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90results about How to "Reduced current efficiency" patented technology

Wastewater treatment method and device combining electrochemical degradation and photocatalysis oxidation technologies

The invention relates to a wastewater treatment method and device combining electrochemical degradation and photocatalysis oxidation technologies taking a diamond film electrode as the anode. The device comprises a flowing electrolytic bath and a photocatalytic reactor. Contaminants have electrocatalytic oxidation at the anode of the flowing electrolytic bath and are electrolyzed to separate out water and then enter the photocatalytic reactor for further degradation. The combination of two technologies can improve the current efficiency reduction caused by oxygen analyzing reaction in an electrochemistry part because oxygen analyzed by the electrochemistry part is a favorable trapping agent of photoelectrons of a photocatalysis part, can improve the separation efficiency of the photoelectrons and cavities and improve the catalytic degradation of the photocatalysis part. Meanwhile, by opening or closing various parts of the device, proper operational modes can be selected according to the kinds and the concentration of wastewater, such as an independent electrochemistry method, an independent photocatalysis method, an electrochemistry and photocatalysis combined method and other different operational modes.
Owner:TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI

Method for electroplating zinc-nickel alloy on sintered neodymium-iron-boron material

The invention relates to the field of surface treatment corrosion protection for a sintered neodymium-iron-boron material, in particular to a method for electroplating a zinc-nickel alloy on the surface of the sintered neodymium-iron-boron material. The method is mainly characterized by comprising the following steps of: firstly, performing treatment before plating on the sintered neodymium-iron-boron material; secondly, carrying out chemical nickel plating; thirdly, carrying out copper electroplating and zinc-nickel alloy electroplating; and finally, carrying out passivation treatment. The binding force between an adopted chemical nickel-plated layer and the neodymium-iron-boron material is excellent; a copper-plated layer can play a role in hydrogen blocking while electroplating the zinc-nickel alloy so as to reduce the hydrogen corrosion to the neodymium-iron-boron material; and a zinc-nickel alloy layer, as an anode coating, effectively protects the neodymium-iron-boron material. The coating obtained by the method is complete, compact, uniform and bright, and is firmly combined with a substrate; and the corrosion resistance of the coating is further improved after the passivation treatment. The method solves the problem that the neodymium-iron-boron electroplated zinc-nickel alloy has poor binding force and affects the corrosion resistance. The method realizes good binding force between the coating and the substrate, dense coating, uniform component and excellent corrosion resistance.
Owner:INST OF METAL RESEARCH - CHINESE ACAD OF SCI

Method used for preparing fluorine salt taking aluminium fluoride as main component from electrolyte-containing material produced in aluminium electrolysis

The invention provides a method used for preparing a fluorine salt taking aluminium fluoride as a main component from electrolyte-containing material produced in aluminium electrolysis. The method comprises following steps: the electrolyte-containing material is mixed with a soluble aluminium salt or an aluminium salt solution, and reaction is carried out at 50 to 100 DEG C; a reaction product issubjected to solid liquid separation, after separation, an obtained solid product is washed and dried so as to obtain the fluorine salt taking aluminium fluoride as a main component, and a liquid solid product obtained through separation and a solid product washing solution obtained in washing of the solid product are mixed so as to obtain a mixture, a strong basicity hydroxide or a solution of the strong basicity hydroxide is added into the mixture to remove calcium and iron impurities in the mixture; evaporation concentration desalting is carried out, and separation is carried out so as to obtain a concentrated mother liquor; a carbonate or a solution of the carbonate is added to remove Lithium-ion impurities in the concentrated mother liquor, after impurity removing, an obtained solution is adopted in diluting or washing step in the method. The method is capable of converting the excess electrolyte-containing material produced in aluminium electrolysis into aluminum fluoride, so that effective circulation of fluoride element in aluminium electrolysis enterprises is realized, and great meaning on aluminium electrolysis industry development of China is achieved.
Owner:郑州于斯新创科技有限公司

Method and system for preparing ferric chloride, electrodeposited copper and copper powder from copper-containing hydrochloric acid waste liquid

