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141results about How to "Stable film formation" patented technology

Electrochemical sensor for determining concentration of heavy metal ions in water sample

The invention relates to a sensor, in particular to an electrochemical sensor for determining the concentration of heavy metal ions in a water sample. The electrochemical sensor specifically comprises a working electrode, a reference electrode and an auxiliary electrode, and the working electrode, the reference electrode and the auxiliary electrode are respectively connected to a control potential meter through conducting wires; the working electrode consists of a polytetrafluoroethylene pipe and a carbon electrode clamped therein, the bottom end of the carbon electrode is connected with a lead wire for leading out, and a sensitive membrane is arranged at the top end of the carbon electrode; and the sensitive membrane consists of a nano-functional absorbing material, a heavy metal ion carrier and an ion exchange agent, 1-20mmol of nano-functional absorbing material, 0.5%-5% by weight of the ion exchange agent and the 0.5-10mmol of the ion carrier are added in each liter of dispersant and evenly mixed, and then 1mu L-30mu L of the mixture is taken and evenly coated on the surface of the carbon electrode. The electrochemical sensor has low cost, simple technology, high selectivity and sensitivity and good stability, and can be extensively applied in the detection of the heavy metal ions in waste water, fresh water, sea water, daily necessities and body fluid.
Owner:YANTAI INST OF COASTAL ZONE RES CHINESE ACAD OF SCI

Vertical tube type falling-film evaporator

The invention relates to a vertical tube type falling-film evaporator. The vertical tube type falling-film evaporator comprises an upper tube box, a lower tube box, a casing, multiple heat exchange tubes, an upper tube plate and a lower tube plate, wherein a solution inlet and a secondary steam outlet I are arranged at the upper tube box, a concentrated liquid outlet and a secondary steam outlet II are arranged at the lower tube box, a steam inlet is arranged at the upper part of the casing, and a condensed water outlet is arranged at the lower part of the casing; a film distributing device used for distributing a solution on the inner walls of the heat exchange tubes is arranged in the upper tube box; the film distributing device comprises a liquid bearing plate, a liquid feeding plate, a liquid distributing plate and liquid guiding tubes. By means of a steam stripping effect generated by secondary steam and liquid films, the heat transferring push force and the evaporation efficiency are increased. The liquid films can be uniformly distributed by the film distributing device, the film forming is stable, the wall drying phenomenon is avoided, the recovery rate of secondary steam produced in an evaporator is high, the recovery is convenient, and the heat transferring efficiency is improved.
Owner:LUOYANG SUNRUI SPECIAL EQUIP

Vertical-tube falling film absorption reactor

A vertical-tube falling film absorption reactor comprises an upper tube box, a lower tube box and a shell, wherein the shell is arranged between the upper tube box and the lower tube box and is connected with the upper tube box and the lower tube box in a sealed manner respectively; a tube plate is arranged at each of the upper end and the lower end of the shell; a vertical tube bundle is arranged between the two tube plates; a film distributing device is arranged inside the shell; the film distributing device comprises an upper liquid distributing plate, a lower liquid distributing plate, and a barrel-shaped overflowing plate arranged on the upper liquid distributing plate; film distributing annular spaces are formed between lower liquid distributing plate tube holes in the lower liquid distributing plate and heat exchange tubes running through the lower liquid distributing plate tube holes; centering bulges for centering the heat exchange tubes are arranged inside the lower liquid distributing plate tube holes; spiral grooves are formed in the outer walls of the heat exchange tubes. The vertical-tube falling film absorption reactor uses the more reasonable film distributing device, so that purposes of uniformly distributing a liquid film and stably forming the film can be achieved, a dry wall phenomenon can be avoided, and the heat transfer efficiency and the mass transfer efficiency are greatly improved.
Owner:LUOYANG SUNRUI SPECIAL EQUIP

Sputtering target, dielectric film formed from the sputtering target and method for producing the dielectric film

