232results about How to "Improve charge and discharge cycle characteristics" patented technology

An electrode for a rechargeable lithium battery which includes a thin film composed of active material that expands and shrinks as it stores and releases lithium, e.g., a microcrystalline or amorphous silicon thin film, deposited on a current collector, characterized in that said current collector exhibits a tensile strength (=tensile strength (N/mm²) per sectional area of the current collector material×thickness (mm) of the current collector) of not less than 3.82 N/mm.

A lithium ion conductive solid electrolyte formed by sintering a molding product containing an inorganic powder and having a porosity of 10 vol % or less, which is obtained by preparing a molding product comprising an inorganic powder as a main ingredient and sintering the molding product after pressing and/or sintering the same while pressing, the lithium ion conductive solid electrolyte providing a solid electrolyte having high battery capacity without using a liquid electrolyte, usable stably for a long time and simple and convenient in manufacture and handling also in industrial manufacture in the application use of secondary lithium ion battery or primary lithium battery, a solid electrolyte having good charge/discharge cyclic characteristic in the application use of the secondary lithium ion battery a solid electrolyte with less water permeation and being safe when used for lithium metal-air battery in the application use of primary lithium battery, a manufacturing method of the solid electrolyte, and a secondary lithium ion battery and a primary lithium battery using the solid electrolyte.

A lithium secondary battery comprising an electrode in which an active material layer which includes an active material that electrochemically occludes and releases lithium is formed on a current collector, wherein cracks are formed in the active material layer by occlusion and release of lithium ions and thereafter a solid electrolyte is formed in the cracks in the active material layer.

An electrode for a rechargeable lithium battery characterized in that thin films of active material capable of lithium storage and release, i.e., microcrystalline or amorphous silicone thin films are deposited on opposite faces of a plate-form current collector.

A nonaqueous electrolyte secondary battery with excellent charging/discharging cycle characteristics is provided, more specifically a nonaqueous electrolyte secondary battery in which deterioration of the conductivity of a negative electrode due to charging/discharging cycle is suppressed and a method for manufacturing the same are provided. The nonaqueous electrolyte secondary battery includes: a positive electrode and a negative electrode that are capable of reversibly absorbing and desorbing Li ions; and a nonaqueous electrolyte having lithium ion conductivity. The negative electrode includes a collector and active material particles that are disposed on a surface of the collector. The active material particles include Si and at least one element R selected from the group consisting of Sn, In, Ga, Pb and Bi. Metallic bond including the element R is formed between the active material particles.

In a negative electrode material for lithium secondary batteries, basic material particles include one of phase A having silicon as a main component, and a mixed phase of phase B including an intermetallic compound of a transition metal element and silicon and the phase A. The phase A or the mixed phase is microcrystalline or amorphous. A carbon material is adhered to surfaces of the basic material particles, and a film containing a silicon oxide is formed on remained surface portions.

A negative electrode including a negative electrode current collector, first protrusions on a surface of the negative electrode current collector, a separation-stopping area on at least a part of a surface of each first protrusion, and a negative electrode active material layer including a negative electrode active material and formed on at least a top face of the first protrusion. This structure suppresses the separation of the negative electrode active material layer from the negative electrode current collector, the degradation of the current collecting ability, and the deformation of the negative electrode itself. A lithium ion secondary battery including this negative electrode has a high battery capacity, a high energy density, and an excellent charge/discharge cycle characteristic, and is capable of stably maintaining a high power over an extended period of time.

The present invention relates to a method for improving charge/discharge cycle characteristics of a lithium secondary battery using a Si based anode active material, the method comprising surface-treating a surface of an anode current collector to have specific morphology, and preferably vapor-depositing a silicon film, as the anode active material by sputtering under application of bias voltage to the surface-treated anode current collector, and/or disposing an adhesive layer between the surface-treated anode current collector and silicon film, so as to reinforce bondability between the anode current collector and active material, ultimately leading to improvement of charge/discharge characteristics of the battery.

The invention provides a cathode active material, a cathode, and a non-aqueous electrolyte secondary battery. The cathode active material has: a composite oxide particle containing at least lithium and one or a plurality of transition metals; and a coating layer provided on at least a part of the composite oxide particle. The coating layer contains at least one kind of element M differing from a main transition metal element A forming the composite oxide particle and selected from Groups 2 to 16 of the periodic table and a halogen element X. In the coating layer, the element M and the halogen element X exhibit different distribution states. It is, therefore, desirable to provide a cathode active material, a cathode, and a non-aqueous electrolyte secondary battery in which a large capacitance and excellent charge/discharge cycle characteristics are obtained and an increase in internal resistance can be suppressed.

A cathode material for a secondary battery containing a cathode active material represented by the general formula Li_nFePO₄ (wherein n represents a number from 0 to 1) as a primary component and molybdenum (Mo), wherein the cathode active material Li_nFePO₄ is composited with the Mo. In a preferred embodiment, the cathode material has conductive carbon deposited on the surface thereof.

The non aqueous secondary battery electrode of the present invention includes a mixture layer and a porous layer formed on the surface of the mixture layer. The mixture layer includes an electrode material expressed by the composition formula SiO_x where x in the composition formula satisfies 0.5≦x≦1.5, a conductive material and at least one binder selected from the group consisting of polyimide, polyamideimide and polyamide. The porous layer includes an insulating material unreactive with Li.

