The invention discloses a preparation method of Sm3+ glass doping brilliant glass ceramics. The Sm3+ glass doping brilliant glass ceramics consists of XZnO-YB2O3-ZSiO2-RNa2O-MAl2O3-NTiO2-QZrO2-TSm2O3, zinc oxide, boric acid, silicon dioxide, aluminum oxide, sodium carbonate, titanium dioxide, zirconium dioxide and samarium sesquioxide serve as raw materials, raw materials are melted at the temperature from 1,400 DEG C to 1,500 DEG C after being grinded and mixed, glass is produced, the annealing is conducted for 2-3 hours at the temperature from 500 DEG C to 550 DEG C, and the glass is cooled to the room temperature. The crystallization treatment is conducted, the coring is conducted for 2-2.5 hours at the temperature from 550 DEG C to 575 DEG C, the crystallization is conducted for 6-12 hours at the temperature from 720 DEG C to 740 DEG C and the zinc borosilicate brilliant glass ceramics is obtained. The method is simple in process, reliable and stable in process condition, wide in application and good in physical and chemical stability. The luminescent property of the glass ceramics is better than that of normal glass materials.