A sputtering target according to the invention including an oxide sintered body containing NbOx and TiOx in which the abundance ratio of Ti atoms in the target is from 70% to 90% both inclusively. Preferably, the oxide sintered body has a specific resistance value not higher than 10Ω·cm. Preferably, theoxidesinteredbody has a thermal expansion coefficient not larger than 7 ×10−6 / K and a thermal conductivity not lower than 10 ×10−4 cal / mm-K-sec.
Owner:NIPPON SHEET GLASS CO LTD

Method for preparing nonpolar polyvinylidene fluoride ultrafiltration membrane

The invention discloses a method for preparing a nonpolar polyvinylidene fluoride ultrafiltration membrane. The method comprises the following steps: (1) mixing raw materials, evenly agitating at 40-80 DEG C, standing and defoaming to obtain polyvinylidene fluoride membrane liquid, and standing for later use; (2) scraping the membrane liquid on a clean and smooth glass plate, exposing in air to volatize solvent for 0.5-24 hours, wherein the thickness of the membrane liquid is 120-600 microns; (3) immersing the scraped membrane liquid into a first coagulation bath alcohol-water solution, and soaking for 0.02-72 hours under the condition at 40-80 DEG C, so as to prepare a coarse ecological membrane; (4) immersing the coarse ecological membrane into a second coagulation bath, and soaking for 24-72 hours under the condition at 0-80 DEG C; (5) immersing the membrane into a third coagulation bath alcohol-water solution for 2-24 hours, and airing under the condition at 20-50 DEG C, so as to obtain the nonpolar polyvinylidene fluoride ultrafiltration membrane with stable performance. The preparation method disclosed by the invention is simple in technology, and low in production cost; the prepared polyvinylidene fluoride ultrafiltration membrane is non-polar, strong in mechanical strength, good in hydrophilicity, and strong in anti-pollution capacity.
Owner:XIAMEN UNIV OF TECH

Hydrous silane coupling agent-polyether grafted polysiloxane polymer coating

ActiveCN103360021AGood fixation effectStable film formationSaline waterChemistry
The invention belongs to the field of coatings, and discloses a hydrous silane coupling agent-polyether grafted polysiloxane polymer coating. The hydrous silane coupling agent-polyether grafted polysiloxane polymer coating comprises the following components in parts by weight: 100 parts of inorganic silicate water solutions, 1-50 parts of hydrous silane coupling agent-polyether grafted polysiloxane polymers, 10-100 parts of water, 0-40 parts of titanium dioxide, 0-40 parts of pigments, 10-50 parts of calcium carbonate, 0-50 parts of silicon dioxide, 0.05-5 parts of defoaming agents, 0.05-5 parts of dispersing agents, 0.05-5 parts of wetting agents, 0.05-5 parts of thickening agents, 0.05-5 parts of anti-freeze agents and 0.1-10 parts of film-forming auxiliary agents. The hydrous silane coupling agent-polyether grafted polysiloxane polymer coating disclosed by the invention has the advantages of abrasion resistance, acid resistance, alkali resistance (without bubbles for 168 hours), easiness for construction, good fixation effect, film-forming stability, excellent film-forming appearance, and the like and is suitable for inner and outer walls.
Owner:GUANGZHOU CHEM CO LTD CHINESE ACADEMY OF SCI

Trivalent chromium concentrated blue and white zinc passivant and passivation method by means of blue and white zinc passivant

InactiveCN103132068AWide process toleranceProcess tolerance is simpleMetallic material coating processesRare-earth elementNitrate
The invention belongs to the field of passivation treatment and discloses a trivalent chromium concentrated blue and white zinc passivant. The trivalent chromium concentrated blue and white zinc passivant is prepared from 8-50g/L of chromic chloride, 10-60g/L of aluminium potassium sulfate, 3-10g/L of aluminium potassium sulfate, 3-20g/L of cobalt nitrate, 8-15ml/L of coupling agent, and 0.5-5g/L of rare earth element. The invention further discloses a passivation method by means of the trivalent chromium concentrated blue and white zinc passivant. The passivation method includes a first step of galvanizing the surface of a product, washing the product with water, activating the product with concentrated hydrochloric acid, and washing the product with water, a second step of processing the product by means of the blue and white zinc passivant, washing the product with water, and sealing the product with hot water, and a third step of drying the product. The trivalent chromium concentrated blue and white zinc passivant and the passivation method by means of the trivalent chromium concentrated blue and white zinc passivant are environment-friendly, wide in technology tolerance, easy to operate, good in stability, firm in film formation, little in consumption, and low in cost.
Owner:CHONGQING DIANSHI METAL SURFACE TREATMENT

