142 results about "DIAPHENYLSULFONE" patented technology

A solvent cast film comprises a polyimide comprising structural units derived from polymerization of a dianhydride component comprising a dianhydride selected from the group consisting of 3,4′-oxydiphthalic dianhydride, 3,3′-oxydiphthalic dianhydride, 4,4′-oxydiphthalic dianhydride, and combinations thereof, with a diamine component comprising 4,4′-diaminodiphenylsulfone; wherein the polyimide has a glass transition temperature from 190° C. to 400° C.; and wherein the film has a coefficient of thermal expansion of less than 60 ppm/° C., a thickness from 0.1 to 250 micrometers, endless than 5% residual solvent by weight.

An epoxy resin composition having components (A), (B), (C), and (D), wherein the epoxy resin composition has a viscosity at 40° C. of about 1×10³ to about 1×10⁴ Pa·s, a curing start temperature of about 90 to about 110° C., and a minimum viscosity at the curing start temperature of about 2 to about 20 Pa·s, wherein the components (A), (B), (C), and (D) are as follows: (A) About 60 weight parts or more of a tetraglycidyl amine type epoxy resin per 100 weight parts of the epoxy resin blend; (B) Dicyandiamide; (C) Diaminodiphenyl sulfone and (D) Urea compound.

The invention discloses epoxy resin silica sol which is characterized by being prepared from the following components: epoxy resin, organic silicon, silane coupling agent, organic solvent and ammonia water at a molar ratio of 1:(0.1-2):(0.01-2):(0.9-18):(0.001-0.06). The invention also discloses a preparation method of the epoxy resin silica sol. The invention also discloses an epoxy resin organic-inorganic nano hybrid material adopting the epoxy resin silica sol, which is characterized in that the epoxy resin curing agent is one or more of methylhexahydrophthalic anhydride, methylhexahydrophthalic anhydride acid, 4,4-diaminodiphenylmethane and 4,4-diamino diphenyl sulfone. The invention also discloses a preparation method of the epoxy resin organic-inorganic nano hybrid material. The product provided by the invention has excellent insulating property, and the method is stable and efficient.

The invention relates to a preparation method of a polysulfone resin material with low cyclic dimer content, belonging to the technical field of polysulfone resin. The preparation method of the polysulfone resin material with the low cyclic dimer content in the invention comprises the following steps: with a phenolic substance and a part of 4,4'-dichlorodiphenyl sulfone used as reaction monomers,adding an aprotic exchange solvent, an acid-binding agent and a water-carrying agent, adding an end-capping reagent and the other part of 4,4'-dichlorodiphenyl sulfone at a constant speed in a water-carrying reaction period, then evaporating out the water-carrying agent, continuing to conduct polymerization, and then carrying out post-treatment to obtain the polysulfone resin material with the lowcyclic dimer content. The target polysulfone resin material prepared by using the method is high in purity and stable in performance.

According to one embodiment of the present invention, an epoxy resin composition comprises: a resin including an epoxy compound, triethylenediamine, diphenylphosphine and/or tetraphenylborate; a curing agent including diaminodiphenylsulfone, ethylenediamine, diaminopropane, methanediamine, phenylenediamine and/or triethanolamine; and an inorganic filler, wherein the inorganic filler includes at least two alumina (Al₂O₃) groups classified by particle size.

The present invention provides an economic and environmentally friendly method for the preparation of polymer grade 4,4'-dichlorodiphenyl sulfone which is substantially free of 2,4' and 3,4'-isomers of dichlorodiphenyl sulfone with yield of over 90%, with substantially reduced reaction times without the use of impregnated catalysts. Further no toxic byproducts such as dimethyl pyrosulfate are formed thereby reducing the load on effluent treatment with the added advantage of substantially recycling the reactants and byproducts. Further the present invention discloses a process is disclosed in which isomeric mixture of 4,4'-, 3,4'-, and 2,4'-dichlorodiphenyl sulfone produced during the preparation of 4,4'-dichlorodiphenyl sulfone is converted to value added products such as diphenyl sulfone, 2,4'-dihydroxydiphenyl sulfone, 4,4'-dihydroxydiphenyl sulfone and 2-aminodiphenyl sulfone.

The invention relates to a preparation method of tetraglycidyl-3,3'-diethyl-4,4'-diaminodiphenyl-methane, which comprises the following steps: mixing 1 mol of 1,3,3'-diethyl-4,4'-diaminodiphenyl-methane, 5-10 mol of epoxy chloropropane, 0.5-1.0 percent by weight of Alpha-halogenated carboxylate catalyst (based on the weight of the 3,3'-diethyl-4,4'-diaminodiphenyl-methane), 70-85g of polyol and 40-50g of water in a reaction container, dissolving, and then raising the temperature to 50-70 DEG C, maintaining the temperature for 4-7h, continuously adding 320g of acetone and 373-412g of 30 percentby weight of sodium hydroxide water solution or 30 percent by weight of potassium carbonate or mixture of the 30 percent by weight of sodium hydroxide water solution and the 30 percent by weight of potassium carbonate for reacting for 3-5h at a temperature of 50-60 DEG C; adding 800-1,000ml of methylbenzene for extracting a target product, and evaporating the methylbenzene, wherein the product isa bit red liquid resin, the epoxy value of the resin is 0.70-0.74equivalent/100g, the viscosity 25 DEG C is 0.40-0.51Pa.s, the heat deflection temperature of the resin after being cured by 4,4'-diaminodiphenylsulfone is 182.1 DEG C, the Rockwell hardness E is 85, and the impaction modulus is 3.2 Gpa.

