927results about How to "Prevent sintering" patented technology

The composite oxide and the composite oxide carrier are manufactured by the precursor forming step and firing step. The composite oxide catalyst is obtained by preparing a composite of catalytic components simultaneously with the formation of the precursor of composite oxide in the step of forming the precursor of composite oxide. The composite oxide and the composite oxide carrier are composed of a composite oxide in which at least one of cerium and zirconium, and aluminium disperse with extremely high homogeneity. With this structure, the heat resistance of the carrier is improved and consequently, enlargement of particles of the composite oxide defining the carrier, and sintering of adjacent particles of the composite oxide can be restrained, whereby the catalyst using the composite oxide carrier in accordance with the present invention is excellent in heat resistance.

The invention relates to a continuous reaction process flow for producing ethylene glycol and 1, 2-propylene glycol through continuous hydrocrackin of sugars and provides a method for producing the ethylene glycol and the 1,2-propylene glycol through continuous hydrocrackin of sugars. In the process flow, sugars (comprising one or more than two of sugar, glucose, fructose, xylose, soluble xylo-oligosaccharide and starch) are hydrocracked in the presence of a catalyst in a reactor and the hydrocracked product enters a separating system. Hydrogen gas in a gas phase is recycled by separating and recovering; a liquid phase product partially reflows to the reactor and other liquid phase products are refined and separated to form the ethylene glycol, the propylene glycol and other polyhydric alcohols; and concentrated soluble catalyst components in the refined and separated residual component liquid phase are partially returned to the reactor.

A catalyst 1 has a heat-resistant support 2 selected from among Al2O3, SiO2, ZrO2, and TiO2, and a first metal 4 supported on an outer surface of the support 2, and included by an inclusion material 3 containing a component of the support 2.

The invention discloses a Bi2Te3 thin-piece / graphene composite material. The Bi2Te3 thin-piece / graphene composite material consists of a micron-sized Bi2Te3 thin sheet and graphene. Due to the actions of dispersion, bearing and isolation of the graphene, the sintering of the micron-sized Bi2Te3 thin sheet in the heat-treatment process can be effectively prevented for maintaining effective scattering of the crystal boundary to phonons, and the great significance for improving the thermoelectric properties of the Bi2Te3 material is embodied. The composite material can be used as a thermoelectric material. The invention also discloses a preparation method of the composite material by a one-step hydrothermal method or a one-step solvothermal method, and has the advantages of simple process, low cost, short period and low energy consumption and the like.

The invention relates to a continuous reaction process for producing ethylene glycol and 1,2-propanediol by catalytic hydrocracking sugar conversion, and provides a method for producing ethylene glycol and 1,2-propanediol by continuous hydrogenation cracking sugar conversion. During this process, sugars (including one or more of sucrose, glucose, fructose, xylose, soluble xylooligosaccharides, and starch) are hydrocracked by catalysts in the reactor and then enter the separation system. The hydrogen in the gas phase is separated and recovered for recycling; part of the liquid phase product is returned to the reactor, and the rest of the liquid phase product is refined to separate ethylene glycol, propylene glycol, and other polyols; it exists in the remaining heavy components after refining and separation. Concentrate in the liquid phase The soluble catalyst components are partially recycled back to the reactor.

The invention relates to a palladium carbon catalyst which comprises the following components: (1) nanometer TiO2-modified active carbons are used as composite carriers; (2) Pd nanometer particles are used as active components, wherein the strong interaction between metals and the carriers exists in the active components and TiO2 on the composite carriers to form a Pd@TiO2 structure so as to form structural Pd@TiO2 / active carbons of the catalyst.

Variation of the amount of power to be produced by a fuel cell unit is limited in accordance with a relationship between an output voltage of the full cell unit and an oxidization-reduction potential of catalyst of a fuel cell of the fuel cell unit. The amount of power to be used to charge or discharged from a battery is then corrected according to the limited variation of the amount of power to be produced by the fuel cell unit 40, so as to meet the required system power output.

The invention discloses an agglomeration method for iron containing dust slime of iron and steel plants; according to the method, the iron containing dust slime is shunted independently, is briquetted, is mixed with other iron ore powder, flux and coke powder, and then is sintered on the basis of the traditional technology. The agglomeration method comprises the following detailed steps of: 1), firstly, mixing the iron containing dust slime with composite binder, mixing uniformly, briquetting, so as to obtain dust slime briquette; 2), mixing the dust slime briquette with other iron ore powder, flux and coke powder, pelletizing, so as to obtain sintered mixture material; and 3), distributing the sintered mixture material by adopting the existing sintering method, igniting, sintering, cooling, granulating, finally the finished product of sintered ore is obtained. Compared with the traditional method of directly returning, sintering and mixing the dust slime, by adopting the agglomeration method, the ratio of the iron containing dust slime in the mixture material is greatly improved, and in addition, the sintered product quality index is improved. By adopting the agglomeration method, the problem on large-scale use of the iron containing dust slime of iron and steel plants is effectively solved, and the agglomeration method is beneficial for industrial production.

A preparation method for a Cu-based hydrogenation catalyst comprises the following steps: dissolving soluble copper salt into water, then adding a carrier into the solution, and uniformly loading a copper precursor on the surface of the carrier to obtain a precursor sample; mixing the precursor sample and ethanol to form a suspending liquid, coating the suspending liquid on the surface of a glass sheet, impulsing polyisocyanate into an MLD reaction cavity, then impulsing an M precursor to be subjected to monomolecular layer reaction on the sample surface in sequence to obtain a hybrid membrane coated copper precursor compound; conducting heat treatment on the compound in air to obtain a nanometer CuO-MOx compound, and then conducting reduction in the reducing atmosphere to obtain the Cu-MOx interface catalyst. The preparation method has the advantage that the Cu-MOx interface structure can be regulated and controlled.