Long-acting concrete water-based mold release agent suitable for steel mold and preparation method of mold release agent

InactiveCN110804483AEnhanced coatability and barrier lubricationEasy to operateLubricant compositionChemistryComposite material
The invention belongs to the technical field of chemical building materials, and particularly relates to a long-acting concrete water-based mold release agent suitable for a steel mold and a preparation method of the mold release agent. Aiming at the problems, the invention mainly overcomes the defects in the prior art, and provides the long-acting concrete water-based mold release agent suitablefor the steel mold and the preparation method of the mold release agent; the long-acting concrete water-based mold release agent comprises the following components: vegetable oil, a coalescing agent,a compound emulsifier, a stabilizer, a corrosion inhibitor and water, wherein the coalescing agent comprises a long-chain alkyl silane coupling agent and aminopropyltriethoxysilane. The prepared concrete water-based mold release agent is stable in performance, good in water scouring resistance and good in reusability, and the apparent mass of hardened concrete can be effectively improved.
Owner:CHINA WEST CONSTR GRP +1

Preparation method of fluorosilicone modified carbamido compound

The invention discloses a preparation method of a fluorosilicone modified carbamido compound. The preparation method comprises following steps: (1) synthesizing fluorosilicone; (2) preparing a fluorosilicone modified carbamido compound; (3) refining the finished product; and (4) diluting and cooling: adding a proper weight of a DMF solvent into the finished product obtained in the step (3) under astirring speed of 500-900 r / min, cooling to the room temperature, measuring, and obtaining the high purity fluorosilicone modified carbamido compound. The provided preparation method has the characteristics of simple technology, good solubility, stable performance, and wide application range.
Owner:广东坚派新材料有限公司

Laminate film

A white laminated film which has practically sufficient reflectivity at a visible range, can be formed stably, is free from deterioration (yellowing) by ultraviolet radiation, rarely deforms by heat and can be advantageously used as a reflector substrate for liquid crystal displays and internal illumination type electrically spectacular signs, is provided. The laminated film comprises a first layer of a composition which comprises 31 to 60 wt% of inert particles having an average particle diameter of 0.3 to 3.0 µm and 40 to 69 wt% of a polyester consisting of 1 to 100 mol% of naphthalenedicarboxylic acid and 0 to 99 mol% of terephthalic acid as a dicarboxylic acid component and ethylene glycol as a diol component, and a layer B of a composition which comprises 0 to 30 wt% of inert particles having an average particle diameter of 0.3 to 3.0 µm and 70 to 100 wt% of a polyester consisting of 3 to 20 mol% of naphthalenedicarboxylic acid and 80 to 97 mol% of terephthalic acid as a dicarboxylic acid component and ethylene glycol as a diol component and which is in direct contact with the first layer.
Owner:TEIJIN DUPONT FILMS JAPAN

Antibacterial emulsion for fresh keeping of var. ramosa Hort. and method for preparing var. ramosa Hort. fresh keeping film

The invention discloses an antibacterial emulsion for fresh keeping of var. ramosa Hort. and a method for preparing a var. ramosa Hort. fresh keeping film. Plant essential oil, carbon quantum dots, aco-emulsifier, an emulsifying agent and distilled water are mixed in a specific sequence and a technology so that a microemulsion is prepared. According to the antibacterial emulsion disclosed by theinvention, a carbon quantum dot technique is introduced into the field of fresh keeping of vegetables for the first time, the characteristics of the carbon quantum dots and the characteristics of antibacterial plant essential oil are sufficiently utilized, and the antibacterial emulsion good in dispersibility, stable in film formation and high in bacteriostasis capacity is obtained. The antibacterial emulsion and propolis liquid are compounded to obtain a mixture, then the mixture is coated onto packaging films to be used for fresh keeping of the var. ramosa Hort. in the warehouse storing course, respiratory intensity of the fresh-cut var. ramosa Hort., microorganism growth and activity of polyphenol oxidase can be well restrained, VC losses in the storage period can be reduced, and favorable organoleptic quality of the var. ramosa Hort. can be maintained. After the fresh-cut var. ramosa Hort. coated with the fresh keeping film is in low-temperature preservation under the condition of4 DEG C, the shelf life can be prolonged to 10-15 days.
Owner:AGRO PROD PROCESSING RES INST YAAS

