319results about "Rhenium compounds" patented technology

Disclosed is a process that relates to the recovery of a metal catalyst from an oxidizer purge stream produced in the synthesis of carboxylic acid, typically terephthalic acid. The process involves the addition of a wash solution to a high temperature molten dispersion to recover the metal catalyst and then subjecting an aqueous mixture or purified aqueous mixture so formed to a single stage extraction to remove organic impurities to produce an extract stream and a raffinate stream comprising the metal catalyst.

The invention discloses a method for preparing a precursor for chemical vapor deposition of metallic rhenium and belongs to the technical field of material preparation. According to the method, ReCl5 is made to react in an oxidizing atmosphere, efficient solid-liquid-gas separation is conducted on reactants and products with a sand core filter bulb so that reactants, reaction products and waste gas can be effectively separated, the reaction products ReOCl4 and ReO3Cl are gathered in a collection vessel heated by an oil bath pan at the same time, oxygen introduction is stopped after reaction ends, circulation of inert gases is maintained, a tube furnace is cooled, the oil bath pan is heated at the same time to enable ReO3Cl to volatilize to enter a rectification unit to be collected, ReOCl4 is purified, and then the high-purity precursor ReOCl4 for chemical vapor deposition of metallic rhenium is obtained. By the adoption of the method, reaction efficiency is high, ReOCl4 and ReO3Cl are separated through rectification, and the purity of the product ReOCl4 is improved.

A single crystalline ternary nanostructure having the formula AxByOz, wherein x ranges from 0.25 to 24, and y ranges from 1.5 to 40, and wherein A and B are independently selected from the group consisting of Ag, Al, As, Au, B, Ba, Br, Ca, Cd, Ce, Cl, Cm, Co, Cr, Cs, Cu, Dy, Er, Eu, F, Fe, Ga, Gd, Ge, Hf, Ho, I, In, Ir, K, La, Li, Lu, Mg, Mn, Mo, Na, Nb, Nd, Ni, Os, P, Pb, Pd, Pr, Pt, Rb, Re, Rh, Ru, S, Sb, Sc, Se, Si, Sm, Sn, Sr, Ta, Tb, Tc, Te, Ti, Ti, Tm, U, V, W, Y, Yb, and Zn, wherein the nanostructure is at least 95% free of defects and / or dislocations.

The present invention describes methods for preparing high quality nanoparticles, i.e., metal oxide based nanoparticles of uniform size and monodispersity. The nanoparticles advantageously comprise organic alkyl chain capping groups and are stable in air and in nonpolar solvents. The methods of the invention provide a simple and reproducible procedure for forming transition metal oxide nanocrystals, with yields over 80%. The highly crystalline and monodisperse nanocrystals are obtained directly without further size selection; particle size can be easily and fractionally increased by the methods. The resulting nanoparticles can exhibit magnetic and / or optical properties. These properties result from the methods used to prepare them. Also advantageously, the nanoparticles of this invention are well suited for use in a variety of industrial applications, including cosmetic and pharmaceutical formulations and compositions.

The present invention is directed to a process for making an amorphous nanostructured cation-doped manganese oxide material useful as an ion intercalation host for rechargeable batteries, including the steps of preparing a solution containing cation permanganate combined optionally with a cation donor compound, mixing the solution with a reducing agent to yield a hydrogel comprising a manganese oxide compound, cryogenically freezing the hydrogel, drying the frozen gel to yield a cryogel amorphous nanostructured cation-doped manganese oxide, and heat treating the dried cryogel.

