The invention discloses a hollow
graphene ball and a preparation method and application of the hollow
graphene ball. The preparation method of the hollow
graphene ball includes the steps that
powder and oxidized graphene are dispersed in liquid at the weight ratio
ranging from 1 : 0.01 to 1 : 20, and dispersed suspension liquid is obtained, wherein
powder is nanometer
powder and / or
micrometer powder;
spray drying is conducted on the dispersed suspension liquid, and a precursor is obtained; in protective gas,
reduction treatment is conducted on the precursor at the temperature
ranging from 200 DEG C to 1100 DEG C, the precursor is cooled to the
room temperature after being treated, and then reduzate is obtained, wherein reduzate contains powder or reactant of powder; the reduzate is mixed with a
solvent to make powder or the reactant of powder dissolved, and then the hollow graphene ball is obtained after solids are separated. The preparation method is simple in operation, environment friendliness is achieved, the yield is high, cost is low, and the preparation method is suitable for industrialized
mass production. The hollow graphene ball has excellent electrochemical performance, and can be used as a positive
electrode material of a
lithium air cell.