1105 results about "Polyethylene glycol monomethyl ether" patented technology

The invention relates to a polyvinyl alcohol-polypeptide-polyethylene glycol graft copolymer and a preparation method thereof. The molecular weight of polyvinyl alcohol is 20,000-80,000; the molecular weight of a polypeptide chain segment is 4,000-8,000; and the molecular weight of a polyethylene glycol chain segment is 350-750. The preparation method comprises the following steps of: (1) synthesizing a polypeptide homopolymer which contains an end-NCO radical: adding the polypeptide homopolymer, diisocyanate, dibutyltin dilaurate serving as a catalyst and dimethyl sulfoxide serving as a solvent into a reactor for reacting to obtain a target product; (2) synthesizing a polyvinyl alcohol-polypeptide graft copolymer: adding the polypeptide homopolymer which contains the end-NCO radical, the solvent and the catalyst into the reactor, adding polyvinyl alcohol and reacting to obtain a target product; and (3) synthesizing a polyvinyl alcohol-polypeptide-polyethylene glycol graft copolymer: adding the polyvinyl alcohol-polypeptide graft copolymer, the solvent and the catalyst into a drying reactor, adding polyethylene glycol monomethyl ether and reacting to obtain a target product.

The invention relates to a preparation method for a chitosan natural polymer modified crude oil desalting demulsifier. The method comprises the following steps: 1) modifying polyethylene glycol monomethyl ether by halogenating; 2) preparing glycidyl dimethyl alkyl ammonium chloride; 3) preparing quaternized carboxy alkyl chitosan; 4) causing the modified polyethylene glycol monomethyl ether to react with the quaternized carboxy alkyl chitosan, thereby obtaining a target product, polyethylene glycol monomethyl ether grafted quaternized carboxy alkyl chitosan. According to the invention, the chitosan natural high-molecular compound is taken as the raw material and has the advantages of wide resource, naturality, non-toxicity, sustainability, excellent biological compatibility of products, degradability, and the like. The demulsifier prepared according to the invention has excellent demulsification dewatering effect; the molecule of the demulsifier contains a large amount of carboxy alkyl groups and quaternary ammonium salt groups and the electronegative ions, including metal cation, naphthene acid radicals, and surfaces are electronegative grains and have strong combining capacity, so that the demulsifier has the capacities of demulsifying while removing oil-soluble salt.

The invention relates to a preparation method of a polyether-grafted chitosan derivative crude oil desalting demulsifier. The preparation method comprises the following specific steps: firstly, performing formylation modification on polyethylene glycol monoethylether; secondly, preparing glycidyl dimethyl alkyl ammonium chloride; thirdly, preparing quaternarization carboxyalkyl chitosan; fourthly, enabling formylation modified polyethylene glycol monoethylether to react with carboxy alkyl chitosan to obtain the polyether-grafted chitosan derivative crude oil desalting demulsifier. The polyether-grafted chitosan derivative crude oil desalting demulsifier disclosed by the invention is prepared by taking chitosannatural polymeric compounds as raw materials, and has the advantages of wide sources, naturalness, no toxicity, sustainability, good biocompatibility of a product, degradability and the like. The prepared demulsifier is good in demulsifying and dehydrating effect; meanwhile, a demulsifying molecule contains a large amount of carboxyalkyl groups and quaternary ammonium salt groups which have strong combining capacity to metal cation, ions with negative electricity such as naphthenic acid radicals as well as particles of which the surfaces are electronegative, so the polyether-grafted chitosan derivative crude oil desalting demulsifier has capacity of removing oil-soluble salts while demulsifying.

The invention discloses an ester slump retaining type polycarboxylate water reducer and a preparation method thereof. The ester slump retaining type polycarboxylate water reducer is made from raw materials comprising the following components in parts by weight: 100 parts of esterified macromer solution by weight, 2-6 parts of unsaturated monomer by weight, 1.5-4 parts of unsaturated phosphate by weight, 1-4 parts of an oxidizing agent by weight, 0.9-3.5 parts of a reducing agent by weight, 1-3 parts of a chain transfer agent by weight, 108 parts of water by weight, and 20 parts of industrial sodium hydroxide solution by weight, wherein the concentration of the esterified macromer solution is 75-85%, and a solute thereof is the mixture of methoxy polyethylene glycol methacrylate, crosslinking monomers triethylene glycol dmethylacrglate and methyl methacrylate; the unsaturated monomer is methacrylic acid, acrylic acid, hydroxyethyl methylacrylate, hydroxyethyl acrylate, hydroxypropyl methacrylate or hydroxypropyl acrylate. The ester slump retaining type polycarboxylate water reducer provided by the invention has good slump retaining performance, good dispersibility, good adaptability and low cost.