Disclosed is a positive active material for a rechargeable lithium battery. The positive active material includes at least one compound represented by formulas 1 to 4 andl a metal oxide or composite metal oxide layer formed on the compound. <table-cwu id="TABLE-US-00001"> <number>1< / number> <tgroup align="left" colsep="0" rowsep="0" cols="3"> <colspec colname="OFFSET" colwidth="42PT" align="left" / > <colspec colname="1" colwidth="77PT" align="left" / > <colspec colname="2" colwidth="98PT" align="center" / > <row> <entry>< / entry> <entry>< / entry> < / row> <row> <entry>< / entry> <entry namest="OFFSET" nameend="2" align="center" rowsep="1">< / entry> < / row> <row> <entry>< / entry> <entry>LixNi1-yMnyF2< / entry> <entry>(1)< / entry> < / row> <row> <entry>< / entry> <entry>LixNi1-yMnyS2< / entry> <entry>(2)< / entry> < / row> <row> <entry>< / entry> <entry>LixNi1-y-zMnyMzO2-aFa< / entry> <entry>(3)< / entry> < / row> <row> <entry>< / entry> <entry>LixNi1-y-zMnyMzO2-aSa< / entry> <entry>(4)< / entry> < / row> <row> <entry>< / entry> <entry namest="OFFSET" nameend="2" align="center" rowsep="1">< / entry> < / row> < / tgroup> < / table-cwu> (where M is selected from the group consisting of Co, Mg, Fe, Sr, Ti, B, Si, Ga, Al, Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ac, Th, Pa, U, Np, IPu, Am, Cm, Bk, Cf, Es, Fm, Md, No and Lr, 0.95<=x<=1.1, 0<=y<=0.99, 0<=,z<=0.5, and 0<=a<=0.5)

The invention provides methods for reduction of metal oxide particles using a high temperature solar aerosol reactor. The invention also provides metal-oxide based processes for the generation of hydrogen from water splitting using a high temperature solar aerosol reactor. In addition, the invention provides solar thermal reactor systems suitable for use with these processes.

A positive plate material for lithium secondary cells stably exhibiting excellent performance including the cell initial capacity, cycle characteristics, and the safety. The material is produced by dripping an aqueous solution of a salt (e.g., cobalt sulfate) of a doping element (e.g., a transition metal, an alkaline metal, an alkaline-earth metal, B, or Al) into an alkaline solution, a carbonate solution, or a hydrogencarbonate solution in any one of which a compound (e.g., manganese oxide) of a metal (Mn, Co, Ni, or the like) which is the major component of the positive plate material so as to precipitate the compound of the doping element on the major component compound and to cover the major component compound, mixing the major component compound covered with the doping element with a lithium compound (e.g., lithium carbonate), and firing the mixture.

The present invention provides for a device for reducing a volatile organic compound (VOC) content of a gas comprising a manganese oxide (MnOx) catalyst. The manganese oxide (MnOx) catalyst is capable of catalyzing formaldehyde at room temperature, with complete conversion, to CO2 and water vapor. The manganese oxide (MnOx) catalyst itself is not consumed by the reaction of formaldehyde into CO2 and water vapor. The present invention also provides for a device for reducing or removing a particle, a VOC and / or ozone from a gas comprising an activated carbon filter (ACF) on a media that is capable of being periodically regenerated.

The LixMn2O4 powder for cathode active material of a lithium secondary battery of the present invention is prepared by a method of comprising the steps of mixing an acetate aqueous solution using Li acetate and Mn acetate as metal precursors, and a chelating agent aqueous solution using PVB, GA, PAA or GC as a chelating agent; heating the mixed solution at 70 DIFFERENCE 90 DEG C. to form a sol; further heating the sol at 70 DIFFERENCE 90 DEG C. to form a gel precursor; calcining the produced gel precursor at 200 DIFFERENCE 900 DEG C. for 5 DIFFERENCE 30 hours under atmosphere. The cathode active material, LixMn2O4 powder for a lithium secondary battery in accordance with the present invention has a uniform particle size distribution, a high crystallinity and a pure spinel-phase, and a particle size, a specific surface area, a lattice of a cubic structure and the like can be controlled upon the preparing conditions. The present invention also provides a method of preparing LiNi1-xCoxO2 powder, which comprises the steps of providing a gel precursor using PAA as a chelating agent and hydroxide, nitrate or acetate of Li, Co and Ni as metal precursors; heating the gel precursor at 200 DIFFERENCE 900 DEG C. for 5 DIFFERENCE 30 hours to form a powder. The LixMn2O4 and LiNi1-xCoxO2 powder of the present invention can be used for a cathode active material of a lithium secondary battery such as a lithium ion battery or lithium polymer battery.

