The invention discloses a high-strength high-tenacity sintered flux for afterheat-free welding. The sintered flux is mixed sinter composed of dry powder and pure sodium water glass with the modulus of 2.8-3.2, and the addition amount of the water glass is 18-20% of the weight of the dry powder. The dry powder is composed of, by weight percent, 18-23% of fluorite, 33-37% of magnesia, 14-17% of bauxite, 3-5% of quartz, 7-12% of marble, 9-13% of wollastonite, 0-1.5% of ferromolybdenum, 1-3% of rare earth fluoride, 1-2% of silicon iron, 1-3% of manganese ore, and 0-3% of borax. Compared with the prior art, the sintered flux can form welding slag with an appropriate melting point and good viscosity and surface tension. In the welding process, arc combustion is stable, welding line transition is smooth, spreading is good, and appearance of welding lines is attractive. The oxygen content in the welding lines is lowered. The sintered flux can be matched with the WS80S welding wire for welding 10CrNi5MoV steel, yield strength of metal of the welding lines can reach more than 735MPa, the metal of the welding lines is -50 DEG C, impact energy can reach more than 50J, and the metal of the welding lines of afterheat-free welding can be crack-free.