The invention relates to a levo-meptazinol phenylamino carbamate-L-(+)-tartrate type-I crystal and a preparation method thereof. The levo-meptazinol phenylamino carbamate-L-(+)-tartrate type-I crystal provided by the invention is stable and is characterized in that the degrees of angles 2[theta] of characteristic peaks shown in an X-ray powder diffractogram are respectively 10.1, 11.9, 13.4, 14.9, 15.4, 17.5, 17.9, 18.7, 19.6, 20.5, 21.7, 22.1, 22.6, 23.3, 24.4, 25.4, 26.9, 27.2, 27.6, 29.0, 29.8, 30.0 and 30.3, and corresponding relative intensities are respectively 42, 14, 26, 43, 66, 28, 14, 20, 33, 100, 25, 31, 51, 14, 15, 10, 10, 12, 16, 10, 12, 11 and 10. The melting point of the levo-meptazinol phenylamino carbamate-L-(+)-tartrate type-I crystal provided by the invention is 101.6-103.8 DEG C.