The invention discloses a CPVC resin preparation method by using a water phase suspension method, and belongs to the technical field of chemical raw materials. The preparation method is characterized in that the preparation steps comprise uniformly spraying a polyhydric
alcohol aqueous solution on the surface of PVC resin by using a spraying device; then uniformly suspending the PVC resin which is sprayed with the polyhydric
alcohol into a deionized water polymerizing kettle; adding an initiating agent and introducing
chlorine gas for chlorination reaction; after the finish of introducing the
chlorine gas, adding a chain terminating agent to stop the reaction; and performing washing and
drying to obtain a product. The preparation method provided by the invention aims at the characteristics of CPVC resin production process by using the water phase suspension method, gives up the use of dispersing agents, first performs surface activating treatment on the PVC resin by using the polyhydric
alcohol, and then performs the chlorination reaction. The prepared CPVC resin has high
chlorine content and aging whiteness, has a good stability property, is easy to plasticize uniformly, and has good processability. As a chemical
raw material, the CPVC resin can be widely used in preparing various products such as tubular materials, board materials, sectional materials, sheet materials, injection molded parts, foam materials and the like.