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159results about How to "Suitable for acidity" patented technology

Hydro-isomerization catalyst for paraffine, and its preparing method and application

A catalyst for the hydroisomerizing reaction of paraffin is composed of the active component (0.05-5.0 Wt%) chosen from Pt, Pd and Ir, and the composite molecular sieve ZSM-22 / ZSM-23 (or ZSM-23 / ZSM-22). It has high catalytic activity and selectivity.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Composite molecular sieve in ten-element cyclic structure and its synthesis process

The composite molecular sieve in ten-element cyclic structure has ten-element cyclic Si-Al structure and ten-element cyclic aluminum silicon phosphate structure. It is prepared through adding ZSM-22, ZSM-23, ZSM-5, EU-1, NU-87 or other ten-element cyclic structure Si-Al molecular sieve into aluminum silicon phosphate sol obtained via mixing Si source, Al source, P source, water and template agent to obtain primary sol; and subsequent hydrothermal crystallization to obtain the compound molecular sieve. The synthesis conditions may be altered based on the requirement to change the two phase ratio and the Si / Al ratio. Normally, the added amount of ten-element cyclic Si-Al molecular sieve is 0.01-0.6 time the total oxide weight in the aluminum silicon phosphate sol. The composite molecular sieve in ten-element cyclic structure may be used in the isometric dewaxing of lubricant oil and the isometric pour point depression of diesel oil and exhibits excellent catalytic performance.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

A silicone modified aluminum hydroxide solid elastomer and preparation method thereof

The invention relates to a method for preparing aluminum hydroxide wafer which is modified by silicon. Wherein, said wafer is baked and converted into silicon-modified gamma-Al203, to obtain following properties, that specific surface area is 400-600m2 / g, the hole capacity is 1.0-2.0cm3 / g, and the silica mass percentage is 2%-20%. In its preparation, after the neutralization between acid aluminum salt solution and alkali compound solution, it adds organic silicon to age, and composite via general steps. The invention has simple method.
Owner:CHINA PETROLEUM & CHEM CORP +1

ZSM-22/ZSM-23 composite molecular screen and its preparation method

The invention relates to a ZSM-22 / ZSM-23 composite molecular sieve and a method for synthesis it, which contains: mixing ZSM-22 molecular sieve with alumina silica colloid prepared by mixing carbon source, aluminum source, inorganic base, water with template agent, and adjusting the acid-base quality of the solution with inorganic acid to prepare initial colloid, the mole composition of the colloid being: SiO2 / Al2O3= 60-300, R / SiO2= 0.05-3, OH- / SiO2= 0.05-0.5, M / SiO2=0.1-0.5, H2O / SiO2= 10-65, the usage of ZSM-22 molecular sieve being 1-60% of silica dioxide by weight, and the temperature agent being one or more of pyrrolidine, isopropyl amine or isobutylamine. The ZSM-22 / ZSM-23 composite molecular sieve is prepared by hydrothermal crystallization of initial colloid.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Carbon-based rice seedling raising substrate for rice and preparation method thereof

InactiveCN105924268ASolve the problem that it is difficult to directly make rice seedling raising substrateReduce leachingBio-organic fraction processingExcrement fertilisersDiseasePotassium
The invention discloses a carbon-based rice seedling raising substrate for rice. The carbon-based rice seedling raising substrate comprises biochar, a straw fermented product, yellow soil, vermiculite and an inorganic fertilizer, wherein a volume ratio of the biochar to the straw fermented product to the yellow soil to the vermiculite is (10-20): (15-30): (25-35): (15-25); the inorganic fertilizer comprises nitrogen, phosphorus pentoxide and potassium oxide; and per 10 m<3> of the carbon-based rice seedling raising substrate for the rice comprises 12 to 18 g of a nitrogen fertilizer, 4 to 7 g of a phosphorus fertilizer and 5 to 16 parts of a potassium fertilizer. The invention also discloses a preparation method of the carbon-based rice seedling raising substrate for the rice. According to the invention, by utilizing the biochar and the fermented product which are prepared from widely-available farmland organic wastes like rice straws, and inorganic substances like the yellow soil and the vermiculite, the carbon-based rice seedling raising substrate for the rice is prepared. The substrate provided by the invention has the characteristics of fertility holding, water holding and good air permeability, and can effectively prevent the occurrences of bakanae disease, sheath blight and the like in a seedling stage.
Owner:CHINA NAT RICE RES INST

