Stainless steel chemical pigmenting liquid and chemical pigmenting method
A chemical coloring and stainless steel technology, which is applied in metal material coating process, superimposed layer plating, coating, etc., can solve the problems of acidic chemical coloring uniformity and insufficient reproducibility of stainless steel, and achieve bright color and wear resistance Good performance and uniform color film
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Embodiment 1
[0022] Among the embodiment Fig. 1: implement as follows:
[0023] (1) Stainless steel surface pretreatment
[0024] The stainless steel test piece 6 is pre-treated by water washing, degreasing, water washing, polishing, water washing, activation, water washing, etc., to remove the dirt layer and oxide layer on the surface of the stainless steel.
[0025] (2) One-step treatment of coloring-hardening film
[0026] The pre-treated stainless steel test piece 6 is used as the cathode, immersed in the coloring solution 3, the formula of the coloring solution 3: concentrated H 2 SO 4 490g / L, CrO 3 250g / L, (NH 4 ) 6 Mo 7 o 24 4H 2 O 7.0g / L, ZnSO 4 5.0g / L, MnSO 4 4.0g / L, OP-10 6.0g / L, solution temperature 65°C, connect the two loops of coloring and potential measurement according to attached figure 1, use DC power supply 1, and control the current density at 6.3mA / dm 2 , Carry out chemical coloring with small electric current, wash with running water after coloring.
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Embodiment 2
[0033] (1) Stainless steel surface pretreatment
[0034] With embodiment 1.
[0035] (2) One-step treatment of coloring-hardening film
[0036] The pre-treated stainless steel test piece 6 is used as the cathode, immersed in the coloring solution 3, the formula of the coloring solution 3: concentrated H 2 SO 4 490g / L, CrO 3 250g / L, (NH 4 ) 6 Mo 7 o 24 4H 2 O 7.0g / L, ZnSO 4 5.0g / L, MnSO 4 4.0g / L, sodium dodecylbenzene sulfonate 6.0g / L, solution temperature 65°C, connect the two loops of coloring and potential measurement according to attached figure 1, use AC power supply 1, and control the current density at 5.2mA / dm 2 , Carry out chemical coloring with small electric current, wash with flowing water after coloring.
[0037] Potential difference / mV
[0038] Next step is with embodiment 1.
Embodiment 3
[0040] (1) Stainless steel surface pretreatment
[0041] With embodiment 1.
[0042] (2) Coloring - hard film treatment
[0043]The pre-treated stainless steel test piece 6 is used as the cathode, immersed in the coloring solution 3, the formula of the coloring solution 3: concentrated H 2 SO 4 490g / L, CrO 3 250g / L, (NH 4 ) 6 Mo 7 o 24 4H 2 O 7.0g / L, ZnSO 4 5.0g / L, MnSO 4 4.0g / L, cetyltrimethylammonium bromide 1.5g / L, solution temperature 65°C, connect the two loops of coloring and potential measurement according to attached figure 1, use pulse power supply 1, and control the current density at 7.0mA / dm 2 , Carry out chemical coloring with small electric current, wash with flowing water after coloring.
[0044] Potential difference / mV
[0045] Next step is with embodiment 1.
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