The invention relates to an
ageing oil
demulsifier and a preparation method thereof, and belongs to the technical field of
petroleum processing. The
ageing oil
demulsifier comprises mixed acid, a
demulsifier monomer and an initiator, wherein the mixed acid consists of
acrylic acid and
maleic anhydride based on the
molar ratio of (1-3): (0.5-1.5); the
molar ratio of the mixed acid to the demulsifier
monomer, namely,
alkyl phenolic resin-polyoxyethylene polyoxypropylene
ether, is (0.5-1.7): (0.5-1.5); the initiator, namely,
lauroyl peroxide, accounts for 8 to 12% of the
mass of the mixed acid. The preparation method comprises the following processes: adding the initiator, namely
lauroyl peroxide to mixed acid and demulsifier
monomer, namely
alkyl phenolic resin-polyoxyethylene polyoxypropylene
ether; polymerizing for 1 to 4 hours under a temperature of 70 to 100 DEG C; heating to reach 100 to 150 DEG C; esterifying for 3 to 7 hours to obtain the
ageing oil demulsifier. The ageing oil demulsifier has the characteristics of being simple in components, simple in process, convenient, fast and efficient to prepare, low in cost, small in dosage, small in toxic and side effects, wide in application scope, good in demulsifying effect, etc.