The invention relates to a synthesis method of a crude oil desalting demulsifying agent. The method specifically includes the steps of firstly, conducting p-nitrophenyl ester modification on methoxypolyethylene glycol; secondly, preparing glycidyl dimethyl alkyl ammonium chloride; thirdly, preparing quaternized carboxy alkyl chitosan; fourthly, making the modified methoxypolyethylene glycol react with quaternized carboxy alkyl chitosan to obtain a product, namely polyethylene glycol questin grafted quaternized carboxy alkyl chitosan. A chitosan type natural high-molecular compound serves as the raw material and has the advantages of being wide in resource, natural, free of toxin, sustainable, good in product biocompatibility, degradable and the like; The prepared demulsifying agent is good in demulsifying dewatering effect; meanwhile, due to the fact that lots of carboxy alkyl groups and quaternary ammonium salt groups are contained in demulsifying agent molecules and have strong binding capacity with metal cations, naphthenic acid radicals and other ions with negative charges and particles with surface electronegativity, the oil-soluble salt removing capacity is achieved during demulsifying.

The invention relates to a water reducing agent with high efficiency used in polycarboxylate concrete and a synthetic method thereof, which is characterized in that: plyethylene glycol methylacrylic acid single armor esterification (MPEGMA) macromonomer synthesized by (methyl) acrylic and polyethylene glycol monomethyl ether added with catalyst and other (methyl) acrylic or (methyl) allyl sodium monomer are grafted and copolymerizated to synthesize into binary or polybasic copolymer comprising carboxyl, sulfonic group and polyoxyethylene chain side under the effect of initiator and chain transfer agent. The products synthetically prepared by the invention has the advantages of high water reducing ratio, low chlorine and low alkali; the cement mixture is high in fluidity and good in mixability, and can restrain slump loss effectively, when 0.7 to 1.2 percent by weight of cement material is added. The water reducing agent with high efficiency used in polycarboxylate concrete is simple in technology, easy in control of reaction condition and reasonable in cost, does not pollute environment, and can be used as the important component of high performance concrete, marine concrete, nuclear power station concrete and anticorrosion concrete and is widely used in the field of industry, civil building, water conservancy, road traffic and nuclear power engineering.

The invention relates to a method for preparing comb-shaped polymer crude oil desalting demulsifier. The method comprises the following steps: (1) performing acrylatioed modification on methoxy polyethylene glycol; (2) preparing glycidyl dimethyl alkyl ammonium chloride; (3) preparing quaternized carboxyalkyl chitosan; (4) reacting modified methoxy polyethylene glycol with quaternized carboxyalkyl chitosan to obtain the target product demulsifier. The demulsifier is prepared by using chitosan naturalpolymer compounds as raw materials, and has the advantages of wide source, nature, no toxicity, sustainability, good product biocompatibility, degradability and the like. The prepared demulsifier has good demulsification and dehydration effect since the molecular structure is a comb-shaped polymer formed by simultaneously grafting a plurality of linear branched chains on a main chain, and has a strong binding capability on metal cations, naphthenate radicals and other negatively charged ions and particles which are electronegative on surfaces since a great amount of carboxyalkyl groups and quaternary ammonium salt groups on the molecules. Therefore, the demulsifier has capabilities of demulsifying and removing oil-soluble salt.

The invention relates to a method for functionalizing a polymer on the surface of nano graphene oxide. The method comprises the following specific steps: preparing graphene oxide from natural graphite powder by an improved Hummers method, utilizing methoxy polyethylene glycol and pyrene acids to carry out esterification to generate polyethylene glycol with pyrenyl as the terminal group, and finally grafting the polyethylene glycol with pyrenyl as the terminal group on the surface of graphene oxide through pi-pi interaction between pyrenyl and the surface of graphene oxide, thus obtaining the graphene oxide with the functionalized polymer on the surface. The solubility of the prepared graphene oxide with the functionalized polymer on the surface is greatly improved. The method has the following advantages: a main process adopted in the experiment is as follows: a polymer with a complex structure is designed and prepared in advance and then is grafted on the graphene oxide, and the grafting reaction can be carried out at normal temperature and pressure, so the whole experiment process is very simple and convenient. Therefore, the study provides a direct method for modifying the graphene oxide and preparing the functionalized graphene oxide-polymer complex to form a new inorganic-organic hybrid material, thereby promoting the development and application of graphene oxide-based materials.

The invention discloses an amphiphilic polymer pigment wetting dispersant for a water-based coating and a preparation method thereof, and the preparation method comprises the following steps: polymerizing macromer or polyethylene glycol methyl ether methacrylate macromer with polymerizable double bonds with one or two hydrophobic (methyl) polyacrylate monomers in the presence of ARGET ATRP (activators regenerated by electron transfer-atom transfer radical polymerization) to obtain a comb-shaped polymer, and further introducing an anchoring functional group in the comb-shaped polymer for preparing the solid wetting dispersant; or polymerizing the macromer or the polyethylene glycol methyl ether methacrylate macromer with the polymerizable double bonds with the (methyl) polyacrylate monomer with the anchoring functional group in the presence of ARGET ATRP to obtain the comb-shaped polymer which is the solid wetting dispersant. By using the preparation method, the cost can be greatly reduced, the efficiency is improved, and the performances of the product can be greatly improved. The obtained wetting dispersant has good dispersion effect and bright color, and the stability of a dispersion system is high.