The present invention relates to a copper foil having a primer resin layer which improves the adhesive strength between a copper foil surface without roughening treatment and a substrate resin and a laminated sheet using the same and is characterized by using a polyimide represented by the following formula (1):

(wherein, R₁ represents a quadrivalent aromatic group which is a residual group of a dicarboxylic acid dianhydride ingredient (pyromellitic acid anhydride, 3,3′,4,4′-biphenyltetracarboxylic acid dianhydride, 3,3′,4,4′-benzophenontetracarboxylic acid dianhydride or 2,3,6,7-naphthalenetetracarboxylic acid dianhydride), R₂ represents a divalent aromatic group which is a residual group of a diamine ingredient (1,3-bis-(3-aminophenoxy)benzene, 3,3′-diamino-4,4′-dihydroxydiphenylsulfone or/and 4,4′-diamino-3,3′,5,5′-tetraethyldiphenylmethane), and n1 represents a repeating number) as a primer resin; and copper foils and laminated sheets having said polyimide layer as a primer have high adhesive strength and are suitable for flexible printed wiring boards.

The invention discloses a preparation method for catalytic synthesis of 4,4'-diaminostilbene. The preparation method comprises the following steps: with a superparamagnetic nanoparticle loaded ionic liquid as a catalyst, subjecting chlorobenzene and thionyl chloride to a Friedel-Crafts reaction under the action of the catalyst, after the reaction is completed, additionally adding a catalyst recovered by a magnetic field, pouring out a reaction solution, dropwise adding a saturated sodium bicarbonate solution into the reaction solution until the pH value of the solution is adjusted to be neutral, then carrying out stirring, filtering the material liquid while the material liquid is hot, cooling a filtrate to 0-5 DEG C for crystallizing, carrying out filtering so as to obtain 4,4'-dichlorodiphenyl sulfoxide, dissolving the 4,4'-dichlorodiphenyl sulfoxide into glacial acetic acid, adding hydrogen peroxide for an oxidation reaction, carrying out cooling after the reaction is finished, andcarrying out filtering so as to obtain 4,4'-dichlorodiphenyl sulfone. According to the invention, the chlorobenzene is used as a reaction raw material and a solvent; no solvent impurities are not mixed; meanwhile, simple process, low cost and few impurities are achieved; an obtained product is high in purity and has a content of 99.2% or above; the content of a 2,4'-isomer is smaller than 0.1%; the yield reaches 90% or above; and the preparation method provided by the invention is good in economic benefit and applicable to industrial production.

The invention discloses an environment-friendly fireproof coating, the coating is prepared from the following components in parts by weight: 10-20 parts of vinyl-modified hyperbranched polyphosphate,5-10 parts of acrylate-modified p-aminophenyl calixpyrrole, 50-70 parts of 1, 3-bis (oxiranylmethyl)-5-(2-propenyl)-1, 3, 5-triazine-2, 4, 6 (1H, 3H, 5H)-triketone/3, 3 '-diamino-4, 4'-difluorodiphenyl sulfone polycondensate, 0.5-1.5 parts of an initiator, 15-25 parts of an inorganic filler, 1-3 parts of a defoamer and 1-3 parts of a dispersant. The invention also provides a preparation method ofthe environment-friendly fireproof coating. The environment-friendly fireproof coating disclosed by the invention is good in comprehensive performance, remarkable in fireproof and flame-retardant effects, good in water resistance, decoration and storage stability, environment-friendly and pollution-free.

The invention belongs to the field of fluorescent probe preparation technology and application, and particularly relates to a fluorescent probe for rapidly identifying 2, 4, 6-trinitrophenol moleculesand a preparation method thereof. The structural formula of the fluorescent probe molecule L is shown in the specification, and the fluorescent probe molecule L is obtained by reacting 8-formyl-7-hydroxycoumarin with 3, 3'-diamino-4, 4'-dihydroxy diphenyl sulfone. The fluorescent probe disclosed by the invention has relatively good selectivity and visual color change on 2, 4, 6-trinitrophenol (TNP), the detection limit is 1.2*10<-7>mol/L, and the fluorescent probe has a very good application prospect.

The invention provides a preparation method of high-performance polysulfone resin. The preparation method includes adding 45-55 parts of 4,4-dichlorodiphenylsulfone, 35-40 parts of salt-forming agent, 80-100 parts of low boiling point organic solvent and 0.01-0.04 parts of 3-fluoro-4-chlorobenzophenone into the reactor, and then 20-60 parts of 4,4'- -dihydroxydiphenylsulfone or bisphenol, injecting nitrogen gas and heating until the temperature inside the reactor rises to 200-210 DEG C, maintaining reaction at constant temperature for 1 to 2 hours, and after the temperature rises to 240-260 DEG C for 4 to 7 hours, adding 0.09-0.16 parts of 3-fluoro-4-chloro benzophenone, reacting 10-20 minutes, then stopping reactor and treating the reactant to obtain high-performance polysulfone resin. The polysulfone resin prepared by the method has high molecular weight, good transparency and heat resistance.

The invention discloses an efficient polysulfone resin preparing method with microwaves as a heat source. The preparing method includes the steps that 4,4'-dichloro(di)phenyl sulfone and bisphenol A serve as initial raw materials, carbonate with the mole number two times that of the bisphenol A is added to serve as alkali, and the mixture is heated and reacted for 2 hours to 5 hours through a microwave reactor in high-boiling-point aprotic polar solvents; then the reaction liquid is slowly poured into deionized water, white fiber-shaped polymers are obtained, then the polymers are soaked for 5 hours to 10 hours under the 60-DEG-C-to-80-DEG-C condition, the process is repeated three times to five times, filtering and drying are carried out, and polysulfone resin is obtained through vacuum drying. By means of the preparing method, the reaction time is shortened to a great degree, energy consumption is reduced, the cost for the production technology is reduced accordingly, and the working efficiency is improved.