The present disclosure relates to a reaction adhesive and a preparation method thereof, the reaction adhesive comprises 90# asphalt, 10# asphalt, rubber oil, SBS, PE, styrene butadiene rubber, petroleum resin, an asphalt modifier, a silane coupling agent, stone powder and silica. By adding of the silane coupling agent and the silica, the asphalt is modified, and by modifying of the characteristicsof the asphalt, when the reaction adhesive is applied, lean concrete grout is first used for paving, and then the reaction adhesive is laid on the surface of cement. During the solidification of thecement, hydration heat is formed, free silica molecules are released, the free silica molecules can be combined with active silica molecules released in the reaction adhesive, chemical bonds are formed in capillary pores of a cement base layer for crosslinking, and the bond strength is improved.