The invention provides a method and a system for preparing ferric chloride, electrodeposited copper and copper powder from copper-containing hydrochloric acid waste liquid. The system comprises a first liquid storage tank, a stirring reactor, a filter, a chlorine absorption tank, a caustic soda solution absorption tower, a solution adjusting tank, an electrodeposition cell and an exhaust fan, wherein the first liquid storage tank is used for storing the copper-containing hydrochloric acid waste liquid; the stirring reactor is used for carrying out replacement reaction between ferrum and copper chloride; the filter is used for filtering a solution obtained through the replacement reaction; the chlorine absorption tank is used for enabling the solution filtered by the filter to absorb chlorine, so that ferrous chloride is oxidized into ferric trichloride; the caustic soda liquid absorption tower is used for treating tail gas emitted from the chlorine adsorption tank; the solution adjusting tank is used for adjusting the concentration of a solution in the electrodeposition cell; the electrodeposition cell is used for an electrodeposition reaction; and the exhaust fan is used for conveying chlorine gas produced by the electrodeposition cell to the chlorine absorption tank. According to the method and the system provided by the invention, replacement of copper ions from ferrous powder is combined with the electrodeposited copper, so that the wastewater discharge problem of the copper-containing hydrochloric acid waste liquid and the pollution problem of the chlorine gas to the environment can be solved, and the phenomenon that the power consumption sharply rises is avoided.
Owner:SHENZHEN YUEPENG ENVIRONMENTAL PROTECTION TECH

Even-plating agent used for electroplating copper and relevant metal copper electroplating combination agent thereof

The invention discloses an even-plating agent used for electroplating copper and a relevant metal copper electroplating formula, and belongs to the technical field of electroplating and electro-deposition. The even-plating agent is one or more organic matters containing a first kind of active functional group or a second kind of active functional group; the first kind of active functional group and the second kind of active functional group are conjugate; and the reduction potential of the organic matters containing the active functional group under an electrochemical system is not higher thanthe reduction potential of copper electro-deposition so that the active functional group in the even-plating agent can have a competitive reaction with copper ions, the copper deposition current efficiency of a cathode is reduced, reduction of the thickness of surface copper is facilitated, the even-plating agent is especially suitable for improving the throwing power of electroplating and blindhole filling of through holes with high ratios of thickness to diameter, and thus the circuit fineness of existing printed circuit boards is improved.
Owner:UNIV OF ELECTRONIC SCI & TECH OF CHINA

Low-energy-consumption electrochemical treatment device and method for degradation-resistant organic wastewater

The invention relates to an electrochemical treatment device and method for degradation-resistant organic wastewater, and designs a'zero polar distance' SPE (Solid Polymer Electrolysis) electrooxidation sewage treatment electrolytic bath like a solid polymer electrolyte fuel cell technology. According to the device, an anode chamber and a cathode chamber are separated by utilizing an ion exchange membrane, the anode with stable titanium-based size, the ion exchange membrane and the nickel cathode are pressed by utilizing an end plate, and a'zero polar distance' SPE electrooxidation sewage treatment electrolytic bath is formed. When the device is subjected to electrolytic operation, the wastewater is electrically oxidized at the anode, so that organic matters and ammonia nitrogen in the water are mineralized and degraded; and running water or the wastewater is introduced into the cathode chamber, and hydrogen separated out due to electrolysis at the cathode is recovered. The device has the advantages that extra supporting electrolyte is not needed to be added, the bath pressure and energy consumption of electrooxidation can be greatly reduced due to the'zero polar distance', and the problem that oxygen (chlorine) and hydrogen separated out in the electrolysis process is solved. In addition, a carbon material is not used, reduction of current efficiency caused by carbon corrosion is avoided, and the reliability and stability of the sewage treatment device are improved. Moreover, continuous water flow is utilized at the cathode, and the scaling and plugging possibility on the cathode side of the ion exchange membrane can be greatly reduced.
Owner:BEIJING JINDAYU ENVIRONMENT TECH CO LTD

Preparation method of multicomponent microalloying aluminium alloy containing titanium, zirconium and scandium

InactiveCN1769536AReduce added costReduce oxide inclusions and hydrogen contentTitaniumOxide
This invention provides a making method for the multicomponent microalloy aluminium alloy such as titanium, zirconium, the scandium, the main steps as follows: under the steadiness of the electrolyzation aluminium production establishment condition, adding the titanium compound, the zirconium dioxide, the scandium trioxide with a certain proportion, using the electrolytic method of the alumina compound and cryolite to produce, the relative mass as follows: Tiíœ0.2úÑú¼Zríœ0.5úÑú¼Scíœ0.5úÑú¼ the rest is aluminium, wherein there are at least two is not 0 in the TiíóZríóSc. This invention decreases the cost for adding the TiíóZríóSc, decreases the oxide lard and hydrogen content in the alloy, thins and strengthens the aluminium.
Owner:ZHENGZHOU UNIV

