The invention discloses terylene afterprocessing oil agent for preventing xanthochromia, which is mainly formed by smoothing agent, emulsifying agent, cleaning agent and addition agent, and is characterized in that weight percentage of each component is smoothing agent 85%-90%, emulsifying agent 5%-10%, cleaning agent 2%-4% and addition agent 1%-1.5%. According to the weight percentage of each component, the method for preparation is that firstly packing emulsifying agent and cleaning agent with precise measure into an autoclave to heat from 50 DEG C to 80 DEG C, secondly packing smoothing agent into the autoclave to mix for 40-60 min, thirdly charging addition agent to mix homogeneously, and then cooling, filtering and packaging. The terylene after-processing oil agent for preventing xanthochromia has the advantages that interfacial force is low, permeability and diffusibility are good, the applying oil process is quick and homogeneous, the volume for applying oil is easy to be controlled, after-processing is smooth and has no imperfect effect on weave process and causticity component, and the invention is easy for washing and not influence on coloration and topical finish, and is good in cohesion property and forming of silk can, high in oil film strength, and strong in ability of preventing xanthochromia, thereby being favorable to store silks.