61 results about "Organometallic polymer" patented technology

Polymeric nanofibers have been developed which are useful in a variety of medical and other applications, such as filtration devices, medical prosthesis, scaffolds for tissue engineering, wound dressings, controlled drug delivery systems, cosmetic skin masks, and protective clothing. These can be formed of any of a variety of different polymers, either non-degradable or degradable. In a preferred embodiment demonstrated in the following examples, nanofibers are formed of biodegradable and non biodegradable polyphosphazenes, their blends with other polyphosphazenes or with organic, inorganic / organometallic polymers as well as composite nanofibers of polyphosphazenes with nanosized particles such as hydroxyapatites.

A semiconductor device capable of high speed operation with a substantially small interlayer capacitance is produced by steps of using an insulating film comprising an organic insulating film and an insulating film composed of an organometallic polymer material as an interlayer insulating film formed by coating, patterning the insulating film in a semi-thermosetting state, etching the organic insulating film as the lower layer by means of the organometallic polymer as a mask, using a plasma gas containing oxygen as the main component, and then conducting ultimate baking treatment of these insulating films.

Polymeric nanofibers have been developed which are useful in a variety of medical and other applications, such as filtration devices, medical prosthesis, scaffolds for tissue engineering, wound dressings, controlled drug delivery systems, cosmetic skin masks, and protective clothing. These can be formed of any of a variety of different polymers, either non-degradable or degradable. In a preferred embodiment demonstrated in the following examples, nanofibers are formed of biodegradable and non biodegradable polyphosphazenes, their blends with other polyphosphazenes or with organic, inorganic / organometallic polymers as well as composite nanofibers of polyphosphazenes with nanosized particles such as hydroxyapatites.

A resist removing composition has an excellent capability for removing a resist, polymer, organometallic polymer and metal oxide and which does not attack underlying layers, and a resist removing method using the same. The resist removing composition includes alkoxy N-hydroxyalkyl alkanamide, at least one selected from the group consisting of alkanolamine, a polar material having a dipole moment of 3 or greater and an attack inhibitor, and hydrogen peroxide or at least one of a fluoride-based reducing agent and a hydroxide-based reducing agent.

An organometallic polymer material is obtained which excels in translucency, shows improved hardness after it is cured and exhibits high reliability at high temperature and high humidity.Characteristically, the organometallic polymer material contains an organometallic polymer having an —M—O—M— bond (M indicates a metal atom), a metal alkoxide having a single hydrolyzable group and / or its hydrolysate and an organic polymer having a urethane bond and a methacryloxy or acryloxy group, and preferably further contains an organic anhydride and / or an organic acid.

A curable organometallic composition containing an organometallic polymer having an -M-O-M- bond (M denotes a metal atom) and an aryl group, and a fluorene-based compound having an acryloyl or methacryloyl group, an organometallic polymer obtained by curing the composition and an optical component using the material.

The present invention discloses a novel process for the fabrication of a class of conductive supported electrocatalysts based on transition metals. The electrocatalysts are formed by pyrolysis of an organometallic polymer complex precursor which is the reaction product of transition metal salts and a templating polymer. The electrocatalysts has enhanced catalytic activity, and are useful in the preparation of supercapacitor and fuel cell electrodes, auto-thermal fuel reformer catalysts, oxygen and hydrogen sensors, zinc-air battery electrode and oxidation catalysts.

The present disclosure is directed to processes, compositions and agents for inhibiting corrosion in various substrates, for example metal substrates. The present disclosure is also directed to corrosion inhibitors comprising organometallic polymers such as metal-organic frameworks (MOFs), including compositions and processes comprising MOFs for inhibiting corrosion in metal substrates.

A semiconductor device capable of high speed operation with a substantially small interlayer capacitance is produced by steps of using an insulating film comprising an organic insulating film and an insulating film composed of an organometallic polymer material as an interlayer insulating film formed by coating, patterning the insulating film in a semi-thermosetting state, etching the organic insulating film as the lower layer by means of the organometallic polymer as a mask, using a plasma gas containing oxygen as the main component, and then conducting ultimate baking treatment of these insulating films.