A single crystalline ternary nanostructure having the formula AxByOz, wherein x ranges from 0.25 to 24, and y ranges from 1.5 to 40, and wherein A and B are independently selected from the group consisting of Ag, Al, As, Au, B, Ba, Br, Ca, Cd, Ce, Cl, Cm, Co, Cr, Cs, Cu, Dy, Er, Eu, F, Fe, Ga, Gd, Ge, Hf, Ho, I, In, Ir, K, La, Li, Lu, Mg, Mn, Mo, Na, Nb, Nd, Ni, Os, P, Pb, Pd, Pr, Pt, Rb, Re, Rh, Ru, S, Sb, Sc, Se, Si, Sm, Sn, Sr, Ta, Tb, Tc, Te, Ti, Tl, Tm, U, V, W, Y, Yb, and Zn, wherein the nanostructure is at least 95% free of defects and / or dislocations.

A lithium-manganese composite oxide for a lithium ion battery having a good cycle property at high-temperature and battery property of high capacity is provided.A spinel type lithium-manganese composite oxide for a lithium ion battery represented by a general formula: Li1+xMn2−yMyO4 (wherein M is one or more elements selected from Al, Mg, Si, Ca, Ti, Cu, Ba, W and Pb, and, −0.1≦x≦0.2, and 0.06≦y≦0.3), and when D10, D50 and D90 are defined as a particle size at which point the cumulative frequency of volume reaches 10%, 50% and 90% respectively, d10 is not less than 2 μm and not more than 5 μm, d50 is not less than 6 μm and not more than 9 μm, and d90 is not less than 12 μm and not more than 15 μm, and BET specific surface area thereof is greater than 1.0 m2 / g and not more than 2.0 m2 / g, and the tap density thereof is not less than 0.5 g / cm3 and less than 1.0 g / cm3.

The invention relates to a method for preparing ammonium perrhenate from waste liquid containing molybdenum and rhenium. In the technical scheme of the invention, the method comprises the following steps of: adding hydrogen peroxide into the waste liquid containing molybdenum and rhenium until the solution turns to yellow, then adding a mixed agent until the pH of the solution is 6 to 7, separating by filter pressing, collecting the filtrate, absorbing the filtrate by a resin exchange column, stopping adsorption until the concentration of rhenium in effluent is constant, eluting with NH3.H2O,collecting the eluate, heating to concentrate the eluate at 98-100 DEG C, cooling, and crystallizing to obtain ammonium perrhenate. The mixed agent is a mixture of calcium hydroxide and calcium oxidein a weight ratio of 5:1. According to the invention, the waste liquid containing molybdenum and rhenium, particularly the absorption liquid of the flue gas during molybdenum roasting, is used as theraw material; the enrichment of rhenium is increased by about 20 times; ammonia water is determined as the eluent of rhenium; the elution rate of rhenium is higher than 98%; the recovery rate of rhenium is higher than 93%, the purity of the ammonium perrhenate product is higher than 99.5%, and the economic, social and environmental benefits are significantly improved.

A closed loop combustion system for the combustion of fuels using a molten metal oxide bed.

The invention relates to systems and processes for recovery and / or extraction of metal values from ore or other raw material containing oxides of the metal and to precipitation of oxides of metals that have oxidation states and / or pollutant loading capacities equal to or greater than that of the metal oxides in the ore or other raw material which are suitable, amongst other uses, as a sorbent for capture and removal of target pollutants from industrial and other gas streams. Further, the invention relates to oxides of metals so recovered and precipitated.

The invention relates to a process for recovering the transition metal component of catalysts used in the hydroconversion of heavy hydrocarbonaceous materials. In accordance with the invention, a slurry of a transition metal catalyst and hydrocarbon is catalytically desulfurized resulting in a desulfurized product and a solid residue containing the transition metal. The transition metal may be recovered by coking the residue and then dividing the coker residue into two portions are combusted with the flue dust from the first combustion zone being conducted to the second combustion zone. The flue dust from the second combustion zone is treated with ammonia and ammonium carbonate in order to obtain ammonium molybdate.

