The invention relates to the field of preparation and application of two-dimensional materials, in particular to a method for effectively preparing a high-orientation and high-compactness two-dimensional material thin film. The method comprises the following steps: taking a circular tube with a smooth inner surface as a casting die; pouring a solution which contains a two-dimensional material intothe die when the die rotates in the peripheral direction at high speed; uniformly coating the inner surface of the die with the solution by using centrifugal force; forming shear force which drives the two-dimensional material to be regularly arranged layer by layer in an oriented manner in the peripheral direction in the solution in a centrifugal rotating process; and meanwhile, driving the two-dimensional material to be accumulated at high compactness by the centrifugal force so as to obtain the two-dimensional material thin film with high orientation and high compactness. The method is suitable for preparing various two-dimensional materials such as graphene, and composite thin films and laminated heterostructure thin films of the two-dimensional materials; electric property, heat property, mechanical property and the like of the thin film are greatly improved; and the method is used in the field of high-performance electric conduction / heat-conduction thin films, heat management materials, high-strength thin films, electronic / optoelectronic devices, compact energy storage, gas / ion separating films, proton transmitting films and the like.