Energy-saving environment protecting function type lubricant agent

The invention discloses an energy-saving environment-protective lubricant with lubricating reinforcing and abrasion proof and squeezing proof effect for the lubricating part of kinds of mechanic equipment, which comprises the following parts: 5%-8% molybdenum disulphite with grain size at 30-5000nm, 5%-8% graphite powder with grain size at 30-5000nm, 5%-8% molybdenum oxide dialkyl dithiophosphate as antiwear agent, 10%-15% succinyl imines as dispersant, 10%-15% polymethacrylate ester as adhesive and residual liquid lubricating material. The invention can repair and fill the side-surface abrade by metal automatically to film rapidly and stably, which lengthens the lift of lubricating part of the mechanic equipment by one time and improves the effective efficiency by 4-10%, therefore saving the fuel by 10-15%, reducing the discharge of harmful gas and smoke obviously and the mechanic noise by 1-8 decibel.
Owner:SHANDONG SUN RISES & THE EAST GASOLINEEUM & CHEM CORP

Production technology of contrast-effect automobile seat cushion leather

The invention relates to a production technology of contrast-effect automobile seat cushion leather. The protection technology comprises the steps of liming: dissolving Na2S, NaHS and lime into water in a mass ratio of 1:1:2 to form a liming alkali liquor, reacting fur with the liming alkali liquor in a liquor ratio of 100:100 for 6 h, adding the liming alkali liquor step by step to enable the liquor ratio to increase to 100:200, and continuously reacting for 12 h; retanning: for every 100 parts of fur, adding 100 parts of water, 1 part of a pre-fatting agent and 3 parts of a chrome tanning agent or a chrome-free tanning agent, reacting at the normal temperature for 1 h, adding 2 parts of sodium formate, reacting at the temperature of 40 DEG C for 1 h, and controlling the pH in a range of 3.6-4.0; and finishing: the finishing comprises the steps of roller coating of a bottom layer, embossing, spraying of a color layer, roller coating of an effect layer and spraying of a top layer. The leather produced through the technology is soft, fine in grain side, full in hand feeling, elastic, safe and environment-friendly and has characteristics of wear resistance, folding endurance, light resistance, color migration resistance and the like; and ornamental and pleasant characteristics of the leather are added due to roller coating of the effect layer, and the rigid and non-flexible appearance of ordinary automobile seat cushion leather is changed.
Owner:HAINING SENDE LEATHER

Special medicinal fertilizer for overwintering pisum sativum and production method thereof

InactiveCN104692929ANutritional balanceLong and significant fertilizer effectSuperphosphatesAmmonium salt fertilisersFruit setImidacloprid
The invention discloses a special medicinal fertilizer for overwintering pisum sativum and a production method thereof. The production method of the special medicinal fertilizer is characterized by mixing and granulating urea, calcium superphosphate, Sugumi potassium, ammonium molybdate, borax and DMPP to obtain inner cores, pelletizing for two times, and coating with a coating agent, wherein the components pelletized for the first time comprise urea, monoammonium phosphate, Sugumi potassium, compound potassium nitrophenolate, the solution of tea saponin and nicotine, matrine, DMPP and a colloidal suspension, the components pelletized for the second time comprise urea, a calcium, magnesium and phosphate fertilizer, Sugumi potassium, a chelated salt of amino acid and trace elements, borax, DMPP and a colloidal suspension, and the components of the coating agent comprise imidacloprid, Dual metolachlor, a film forming agent, pearl powder, titanium dioxide and a dye. Through one-time coating, two-time granulating and three-time controlled-release material using, the effective period of urea can be prolonged to 170 days from 15 days or so. The special medicinal fertilizer disclosed by the invention has the effects of weeding, killing insects, promoting the growth of plants and increasing the fruit setting rate of plants.
Owner:SHANDONG COTTON RES CENT