The present invention relates to a method for manufacturing a valuable-metal sulfuric-acid solution from a waste battery, and to a method for manufacturing a positive electrode active material. The method for manufacturing the valuable-metal sulfuric-acid solution includes: a step of obtaining valuable-metal powder containing lithium, nickel, cobalt, and manganese from waste batteries; a step of acid-leaching the valuable-metal powder under a reducing atmosphere in order to obtain a leaching solution; and a step of separating the lithium from the leaching solution so as to obtain a sulfuric-acid solution containing the nickel, cobalt, and manganese.

Methods of forming a nanocrystal are provided. The nanocrystal may be a binary nanocrystal of general formula M1A or of general formula M1O, a ternary nanocrystal of general formula M1M2A, of general formula M1AB or of general formula M1M2O or a quaternary nanocrystal of general formula M1M2AB. M1 is a metal of Groups II-IV, Group VII or Group VIII of the PSE. A is an element of Group VI or Group V of the PSE. O is oxygen. A homogenous reaction mixture in a non-polar solvent of low boiling point is formed, that includes a metal precursor containing the metal M1 and, where applicable M2. For an oxygen containing nanocrystal the metal precursor contains an oxygen donor. Where applicable, A is also included in the homogenous reaction mixture. The homogenous reaction mixture is under elevated pressure brought to an elevated temperature that is suitable for forming a nanocrystal.

Aqueous solutions containing lead, zinc and manganese are treated to recover these metals by sequential solvent extraction steps. Solvent extractants are selected to extract preferentially lead, then zinc and then manganese in that order. Any interfering metals are removed (as by ion exchange) before extraction. The loaded extractant phases are stripped with selected acids and lead, zinc and manganese each recovered from the strip solutions. Optionally calcium can be recovered when present. A preferred type of extractant (for lead especially) is substituted monothiophosphinic acids. A closed loop system is described which is advantageous with leachate from sulphide and carbonate ores.

Solvent extraction of one or more metal ions from an aqueous solution in the presence of hydrocarbon-soluble aminomethylenephosphonic acid derivatives.

Method of recovering active material from waste battery materials comprises: (1) an electrode material mixture recovery step of separating an electrode from the waste battery material to recover an electrode material mixture including the active material, a conductive material, and a binder from the electrode; (2) an activation agent mixing step of mixing an activation agent including one or more alkali metal compounds with the recovered electrode material mixture; (3) an activation step of heating the obtained mixture to a retention temperature not less than a melting start temperature of the activation agent to activate the active material included in the mixture; and (4) an active material recovery step of recovering the activated active material from a mixture obtained as a result of cooling after the activation step.

The invention provides granular secondary particles of a lithium-manganese composite oxide which are granular secondary particles made up of aggregated crystalline primary particles of a lithium-manganese composite oxide and have many micrometer-size open voids therein, the open voids having an average diameter in the range of from 0.5 to 3 μm and the total volume of the open voids being in the range of from 3 to 20 vol. % on average based on the total volume of the granules. These particles are suitable for use as a constituent material for non-aqueous electrolyte secondary batteries showing high-output characteristics. The invention further provides a process for producing the granular secondary particles of a lithium-manganese composite oxide which includes spray-drying a slurry prepared by dispersing a fine powder of a manganese oxide, a lithium source, an optional compound containing at least one element selected from Al, Co, Ni, Cr, Fe, and Mg, and an agent for open-void formation to thereby granulate the slurry and then calcining the granules at a temperature of from 700 to 900° C.

A method for recovering and recycling catalyst coated fuel cell membranes includes dissolving the used membranes in water and solvent, heating the dissolved membranes under pressure and separating the components. Active membranes are produced from the recycled materials.

An oxygen reduction electrode, e.g., an air cathode, comprising manganese oxides having octahedral molecular sieve structures as active catalyst materials and use of such an electrode as a component of a metal-air cell.