The invention discloses a preparation method of positive material for
cobalt nitride /
porous carbon plate / carbon cloth self-supported
lithium-
sulfur battery, belongs to the field of
electrochemical energy storage of
new energy material. The preparation method comprises the following steps: using a
metal organic skeleton compound as a precursor, carbon cloth as a carrier, a
metal organic skeleton compound vertically and uniformly grow on the flexible carbon cloth, performing treatment such as
carbonization and nitridation to obtain
cobalt nitride particles embedded
nano carbon plate. The porousnano carbon plate is loaded on the
fiber surface of the carbon cloth in a
vertical growth manner and shows good electrochemical performance as the positive material of the
lithium-
sulfur battery. Thecompound self-supported
lithium-
sulfur battery positive material disclosed by the invention has developed pore structure, greatly shortens the
diffusion distance of substances such as ions, electronsand
electrolyte; the
cobalt nitride particles with
nano size adsorbs and catalytically converts the
polysulfide, so the
dissolution and shuttling of the
polysulfide are effectively inhabited, the electric
conductivity of the material is greatly improved by the carbon cloth and the application prospect is wide.