Electrochemical water scale removal device

The invention provides an electrochemical water scale removal device. The device comprises a water scale crystal nucleus generating unit used for electrochemical water treatment, wherein the water scale crystal nucleus generating unit comprises a tank body, diaphragms, an anode, cathodes and auxiliary electrodes; a water inlet and a drain outlet are formed in the bottom of the tank body; the diaphragms are arranged inside the tank body and divide the tank body into cathode chambers and an anode chamber; the anode is arranged inside the tank body; the cathodes and the auxiliary electrodes are arranged inside the cathode chambers; a catholyte water outlet and an anolyte water outlet are formed in the top end of the tank body. The device has the beneficial effects that with electrochemical operation, water scales can be deposited on the surfaces of the diaphragms and hinder ionic migration through the diaphragms, so that the resistance is increased, the current efficiency is reduced and the diaphragms need to be regenerated; the cathode chambers are emptied, the anolyte is led into the cathode chambers, then the auxiliary electrodes serving as anodes are connected and the anolyte generates chlorine and hydrochloric acid near the auxiliary electrodes, so that the water scales on the surfaces of the diaphragms are completely washed and the diaphragms are regenerated in situ.
Owner:章明歅 +1

Anode changing method of electrolyzer

The invention discloses an anode changing method of an electrolyzer. The method comprises the steps of: removing a residual electrode ; and arranging a heated new anode at a temperature of 50-500 DEG C into the electrolyzer. Compared with direct usage of a cold wet anode in the electrolyzer, the heated anode can reduce frequency of ''needle vibration'' of the electrolyzer, improve stability of the electrolyzer, reduce Fe-C pressure drop of the anode and improve anode conductivity, so as to realize the electrolyzer production with high efficiency and low consumption.
Owner:SNTO TECH GRP

Method and device for operating an OLED device

The invention relates to a method for operating an organic light emitting component ( 1 ), in particular organic light emitting diode (OLED), and an organic light emitting component ( 1 ) with an organic layer ( 1 c) comprising a plurality of different emitter materials, which emit light of different colours, and an electrode arrangement ( 1 a , 1 b) for applying electric control pulses to the organic layer ( 1 c), the method having the following steps: operating the organic light emitting component ( 1 ) with the help of the electric control pulses in a pulsed operating mode with an operating frequency of at least about 25 Hz; at least partially compensating an ageing induced varying colour change of the light emitted from the organic layer ( 1 c) during the course of the pulsed operation by recording at least one operating parameter characterizing the running pulsed operation of the organic light emitting component ( 1 ) and for which a dependence relationship to the ageing induced varying colour change is known at least approximately, and by adjusting a pulse height of the electrical control pulses according to the at least one recorded operating parameter and the ageing induced varying colour change; and regulating a predetermined luminance of the light emitted from the organic layer ( 1 c) during the course of the pulsed operation by adjusting a pulse length of the electric control pulses for regulating the predetermined luminance of the light emitted from the organic layer ( 1 c).
Owner:NOVALED GMBH

Electrolytic method for manufacturing aluminum-manganese alloy in fluoride-chloride molten salt system

InactiveCN102912382AHigh in magnesiumIncrease volatile lossElectrolysisManganese
The invention aims to provide an electrolytic method for manufacturing aluminum-manganese alloy in a fluoride-chloride molten salt system. The electrolytic method includes that in an electrolytic bath, inert metal molybdenum is used as a cathode and is placed at a lower portion of the electrolytic bath, and graphite is used as an anode; an electrolyte comprises 39% of NaCl, 50% of KCl and 11% of AlF3, is prepared according to the mass ratio and is heated, so that the temperature of the electrolyte ranges from 680 DEG C to 730 DEG C; MgCl2 is added into the electrolyte after the electrolyte is melted, and the quantity of the added MgCl2 accounts for 40-75% of the mass of the AlF3; direct-current power is switched on for electrolysis, the electrolytic temperature ranges from 680 DEG C to 730 DEG C, the current density of the cathode ranges from 5.2A/cm<2> to 8.7A/cm<2>, the current density of the anode ranges from 0.6A/cm<2> to 1.1A/cm<2>, and the voltage of the bath ranges from 4.7V to 6.1V; and liquid Al-Mg alloy is deposited at a position close to the cathode of the electrolytic bath after electrolysis is carried out for 1.5 to 4 hours, and is cooled down to obtain the solid Al-Mg alloy. The electrolytic method has the advantages that a process of a production technology can be greatly shortened, the technology is simple, energy is saved, and the purity of the product is high.
Owner:HARBIN ENG UNIV
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