The invention provides a composition comprising at least one dopant, and a polymer containing at least one unit selected from the structure I shown in the specification, wherein M is selected from Fe, Co, or Ni; R1, R2, R3 , R4 and R5 are independently selected from hydrogen, deuterium, halogen, substituted or unsubstituted (C1-C16) alkyl, substituted or unsubstituted (C6-C16) aryl, substituted or unsubstituted (C3-C16) cycloalkyl, substituted or unsubstituted 5- to 7-membered heterocycloalkyl group, substituted or unsubstituted (C6-C16) aryl condensed with one or more cycloalkyls; 5- to 7- membered heterocycloalkyl group condensed with one or more substituted or unsubstituted aromatic rings or (C3-C16) cycloalkyl condensed with one or more substituted or unsubstituted aromatic rings, substituted or unsubstituted (C1-C16) silyl, cyano, nitro or hydroxyl; n is greater than or equal to 1; x is 0-4; y is 0-5; the dopant is a P-type dopant. The polymers containing and free of dopants can be used to prepare films and electronic devices, such as an organic light emitting diode (OLED).

The invention relates to an organometallic polymer ceramic precursor, and a preparation method and application thereof. The organometallic polymer ceramic precursor is prepared by copolymerization of a double-bond-containing organometallic zirconium or titanium or hafnium monomer and a boron-containing monomer. By using the organometallic polymer ceramic precursor for preparing M(Zr,Ti,Hf)-B-C ceramic, the ceramic yield is up to 40-60%, and the content of the super-high-temperature-resistant component (ZrC / ZrB2,TiC / TiB2,HfC / HfB2) in the prepared ceramic material is higher than 70 wt%. When being treated at 2000 DEG C for 2 hours, the organometallic polymer ceramic precursor is not subjected to obvious weight loss, thereby having favorable high-temperature resistance.

Compositions comprising a polymer of organometallic polymerizable monomer acid or ester are useful as resists and are sensitive to imaging irradiation while exhibiting enhanced resistance to reactive ion etching.

An oxygen reduction catalyst and the catalyst as an electrode catalyst are provided. The oxygen reduction catalyst is characterized by including an organometallic polymer structure in which a transition metal or zinc is coordinated with an organic polymer compound including a ligand comprising a heterocyclic 5-membered ring or a heterocyclic 6-membered ring containing at least not less than two elements selected from nitrogen (N), oxygen (O), sulfur (S), and selenium (Se), and derivatives thereof. Thereby, even when an amount of a metal is smaller than that in a platinum particulate catalyst, an oxygen reduction capacity equal to or more than that of the platinum particulate catalyst can be obtained. Further, by coordinating a metal with an organic polymer, stability in an oxygen reduction condition can be significantly improved compared to the case of metal based macrocyclic compounds.

A method of fabricating metal-bearing structures in an integrated circuit such as metal-polysilicon capacitors using conductive metal compounds. Defects due to organometallic polymers formed during the etch of a hard mask material are minimized by using a process that includes a plasma etch for the hard mask that achieves a predominantly chemical character using a fluorine-based etch chemistry. Using a low-temperature liquid-phase strip of the hard mask photoresist instead of an ash prevents further cross-linking of polymers formed during the plasma etch. Etching the metal-bearing material using a hot fully-concentrated mixture of ammonium hydroxide and hydrogen peroxide allows short etch times that are particularly shortened for tantalum nitride films deposited with a nitrogen concentration of about 30 percent or greater.

The invention relates to the technical field of photocatalytic materials, in particular to a preparation method and application of a perylene bisimide based organometallic polymer with visible-light photocatalytic performance.The preparation method includes the steps: 1, adding transition metal salt Tm and perylene bisimide derivative H2PDI in the molar ratio of 1:1.0-1.5 into a mixed solvent of N,N-dimethylformamide and water in the volume ratio of 1:2-2.5, and regulating the solution to alkalescence with NaOH; 2, putting the reaction solution prepared in the step 1 in an oven with the temperature controlled between 90 DEG C and 110 DEG C and time controlled between 60h and 80h, closing the oven, cooling to room temperature, crystallizing out, filtering and drying to obtain the target material Zn-PDI.The catalyst is simple to synthesize and easy to operate, the catalyst and the raw materials for catalytic reaction are low in cost, yield is high, visible-light photocatalysis can be realized under mild conditions, and convenience is brought to widespread popularization and application.

An organometallic polymer material is obtained which excels in translucency, shows improved hardness after it is cured and exhibits high reliability at high temperature and high humidity.Characteristically, the organometallic polymer material contains an organometallic polymer having an -M-O-M- bond (M indicates a metal atom), a metal alkoxide having a single hydrolyzable group and / or its hydrolysate and an organic polymer having a urethane bond and a methacryloxy or acryloxy group, and preferably further contains an organic anhydride and / or an organic acid.