The invention provides a perovskite type methane combustion catalyst as well as a preparation method and application thereof. The catalyst comprises an active component and a carrier, wherein the active component has a general formula: Al-xA'xB1-yB'yO3; in the formula, A is a rare earth metal element; A' is an alkaline earth metal element; B and B' represent transition metal elements; x is more than or equal to 0 but less than or equal to 0.9; y is more than or equal to 0 but less than or equal to 0.9; the carrier consists of spherical aluminum oxide of at least two crystal phases in delta-Al2O3, theta-Al2O3 or alpha-Al2O3, The aluminum oxide carrier has larger specific surface area, so that the loading capacity of the active component on the carrier can be improved; meanwhile, the uniform dispersion of the active component is facilitated, so that the sintered agglomeration of the active component is prevented, and the service life of the catalyst is prolonged; in addition, the catalyst provided by the invention is good in activity, and the selectivity of the reaction of methane and oxygen for CO2 is high; the perovskite type methane combustion catalyst has the advantages of being low in initiation temperature, high in combustion efficiency, good in mass transfer and heat transfer performance, and the like.

The invention relates to a catalyst for converting aromatic hydrocarbon from alcohol ether, and a preparation method and application method thereof. The catalyst is composed of molecular sieve, metal component, structural reinforcer and stability assistant. The preparation method comprises the following steps: preparing the molecular sieve, metal component, structural reinforcer and stability assistant into composite granules, treating with steam, impregnating the metal component and stability assistant, and repeating the steam treatment and impregnation many times to load the required metal component and stability assistant component in batches. The application method comprises the following step: reacting raw materials alcohol and ether at 350-550 DEG C under the pressure of 0-3 MPa, wherein the weight hourly space velocity of the reaction raw materials is 0.1-20 h<-1>. The catalyst provided by the invention can effectively reduce metal component loss in a high-temperature hydrothermal environment, and avoids metal sintering due to excessive loading of metal component at one time since the metal component dispersity is good.

A catalyst for purifying exhaust gases includes a support substrate, and a catalytic loading layer. The support substrate demarcates an exhaust-gas flow passage, an exhaust-gas inlet end and an exhaust-gas outlet end, and has an overall length between the exhaust-gas inlet end and the exhaust-gas outlet end. The catalytic loading layer is formed on a surface of the exhaust-gas flow passage, and is composed of a porous oxide support and a noble metal. The catalytic loading layer includes a coexistence area, and a rhodium area. The coexistence area occupies the overall length of the support substrate by a factor of 4 / 10 or less from the exhaust-gas inlet end, and is composed of rhodium and platinum loaded thereon. The rhodium area is formed toward the exhaust-gas outlet end from the coexistence area, and is composed of rhodium loaded uniformly thereon in a flow direction of the exhaust gases.

The invention discloses a composite material 3d printing method realized by photocuring-jetting nano ink, and the method comprises the following steps: preparing the nano ink; by means of micro-droplet jetting, jetting the nano-ink by an ink-jet print head; dividing three-dimension modeling into a plurality of two-dimension graphs, and calculating the print time for each graph; according to the print time for each graph, turning on an ultraviolet light source in a fixed time, monitoring the temperature of curing regions in real time by a temperature sensor, monitoring the curing moulding status of nano-particle ink in printing regions, and turning off the ultraviolet light source after curing is finished; and performing printing layer by layer, and performing curing layer by layer, so as to finish product printing. The method is suitable for printing ceramics, glass, nylon or plastic products; by using the ultraviolet light for curing moulding, the technical problems in an existing 3D printing technology on narrow range of material choice, poor moulding precision, small moulding size, slow moulding speed and the like are solved. The invention also discloses a micro-droplet-jetting 3d printer which is suitable for 3D printing in the above method.

The invention discloses a method for casting a valve body of a flat gate valve, and belongs to the technical field of valve body casting processes. The method is technically characterized in that a valve body cavity is vertically formed between a sand mold and a sand core; a plurality of valve body heat preserving risers are uniformly arranged at the open end of the valve body through the sand mold; a flange heat preserving riser is arranged at the upper end of a flange plate on each of two sides; a first external chill is arranged at the lower end of each flange plate; a plurality of second external chills are uniformly arranged at the periphery of a valve belly below the middle line of a flange; a third external chill is arranged on the outer bottom surface of the blind end of a main body of the valve body; process supplementary ion is arranged in an inner hole of the flange plate on each of the two sides; a fourth external chill is arranged on each of two end surfaces of a valve seat table in an inner cavity of the valve body. Therefore, the probability of occurrence of casting impurities and pore defects is reduced by using a vertical pouring method, gravity feeding is easy to implement so as to be matched with the chilling action of each external chill, and castings can be fed in sequence, so that the internal quality of the castings is well improved.

The present invention relates to the efficient clean utilization of marsh gas and is especially one new kind of catalyst for reforming methane-CO2 to produce synthetic gas. The present invention is one green process to utilize marsh gas with methane and CO2 as main components to produce synthetic gas via reformation. The present invention is significant for sustained supply of power source and environment protection.