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Petroleum fraction hydrofining catalyst and preparing method thereof

A technology for hydrorefining and petroleum fractions, which is applied in catalyst activation/preparation, chemical instruments and methods, metal/metal oxide/metal hydroxide catalysts, etc. It is not easy to disperse evenly, etc.

Inactive Publication Date: 2004-12-08
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

CN1110304A has announced a kind of preparation method of the silicon-containing and phosphorus-containing aluminum oxide of macroporous, in the preparation process of this aluminum oxide, silicon and phosphorus are added with step-by-step colloidal method, and this method process is complicated, and production cost is high, And the amount of silicon added is limited, generally about 1wt% to 4wt%, which has a limited effect on the regulation of catalyst performance
CN1321726A introduces a kind of hydrogenation treatment catalyst and preparation method thereof, adds silica sol during the kneading process of aluminum hydroxide monohydrate (pseudo-thin water aluminum oxide), but because silica sol is the material with bigger micelle, it is not easy to disperse evenly, its not fully functioning

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] (1). Molybdenum-containing fluorine-silicon-alumina (Mo / F-SiO 2 -Al 2 o 3 ) preparation

[0029] (a). Binder preparation: 55g pseudo-thin water alumina, 800g silica sol (containing 30wt% SiO 2 ), with 110ml 3% HNO 3 The solutions were mixed, stirred evenly, and left for 6 hours;

[0030] (b). Preparation of molybdenum-containing fluorine-silicon-alumina: 370g pseudo-thin water alumina, 92g MoO 3 , 38g AlF 3 , 430ml 3% HNO 3 Mix the solutions together, add the binder prepared in (a), fully mix, knead into a plastic shape, and extrude into clover strips (φ=1.4mm). The wet strips were dried at 120°C for 3 hours after air drying overnight. Place the dried sample in a high-temperature furnace, raise the temperature to 330°C at a rate of 3°C / min, and keep the temperature constant for 1 hour. Then, the temperature was raised to 430° C. at a rate of 3° C. / min, and the temperature was kept constant for 3 hours.

[0031] (2), the preparation that contains nickel-phospho...

Embodiment 2

[0036] (1), molybdenum-containing fluorine-silicon-alumina (Mo / F-SiO 2 -Al 2 o 3 )preparation

[0037] (a). Adhesive preparation: same as Example 1 (1-a);

[0038] (b). Preparation of molybdenum-containing fluorine-silicon-alumina: the same as in Example 1 (1-b). But MoO 3 The amount of addition was changed to 105g;

[0039] (2), preparation of nickel-containing solution

[0040] 120gNi(NO 3 ) 2 ·6H 2 O was dissolved in 470ml of water, and 35ml of H was added 3 PO 4 (85%), stir evenly.

[0041] (3), catalyst preparation

[0042] Same as Example 1(3).

Embodiment 3

[0044] (1). Molybdenum-containing fluorine-silicon-alumina (Mo / F-SiO 2 -Al 2 o 3 ) preparation

[0045] (a). Adhesive preparation: same as Example 1 (1-a);

[0046] (b). Preparation of molybdenum-containing fluorine-silicon-alumina: 370g pseudo-thin water alumina, 92g MoO 3 , 38g AlF 3 , 430ml 3% HNO 3 Mix the solutions together, add the binder prepared in (a), fully mix, knead into a plastic shape, and extrude into clover strips (φ=1.4mm). The wet strips were dried at 120°C for 3 hours after air drying overnight. Place the dried sample in a high-temperature furnace, raise the temperature to 330°C at a rate of 3°C / min, and keep the temperature constant for 1 hour

[0047] (2), the preparation that contains nickel-phosphorus solution

[0048] 100gNi(NO 3 ) 2 ·6H 2 O was dissolved in 470ml of water, and 33ml of H was added 3 PO 4 (85wt%), stir evenly.

[0049] (3), catalyst preparation

[0050] Same as Example 1(3).

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Abstract

A catalyst for petroleum fractions hydrogenation and its preparation are disclosed. It includes preparing silicon binder, fully mixing pseudooligaaqueous aluminum oxide, fluo-compound and compound containing VIB family metals such as molybdenum or tungsten with silicon binder, kneading, stripping, shaping, drying, and high temperature roasting to form Mo(W) / F-SiO2-Al2O3 as carrier, immersing in an aqueous phosphoric acid solution containing VIIIB family metals such as nickel or cobalt, drying and high temperature roasting to obtain the catalyst of petroleum fractions hydrogenation. Its advantages include simple preparation, easy operation, low cost, good active ingredient dispersing status, large specific area and pore volume.

Description

technical field [0001] The invention relates to a petroleum distillate hydrorefining catalyst and a preparation method thereof, in particular to a high metal content hydrorefining catalyst with large specific surface area and pore volume and a preparation method thereof. Background technique [0002] Petroleum fractions contain organic sulfur compounds, organic nitrogen compounds, and organic metal (such as nickel, vanadium, iron) compounds and other harmful compounds. The existence of these compounds not only affects the storage stability of oil products, but also emits harmful pollutants during use. Sulfur, nitrogen, and oxide gases will pollute the environment, and may also cause catalyst poisoning during the processing of some petroleum fractions. The main purpose of hydrofinishing is to remove these harmful compounds from petroleum fractions. Mo(W)-Ni(Co)-Al 2 o 3 Catalysts are widely used in the hydrorefining process of petroleum distillates. [0003] A hydrorefini...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J21/04B01J21/08B01J23/85B01J27/12B01J27/14B01J37/00C10G45/08
Inventor 何金海罗锡辉
Owner CHINA PETROLEUM & CHEM CORP
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