The invention provides an improvement to an inorganic / organic composite
proton fuel
cell exchange membrane and a preparation method thereof, which is characterized in that the inorganic / organic composite is composed by embedding perfluoro
sulfonated polymer or non-perfluoro
sulfonated polymer into SiO2 and / or TiO2 of a three-dimensional mesh structure.
Inorganic particles form into a
network structure with each other in the membrane, so as to not only enhance the
mechanical strength of the
composite membrane but also to obtain the
composite membrane with good
moisture, thereby effectively solving the contradiction between the
proton exchange membrane and
high conductivity rate at high temperatures, therefore, not only the obtained
composite membrane has characteristics of high temperature and
high conductivity rate, lower swelling rate of water absorption and the like, but also
mechanical strength and
thermal stability of the composite membrane can be correspondingly increased so as to improve the service life. The obtained
membrane structure is characterized in that: the
inorganic particles represent an orderly, uniform and open three-dimensional mesh structure, and the
organic polymer substance of the conductive
proton is filled in the three-dimensional mesh of the
inorganic particles. The structural characteristic provides a good space configuration for adulterating other conductive substances (such as
heteropoly acid). The inorganic / organic composite proton fuel
cell exchange membrane has advantages that the obtained composite membrane is not only superior in performance, but also plays an important role in improving the performance of the fuel
cell and reducing the battery costs, in addition, enriches the preparation technology of proton exchange membranes.