The present invention discloses a one-time surface treatment method for electrolysis copper foil. The process method comprises: 1, coursing solution preparation: carrying out mixing dissolving on cathode cooper, sulfuric acid and soft water to produce a copper sulfate solution, adding an additive A to the copper sulfate solution, completely mixing, and adding the obtained mixture to a coursing tank to be subjected to electroplating; 2, curing solution preparation: carrying out mixing dissolving on cathode cooper, sulfuric acid and soft water to produce a copper sulfate solution, and adding the copper sulfate solution to a curing tank to be subjected to electroplating; 3, zinc plating alloy solution preparation and a passivation treatment: respectively dissolving zinc sulfate, chromic anhydride and phosphoric acid, adding the zinc sulfate solution to a chromic acid and phosphoric acid mixed solution, adding an additive D solution to the obtained mixing solution in a dropwise manner while adjusting the pH value by using sodium hydroxide, completely mixing, and then adding the obtained mixture to a zinc plating alloy tank to be subjected to electroplating; and 4, spray coating of an adhesive: dissolving an adhesive in water, and carrying out cycle spray coating of the adhesive on the surface of copper foil. According to the present invention, the process is simple, the steps are less, passivation solution components are stable, and the treated electrolysis copper foil has excellent physical properties.