Preparation method of hydrotreatment catalyst

The invention discloses a preparation method of a hydrotreatment catalyst, comprising the following steps of: introducing silicon and boron additives in the way that an organic silicon source is added after aluminium hydroxide gel forming and then a boron-containing organic compound solution is added, so as to obtain silicon and boron containing aluminium hydroxide, mixing parts of an active metal component with boron-containing aluminium hydroxide by a kneading method, carrying out three-stage roasting to obtain a catalyst intermediate, loading residual part of the active metal onto the catalyst intermediate by dipping, and drying to obtain the hydrotreatment catalyst. By the adoption of the method provided by the invention, the silicon and boron additives and the active metal component are uniformly distributed on the surface of the catalyst. In addition, the active metal component has different existing forms in the catalyst when introduced in the two modes, loss rate of the catalyst activity is reduced by mutual cooperation, and running period of a device is prolonged. The catalyst has large pore volume, large specific surface area, appropriate pore structure and acidity, and is especially suitable for hydrodenitrogenation process of heavy hydrocarbon.
Owner:CHINA PETROLEUM & CHEM CORP +1

Hydrodenitrogenation catalyst capable of removing nitrogen-containing compound from coal tar, and preparation method and application thereof

The invention belongs to the technical field of catalysts for hydrodenitrogenation of coal tar. The technical problem to be solved is to provide a hydrodenitrogenation catalyst capable of deeply removing a nitrogen-containing compound from coal tar and provided with high mechanical strength, wear resistance and water resistance, and a preparation method and application thereof. The invention adopts the technical scheme that in the hydrodenitrogenation catalyst capable of removing nitrogen-containing compound from coal tar, active components consist of tungsten trioxide, nickel monoxide and chromium sesquioxide; aids comprise fluorine and phosphorus; and a carrier consists of aluminum oxide, zirconium oxide, a Hbeta molecular sieve, a binder and an extrusion aid. By adopting the hydrodenitrogenation catalyst capable of deeply removing the nitrogen-containing compound from the coal tar, the oil nitrogen content of the hydrogenation product can be reduced to be below 50 micrograms/gram; and the hydrodenitrogenation property is high, so that the oil sulfur content of the hydrogenation product can be reduced to be below 40 micrograms/gram.
Owner:山西中科化美科技有限责任公司

Synthetized modification HZSM-5 zeolite catalyst and method for preparing the same and use thereof

The present invention relates to one kind of comprehensively modified HZSM-5 zeolite catalyst and its preparation process and use. The process of preparing the catalyst includes the following steps: mixing HZSM-5 zeolite and adhesive in the weight ratio of 1-4, adding sesbania powder and water solution of HNO3 into the mixture to reach sesbania powder concentration of 1-3 wt% and HNO3 concentration of 2-5 wt%, kneading, extruding, drying and roasting to form catalyst carrier intermediate, hydrothermally modifying and organic acid treating the intermediate to obtain catalyst carrier, supporting active metal components onto the carrier, drying, and roasting to form catalyst product. The comprehensively modified HZSM-5 zeolite catalyst is applied in the hydrogenating modification of catalytically cracked gasoline, and can lower its olefin and sulfur content and improve its anti-knock index.
Owner:CHINA UNIV OF PETROLEUM (BEIJING)

