The invention belongs to the field of preparation of composite
titanium dioxide, and relates to a preparation method of composite
titanium dioxide. The preparation method comprises the following steps: mixing and stirring
oxalic acid, absolute ethyl
alcohol and deionized water to obtain a stirred solution; mixing tetrabutyl
titanate and absolute ethyl
alcohol to obtain a
mixed solution; adding themixed solution in the stirred solution, standing, placing precipitates in a water bath for
evaporation, and
drying to obtain a dried material; adding
hydrochloric acid, mixing, standing, and filtering to obtain a filter residue, placing the filter residue in hot water, stirring, filtering to obtain a filter residue a,
grinding, sieving to obtain a sieved material, adding a
coupling agent and an
ethanol solution, mixing, oscillating, performing suction filtering,
drying,
grinding to obtain a ground material, adding absolute ethyl
alcohol and deionized water, mixing, stirring, adding a flourescent brightener, centrifuging, and performing
vacuum drying on precipitates to obtain a dried material a; and mixing modified
calcium carbonate, a dispersant,
sodium dodecyl
benzene sulfonate and water,
grinding, adding the dried material a, grinding, dehydrating,
drying, and crushing to obtain the composite
titanium dioxide.