Described here are compositions, methods and apparatus for biological and physical geoengineering. Disclosed are inorganic particles, prill, pucks, or floats for dispersal on a body of water, the compositions having several properties: 1) positive buoyancy, 2) a sustained-release matrix for delivery of iron, calcium, magnesium, zinc, copper, molybdenum, manganese, cobalt, boron, selenium, vanadium, chromium, nickel, sulfur, nitrogen, phosphorus, silicon, preferably as a combination thereof, at biologically efficacious levels, and synergically, 3) a light-reflective surface for increasing planetary albedo when dispersed over large surfaces. These compositions are found to A) increase yields for pelagic aquaculture, B) increase carbon sequestration, and C) provide immediate relief from global warming by directly increasing surface albedo and indirectly by increasing cloud nucleation activity. A preferred composition comprises a mixture of inorganic salts and binders (such as a glass or ceramic) effective for increasing the growth of primary aquatic producers such as coccolithophorids, diatoms, silicoflagellates, dinoflagellates, and microalgae (and higher trophic levels) in a sustained-release composition having a T1 / 2 of 0.5-3 years. To validate resultant carbon fixation and sequestration, a vertical spar buoy is provided. The buoy is designed to resist wave motion while supporting a stable long-term platform and submerged spaceframe with laser particle counters suspended below the 100 year horizon. Validation of exsolation energy credits, issuance of an associated financial instrument, and trading markets for those instruments are also described.