanical
properties of water-based polyurethane become poor caused by the complex additive type flame retardant. When the reactive type intumescent flame retardant provided by the invention is used for preparing water-based polyurethane, the process is easy to control, the properties are easy to regulate, and prepared water-based polyurethane is widely applied to leather finishing, synthetic leather coatings, fabric coatings, building fireproof materials,
coating materials, adhesives and other industries. The formula I is described in the specification.