Nano glass antifogging agent and preparation method thereof

The invention provides a nano glass antifogging agent and a preparation method thereof. The nano glass antifogging agent comprises effective components and water. The effective components comprise an anionic surfactant, a non-ionic surfactant, a nano photocatalytic active substance, an active agent stabilization additive, an organic acid solvent and a volatilization dispersant. In the preparation process, the organic acid solvent and the volatilization dispersant are mixed with partial water so as to obtain solution A; the anionic surfactant is mixed with the non-ionic surfactant so as to obtain solution B; the active agent stabilization additive is added to the solution B, the solution is uniformly mixed, then the solution A is added, and the rest water is added after uniformly mixing, the nano glass antifogging agent is obtained after uniformly mixing. The preparation method is capable of stably dispersing the nano photocatalytic active substance into a carrier solvent, using the super-hydrophilic property and nano adhesiveness thereof, and using own specific ultraviolet shielding and the decomposing and removing of harmful gases in the air as the function extension of the nano glass antifogging agent, and obtaining the nano glass antifogging agent with the long-term stable antifogging effect and the possible functional recovery after long-term use.
Owner:重庆返璞科技有限公司

Efficient denitrification biological carrier filler and applications of efficient denitrification biological carrier filler in sewage treatment

The invention discloses an efficient denitrification biological carrier filler and applications of the efficient denitrification biological carrier filler in sewage treatment. The efficient denitrification biological carrier filler comprises a shell and hollow bamboo balls, and specially comprises a hollow plastic spherical shell and a plurality of built-in hollow bamboo ball knitted from phyllostachys pubescens strips, wherein the surface of the phyllostachys pubescens contains a large amount of hydroxyl groups and carboxyl free radicals, and has good hydrophilicity and good bio-affinity so as to rapidly form the active sludge film and provide the firm active sludge film, and when the carbon source is insufficient, the hollow bamboo balls can be decomposed into denitrifying bacteria so as to provide the carbon source. According to the present invention, the efficient denitrification biological carrier filler has the characteristics of rapid film forming and firm formed film of the bamboo filler, the characteristic of high mechanical strength of the plastic filler, further has characteristics of greatly-increased filler surface area, unit volume biomass increasing, greatly-increased active sludge concentration in the reactor, nitrification effect improving, denitrification effect improving, and substantially-increased denitrogenation efficiency of the high concentration nitrogen-containing wastewater.
Owner:CENT SOUTH UNIV +1

Method for preparing skin-free homogeneous structural polyvinylidene fluoride transfer film

The invention discloses a method for preparing a skin-free homogeneous structural polyvinylidene fluoride transfer film, which comprises the following steps of: (1) mixing raw materials, stirring the raw materials uniformly at the temperature of between 60 and 140 DEG C, standing and de-foaming the mixture to obtain polyvinylidene fluoride film-making solution, and standing the film-making solution for later use; (2) scraping the film-making solution on a clean and flat glass plate, wherein the thickness of the film solution is 300 to 700 microns; (3) dipping the scraped film solution into a first gel bath, and soaking the film solution for 0.05 to 48 hours at the temperature of between 0 and 30 DEG C to obtain a coarse ecological film; (4) dipping the coarse ecological film into a second gel bath, and soaking the coarse ecological film for 0.1 to 2 hours at the temperature of between 5 and 70 DEG C; and (5) soaking the film into purified water for at least 24 hours, fully displacing the residual organic solvent and additive, then taking the film out, and naturally airing the film to obtain the homogeneous network structural polyvinylidene fluoride transfer film. The preparation method has simple process and low production cost, and the prepared polyvinylidene fluoride transfer film has high strength and high protein adsorption quantity.
Owner:ZHEJIANG UNIV
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