The invention relates to a preparation method of ordered mesopore molybdenum carbide, which belongs to the field of ordered mesopore material preparation. The preparation method comprises the following steps of adopting a hard template method, adopting saccharose as a carbon source and an SBA-15 molecular sieve as a template, stirring, carrying out ultrasound, drying and carbonizing, roasting, and acid pickling to obtain an ordered mesopore carbon material; then soaking the ordered mesopore carbon material into an ammonium molybdate solution (a molybdenum source), stirring, drying by distillation, and roasting to obtain an ordered mesopore carbon / molybdenum trioxide compound; mixing the ordered mesopore carbon / molybdenum trioxide compound with magnesium powder, and carrying out magnesiothermic reduction reaction in a tube furnace to obtain the ordered mesopore molybdenum carbide material. During the preparation process, the carbonization reduction temperature is greatly reduced; the molybdenum carbide prepared at a low temperature condition is concentrated in bore diameter and large in specific surface area; the rich mesoporous structure is beneficial to diffusion of reactants and exposure of active sites, so that the activity and the stability of a molybdenum carbide catalyst are improved. The preparation method is advanced in process, low in cost, easy for getting raw materials, reasonable in match ratio, and stable in products, and is an advanced method for preparing the ordered mesopore molybdenum carbide.