The invention discloses a preparation method of a polylactic acid glycollic acid-polypeptide-polyethylene glycol diblock-grafted copolymer. The method comprises the following steps: 1, adding a polypeptide homopolymer, diisocyanate, a catalyst and a solvent to a dry reactor, reacting in an inert atmosphere under stirring at 50-55DEG C for 40-60min, and removing excess diisocyanate through a dialysis process to obtain a terminal -NCO group-containing polypeptide homopolymer; 2, adding the terminal -NCO group-containing polypeptide homopolymer, the catalyst and the solvent to the dry reactor, adding polylactic acid glycollic acid monolauryl ether, reacting in an inert atmosphere under stirring at 50-55DEG C for 50-70min to obtain a polylactic acid glycollic acid-polypeptide diblock copolymer; and 3, adding the polylactic acid glycollic acid-polypeptide diblock copolymer, a catalyst and the solvent to the dry reactor, adding polyethylene glycol monomethyl ether, and reacting in an inert atmosphere under stirring at 55-58DEG C for 2-4d to obtain the polylactic acid glycollic acid-polypeptide-polyethylene glycol diblock-grafted copolymer. The preparation method is simple.

The invention relates to nonionic self-emulsifying waterborne epoxy resin and a preparation method and application thereof. The nonionic self-emulsifying waterborne epoxy resin is prepared by the following steps of: mixing 15 to 55 parts of diisocyanate, 70 to 150 parts of polyethylene glycol monoethylether and 4 to 10 parts of an acetyl chloride acetone solution together in parts by mass, and then reacting at 35 to 65 DEG C for 1 to 5 hours; and adding 100 to 300 parts of epoxy resin into the mixed system, adding 0.5 to 5 parts of a catalyst into the mixed system, and reacting at 40 to 85 DEG C for 1 to 5 hours after mixing. The invention also provides a method for preparing the waterborne epoxy resin into a waterborne epoxy varnish. According to the nonionic self-emulsifying waterborne epoxy resin, after a polyethylene glycol monomethyl ether chain is introduced into a segment, alkaline water or volatile organic weak monoacid is not needed to be added, so that the application range of an emulsion is wide, and the emulsion is easy to prepare; and after crosslinking curing of the emulsion, the network chain molecular weight is improved, the crosslinking density is reduced, and a formed coating film is toughened.

The invention belongs to the filed of biopolymer material synthesis, relates to a preparation method of a polyethylene glycol monomethyl ether-dl-polylactic acid block copolymer. The method includes the following steps of: adding a solvent with volume more than 3-6 times of total weight of reagents into a dried reactor, adding stannous octoate as a catalyst, and polyethylene glycol monomethyl ether and dl-lactide whose weight ratio is in the range of 65:35 to 20:80, introducing nitrogen, removing air, then heating and reacting, pouring a product into a compound of petroleum ether-carbon dioxide dry ice, simultaneously, violently stirring, obtaining the needed product after drying a white filtered solid in a vacuum drying oven. The new-type solvent is used in the invention, and a novel purification processing method is provided and is simple and easily controlled, the copolymer with a certain amount of molecular weight can be synthesized according to the specified requirement, and the requirement of further producing a pharmaceutical preparation is met.

The invention relates to an ultra-hydrophobic nanometer SiO2/high polymer complex film and a preparation method thereof. The method comprises the following steps: carrying out an ester exchange reaction of MPEG and PEDS to synthesize an MPEG-g-PEDS graft polymer; adding a certain amount of water to the MPEG-g-PEDS graft polymer for a solation-gelation reaction; then, grinding and pulverizing gel, dispersing the gel powder as a filling to a high polymer solution; and coating the solution on a basal material and drying to form a film. The complex film is soaked in a water/alcohol solution, uses a surface dressing agent for the self assembly of surface molecules, uses normal hexane to wash away residual liquid and is dried so as to obtain the ultra-hydrophobic nanometer SiO2/high polymer complex film.

The invention belongs to the field of medical technology, relates to a high-stability polyethylene glycol-polyester polymer and an application thereof, and particularly relates to an amphiphilic block copolymer having a hydrophilic block and a hydrophobic block with terminal hydroxyl, wherein the terminal hydroxyl of the hydrophobic block is replaced by a cholic acid group. The hydrophilic A block is any one of ethylene glycol monomethyl ether, polyethylene glycol, polyvinyl alcohol and polyvinylpyrrolidone; the hydrophobic B block is any one of polylactide, polylactide-co-glycolide, polyglycollide, polycaprolactone, polylactide-co-caprolactone, polyglycollide-co-caprolactone and polylactide-co-glycolide-cocaprolactone. The polymer provided by the invention can spontaneously form high-stability micelle in a waterborne medium, and can be used as a carrier of various water-insoluble drugs.