The invention relates to a method for preparing an electrochemical nano
dot array electrode by using an ultra-long
nanowire, and belongs to the technical field of nano
electrode preparation. In orderto simply, efficiently and repeatedly prepare a nano
dot array electrode, the method includes: pouring PDMS on a
silicon template containing a micron groove array; pouring resin on the cured PDMS moldto obtain a resin block with a micron groove array; and depositing a layer of
metal film on the resin block, performing embedding with resin, carrying out nano
slicing, transferring a single resin sheet containing the
nanowire array or a plurality of resin sheets containing the
nanowire array alternately stacked with the hollow resin sheets to the substrate, lapping and fixing the lead on the surface of the
nanowire array, adding resin for packaging, and trimming and
polishing one end of the non-lapped wire to obtain the nano-
dot array electrode. According to the invention, the overlapping ofthe
capacitance and the
diffusion layer of the adjacent electrode is avoided, and the new clean nano dot array can be obtained by re-trimming and
polishing the end surface of the nanowire, so that the long-term repeated use of the nano dot array electrode is facilitated.