Preparation method of boron-modified alumina carrier

The invention relates to a preparation method of a boron-modified alumina carrier. The method comprises the following steps of: firstly wetting an alumina precursor by the use of a low carbon alcoholic solution, adding a boron-containing solution formed by polyol and boric acid, and preparing the boron modified alumina carrier. By the adoption of the method, local supersaturation adsorption phenomenon caused by directly adding the boron-containing solution into the alumina precursor can be avoided, and the solution will not be over-absorbed into internal pores. Simultaneously, with the increase of the temperature during the kneading process, volatilization of low carbon alcohol and low surface tension help boron to uniformly disperse onto the surface of the alumina carrier. In addition, the method is beneficial to improving specific surface area and pore volume of the carrier. The boron modified alumina carrier provided by the invention is especially applicable to being used as a carrier for a hydrodenitrogenation catalyst.
Owner:CHINA PETROLEUM & CHEM CORP +1

Zeolite molecular sieve containing TON/MTT skeleton topology structure and preparation method of zeolite molecular sieve

The invention relates to a non-aluminium zeolite molecular sieve containing a TON/MTT skeleton topology structure and a preparation method of the zeolite molecular sieve. The preparation method comprises the steps of dissolving an inorganic alkaline source by using deionized water, then adding a template agent A, a boron source, an iron source or a gallium source, dissolving completely, then adding a template agent B or a silicon source, and adding an-all silicon ZSM-22 molecular sieve as seed crystal into obtained initial gel and then performing ultrasound; utilizing microwave radiation to heat a mixture subjected to the ultrasound so as to obtain a non-aluminum zeolite molecular sieve with a TON/MTT composite topology structure after crystallization. According to the method, the non-aluminium zeolite molecular sieve replaced with a heteroatom is utilized, the acidity is moderate, and the multilevel acidity distribution is adjustable; by adopting the preparation method provided by the invention, the synthesis time is short, the miscellaneous crystal is less, the particle size is uniform, and the repeatability is good. The composite molecular sieve has a huge potential application value in the aspects such as hydrocracking and isomerization.
Owner:SHANXI INST OF COAL CHEM CHINESE ACAD OF SCI

Preparation method of high-silicon macroporous amorphous silicon aluminum dry glue by using carbonation method

The invention relates to a preparation method of high-silicon macroporous amorphous silicon aluminum dry glue by using a carbonation method. The preparation method comprises steps of: (1) separately preparing a sodium aluminate solution and a silicon-containing compound material; (2) adding the sodium aluminate solution into a sealed pressure reactor, feeding carbon dioxide under stirring, with the pressure being raised to 0.2-2.0 MPa, the reaction temperature being controlled to be 10-35 DEG C and the reaction pressure during a reaction process being maintained; (3) adding a measured solution of the silicon-containing compound in to the reactor, feeding the carbon dioxide under stirring, with the reaction pressure being controlled at 0.2-2.0 MPa, the reaction temperature being controlled at 10-35 DEG C and the reaction pressure being maintained during the reaction process; and (4) ageing after the neutralization reaction is finished, filtering, washing and drying to obtain an amorphous silicon aluminum dry glue product. Compared with the prior art, the preparation method increases the utilization rate of the carbon dioxide, improves the environment of the neutralization reaction, and facilitates quality improvement of the amorphous silicon aluminum dry glue product.
Owner:CHINA PETROLEUM & CHEM CORP +1

Synthetic method of 3-methyl-3-buten-1-ol, catalyst and preparation method of catalyst

The invention relates to a synthetic method of 3-methyl-3-buten-1-ol, a catalyst and a preparation method of the catalyst, and relates to the technical field of catalyst synthesis. The preparation method of the catalyst for synthesis of 3-methyl-3-buten-1-ol includes the steps: baking a phosphorus-silicon-aluminum molecular sieve at the temperature of 300-600 DEG C for 3.5-5 h, carrying out equivalent-volume impregnation in an alkaline phosphate solution, then aging, drying, and baking. The preparation method is simple to operate and prone to industrialized production; the 3-methyl-3-buten-1-ol catalyst prepared by the method has good catalytic effect; when the catalyst is applied in the synthesis of 3-methyl-3-buten-1-ol, the yield of 3-methyl-3-buten-1-ol is effectively improved, the production efficiency is effectively improved and the preparation cost is reduced.
Owner:SHANDONG YUHUANG CHEM CO LTD
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