The invention discloses a fluorenyl donor-
acceptor H type molecular material with high
fluorescence quantum efficiency and a preparation method and applications thereof. The bridging
electron acceptor unit of Friedel-Crafts reactions of
tertiary alcohol of a halogenated
aryl group is taken as the bridging group; the
aryl group is coupled to a chromophoric group through the
halogen to form the H type molecular material, the
structural formula of the molecular material is shown in the description, in the
structural formula, Ar1, Ar2, Ar3, Ar4, and Ar11 individually represent an
aryl group, Ar11 is an
electron acceptor unit, Ar5, Ar6, Ar7, Ar8, Ar9, and Ar10 individually represent an aryl group or a non-aryl group; and SG1, SG2, SG3, and SG4 represent an aryl group or a non-aryl group. The synthesis of the material is in a modularization mode, the selection range of
electron acceptor units is wide, the reaction steps are simple, the conditions are mild, and moreover, the molecular material has high
thermal stability, electrochemical stability, and
optical stability, and is an organic optoelectronic functional material with a wide application prospect.