The invention provides an anodic carbon material for a lithium secondary battery and a lithium secondary battery anode having excellent charge/discharge cycle characteristics, and a lithium secondary battery using the same. More specifically, an anodic carbon material for a lithium secondary battery according to the present invention comprises: composite particles composed of silicon-containing particles containing an alloy, oxide, nitride, or carbide of silicon capable of occluding and releasing lithium ions and a resinous carbon material enclosing the silicon-containing particles; and a network structure formed from nanofibers and/or nanotubes that bond to surfaces of the composite particles and that enclose the composite particles, and wherein: the network structure contains silicon.

There is provided an electrode for a lithium secondary battery where particles, composed of an active material capable of occluding and releasing lithium, are arranged on a current collector, the active material particle being directly bonded to the surface of the current collector in a state where the bottom of the active material particle is imbedded in a concave portion formed on the surface of the current collector. A second particle layer may be provided on a first particle layer comprising the active material particles directly bonded to the surface of the current collector.

A non-aqueous secondary battery contains a positive electrode, a negative electrode, a separator and a non-aqueous electrolytic solution. The positive electrode contains a layered structure lithium-containing compound oxide, or a spinel lithium-containing compound oxide containing manganese as an active material. The non-aqueous electrolytic solution contains at least one additive selected from a sulfonic acid anhydride, a sulfonate ester derivative, a cyclic sulfate derivative and a cyclic sulfonate ester derivative, and a vinylene carbonate or a derivative of the vinylene carbonate.

In a lithium ion secondary battery including a positive electrode, a negative electrode containing an alloy-based negative electrode active material, a separator, a positive electrode lead, a negative electrode lead, a gasket, and an outer case, the positive electrode is allowed to contain an oxygen deficient non-stoichiometric oxide, or an oxygen removing layer containing an oxygen deficient non-stoichiometric oxide is provided between the positive electrode and the separator. In a lithium ion secondary battery containing the alloy-based negative electrode active material, a reaction between oxygen generated in the positive electrode and the alloy-based negative electrode active material, and heat generation accompanying the reaction are prevented.

A negative electrode for a lithium secondary battery obtained by sintering an active material layer on a current collector under a non-oxidizing atmosphere after the active material layer including primary particles of an active material containing silicon and/or a silicon alloy and a binder is formed on an electrically conductive metal foil as a current collector. A mean diameter of primary particles of the active material is less than 1 mum, the primary particles are dispersed uniformly in the active material layer, and the primary particles and the binder are uniformly mixed and distributed.

A lithium battery which has an anode, a cathode having a compound capable of intercalating and deintercalating lithium, a separator interposed between the cathode and the anode, and an electrolyte solution having an electrolyte solute dissolved in a nonaqueous solvent. The nonaqueous solvent includes a mixed solvent containing 8 to 15% by volume of ethylene carbonate, 10 to 35% by volume of γ-butyrolactone, 35 to 65% by volume of at least one linear carbonate selected from the group consisting of dimethyl carbonate, diethyl carbonate, ethylmethyl carbonate, methylpropyl carbonate, ethylpropyl carbonate and methylbutyl carbonate and 8 to 15% by volume of fluorobenzene, and 0.5 to 9 parts by volume of vinylene carbonate based on 100 parts by volume of the mixed solvent. The nonaqueous solvent may further include 0.05 to 5 parts by volume of vinyl sulfone, isooxazole or a mixture thereof based on 100 parts by volume of the mixed solvent.

There is provided a method for manufacturing the lithium ion secondary batteries includes a mixing step of mixing a phenol resin and a resin composition containing silica particles so as to obtain a mixture, a spraying step of spraying the mixture obtained in the mixing step so as to form liquid droplets, a first thermal treatment step of carrying out a first thermal treatment on the liquid droplets obtained in the spraying step so as to generate a carbon precursor, and a second thermal treatment step of carrying out a second thermal treatment, which is carried out at a higher temperature than the first thermal treatment, on the carbon precursor obtained in the first thermal treatment step so as to generate a carbon material containing carbon and silicon oxide represented by SiOx (0<X<2).

A high voltage dynamic lithium ion built-in battery is provided, which comprises a shell filled with electrolyte and at least two battery cells inside the shell. The positive and negative electrodes of each of the lithium ion battery cells are connected in series to form a battery cells body that will be wholly encapsulated into a shell. The invention is characterized in separately placing each of the said battery cells connected in series in each battery cell cabin. The invention is scientifically designed with refined and reasonable structure. Based on the characteristics of the invention, the said invention greatly improves its structure and lowers the possible damage due to the rise in temperature when using the battery. The structure can possibly increase the monomeric voltage of the lithium ion battery from 2.0V to hundreds of V, and brings better property of recharge cycles, meeting the requirement in various fields and under different loading conditions.

In a non-aqueous electrolyte comprising an organic solvent and a solute dissolved in the organic solvent, a lithium salt containing at least one organic anion selected from phthalimide, a derivative of phthalimide, phthalimidine and a derivative of phthalimidine is used as the solute. Such non-aqueous electrolyte is not liable to react with the negative electrode in a primary battery and a secondary battery during a long-term storage at high temperatures. As a consequence, by using this non-aqueous electrolyte, a non-aqueous electrolyte battery having an excellent storage property can be obtained; and the charge/discharge cycle characteristics are improved in a secondary battery.</PTEXT>