The invention discloses a preparation method of a heat shrinkable
polyester film. The method comprises the following steps of: carrying out esterification and condensation
polymerization reaction on multi-component
dicarboxylic acid and multi-component dihydric
alcohol in the presence of a catalyst, a stabilizing agent, an
antistatic agent, a chain
extender, an anti-
caking agent or a modifying agent to prepare a multi-component
polyester; carrying out
melt extrusion, extension and pelleting on the multi-component
polyester to prepare a multi-component polyester slice; and carrying out melted
extrusion, die head
casting, transverse
far infrared drawing, cooling molding, rolling and
cutting on the multi-component polyester slice to prepare the heat shrinkable polyester film. The heat shrinkable polyester film with high shrinkage percentage prepared by using the method is pretty high in strength and heat shrinkage performance, excellent in transparency, malleability, and
toughness, good in glossiness, uniform in shrinkage, non-toxic, odorless, and easy to recycle, and a product of the film is suitable for labels for various containers and direct packaging of a food product, a beverage product, an electronic product, an electric product, a mechanical product, a hardware product and the like.