The present invention relates to polymeric composites comprising inorganic fillers and organic, or organometallic, polymers. The filler compositions are used in the preparation of inorganic-organic polymeric composites, and, in particular, light curable composites. The composite fillers are used in dental applications, such as tooth restorations, for example, cavity fillings, adhesive compositions, veneers, crowns, bridges and teeth replacements. The inventive composition is a composite filler comprising porous inorganic particles having a diameter of 2-25 microns and a polymer occupying the pores of the porous inorganic particles, wherein the composite filler has a diameter of 2-25 microns.

The invention provides an optical polymer material having a low viscosity before curing, a high refractive index of a cured product, little alteration of refractive index under high temperature and high humidity, and an excellent heat resistant shock property and an optical component using the optical polymer material.The optical polymer material is characterized in that the material contains a fluorene compound having four (meth) acryloyl groups and a (meth) acrylate having an aryl group and may further contain -M-O-M- bond (M is a metal atom), an organometallic polymer having an aryl group, a monofunctional (meth)acrylate and / or a polyfunctional (meth)acrylate.

The invention provides an organometallic polymer composite ceramic precursor and a preparation method and application thereof.The organometallic polymer composite ceramic precursor can be used to prepare Zr-Si-C-N ceramics, the yield of the ceramics is 40-60%, no evident weight loss is discovered when the ceramics are processed at 2000 DEG C for 2 hours, and the ceramics are good in high temperature resistance.The ceramics are promising in application prospect in fields such as aviation and supersonic aircrafts.

The invention discloses a core-shell structure precious metal-nitrogen heterocyclic Carbene polymer magnetic catalyst and a preparation method thereof and belongs to the technical field of organometallic polymers. The core-shell structure precious metal-nitrogen heterocyclic Carbene polymer magnetic catalyst comprises a paramagnetic Fe3O4 core and a precious metal-nitrogen heterocyclic Carbene polymer coating the surface of the paramagnetic Fe3O4 core. In the presence of Fe3O4 nano-particles, an imidazolium salt monomer TIPT-Cl or TIPB-Cl and a precious metal acetate undergo an ultrasonic reaction at a temperature of 90 DEG C in N,N-dimethyl formamide (DMF) as a solvent for 1h, and then the reaction system undergoes a reaction in an oil bath at a temperature of 110 DEG C for 5h to product the core-shell structure precious metal-nitrogen heterocyclic Carbene polymer magnetic catalyst. The core-shell structure precious metal-nitrogen heterocyclic Carbene polymer magnetic catalyst has high-dispersed active sites and good catalytic activity. Through the magnetic Fe3O4 core, the catalyst can be separated easily in the liquid phase reaction and can be conveniently recovered and recycled.

A curable organometallic composition containing an organometallic polymer having an -M-O-M- bond (M denotes a metal atom) and an aryl group, and a fluorene-based compound having an acryloyl or methacryloyl group, an organometallic polymer obtained by curing the composition and an optical component using the material.

The invention belongs to the technical field of heterogeneous catalysts, and particularly relates to a monodisperse porous organic metal polymer material and a preparation method and application thereof. The polymer is prepared by taking homogeneous double carbene iridium, palladium, gold, copper, cobalt and manganese compounds as monomers and aromatic hydrocarbon as a comonomer in a manner of adding a cross-linking agent and carrying out Friedel-Crafts alkylation under the catalysis of Lewis acid. The polymer can be used for catalyzing hydrogenation cyclization of levulinic acid to prepare gamma-valerolactone, or catalyzing oxidative dehydrogenation of polyol and derivatives thereof and carbohydrate compounds to efficiently prepare lactic acid and derivatives thereof, and dehydrogenationcoupling of alcohol compounds and amine to efficiently prepare pyrrole and derivatives thereof. The polymer material completely holds intrinsic high activity and high selectivity of a homogeneous catalyst precursor and has the characteristics of heterogeneous catalysis stability and easiness in recovery, so that biomass can be converted into various fine chemicals with high efficiency, high selectivity and a large amount; the catalyst can be recycled for multiple times and has a good industrial application prospect.

A circuit board structure and fabrication method thereof are disclosed, including: a circuit board with a circuit layer thereon; a reactant formed on the surface of the circuit layer, wherein the reactant is an organic metallic polymer having a polymer end and a metal ion end; and a dielectric layer formed above the reactant and the circuit board, thus forming a metallic bond between the metal ion end of the reactant and the circuit layer and forming a chemical bond between the polymer end of the reactant and the dielectric layer. Owing to enhanced bonding between the dielectric layer and the circuit board, electrical performance of the circuit board structure is improved, and the demand for fine circuits is met.

The present invention provides metal-organic materials, more specifically organometallic polymers, comprising polypyridyl organic ligands such as tetrakis(4-(pyridin-4-ylethynyl)phenyl)methane, tetrakis(4-(2-(pyridin-4-yl)vinyl)phenyl)methane,,3,5,7-tetrakis(4-(pyridin-4-ylethynyl)phenyl)adamantane or 1,3,5,7-tetrakis(4-(2-(pyridine-4-yl)vinyl)phenyl) adamantine, and metal ions structurally coordinated with said ligands, and having three-dimensional crystalline micro or sub-micro structure; as well as a method for the preparation thereof. These metal-organic materials are useful as adsorbents in processes for gas adsorption or separation.

A laminated optical element includes an optical substrate made of an optical material, an intermediate layer provided on the optical substrate, and an optical resin layer provided on the intermediate layer. The optical resin layer is made of a resin composed of an organometallic polymer having an -M-O-M- bond (M is a metal atom), a metal alkoxide and / or a hydrolysate thereof having only one hydrolyzable group, and an organic polymer having a urethane bond and a methacryloxy group or an acryloxy group. The intermediate layer is obtained by dispersing metal oxide microparticles in a matrix resin composed of a metal alkoxide having a radical polymerizable group and a hydrolyzable group and / or a hydrolysate thereof.

The invention belongs to the technical field of organic synthesis and heterogeneous catalysis, and particularly relates to a method for preparing a formamide compound by catalyzing carbon dioxide hydrogenation through a porous material. The method comprises the following steps: by taking a porous organic metal polymer as a catalyst, reacting an amine compound with carbon dioxide and hydrogen in anair atmosphere to prepare the formamide compound. The method has the advantages of high reaction efficiency, good selectivity, mild conditions, economy, environmental protection, simple operation andthe like; wherein a solid metal polymer material with large specific surface area, strong carbon dioxide adsorption, hierarchical pore channel distribution and highly dispersed metal centers is designed and synthesized as a reaction catalyst by changing a cross-linked copolymer proportion; the catalyst is especially used for catalytic synthesis of fine chemical N, N-dimethylformamide (DMF), doesnot need any additional solvent, alkali or other additives, and is convenient for separation and purification of DMF. The catalyst can be recycled; no special equipment is needed in the reaction, thereaction operation is simple, and further industrial application is facilitated.

Disclosed is a multilayer optical device which is a composite optical device wherein an optical resin layer is arranged on an optical base such as a glass base. This multilayer optical device is excellent in reliability since the optical resin layer is hardly separated even under high temperature, high humidity conditions. Specifically disclosed is a multilayer optical device comprising an optical base (1) made of an optical material, an intermediate layer (2) arranged on the optical base (1), and an optical resin layer (3) arranged on the intermediate layer (2). This multilayer optical device is characterized in that the optical resin layer (3) is a resin layer made of an organic metal polymer having an -M-O-M- bond (wherein M represents a metal atom), a metal alkoxide having one hydrolyzable group and / or a hydrolysis product thereof, and an organic polymer having an urethane bond and a methacryloxy or acryloxy group. The intermediate layer (2) is a layer wherein fine particles of a metal oxide are dispersed in a matrix resin which is made of a metal alkoxide having a radically polymerizable group and a hydrolyzable group and / or a hydrolysis product thereof.

An organometallic polymer material, characterized in that, in an organometallic polymer having a -M-O-M-bond (M is a metal atom), a metal alkoxide with only one hydrolyzable group and / or It is more preferable that its hydrolyzate further contains an organic acid anhydride and / or an organic acid.

This invention relates to an organometallic polymeric photonic bandgap (OMPBG) material that can be defined by blending block copolymer (BCP) and at least two homopolymers, thereby obtaining an organometallic polymeric photonic bandgap hybrid material with periodic structure by self-assembly, wherein said homopolymers include at least one organometallic homopolymer. The improved material has high reflectivity.

A circuit board structure and fabrication method thereof are disclosed, including: a circuit board with a circuit layer thereon; a reactant formed on the surface of the circuit layer, wherein the reactant is an organic metallic polymer having a polymer end and a metal ion end; and a dielectric layer formed above the reactant and the circuit board, thus forming a metallic bond between the metal ion end of the reactant and the circuit layer and forming a chemical bond between the polymer end of the reactant and the dielectric layer. Owing to enhanced bonding between the dielectric layer and the circuit board, electrical performance of the circuit board structure is improved, and the demand for fine circuits is met.