The invention discloses a
metal nanocrystalline-anchoring molecule synergistic
passivation perovskite solar cell, which comprises a conductive substrate, an
electron transport layer, a
perovskite layer, a
hole transport layer and a
metal electrode which are sequentially stacked from bottom to top, and is characterized in that the
perovskite layer is a composite layer formed by embedding
metal nanocrystalline-anchoring molecule into a perovskite
grain boundary; wherein the metal nanocrystalline-anchoring molecule is obtained by irradiating a
mixed solution of an anchoring molecule and a metal material with a
laser beam, the
mixed solution of the anchoring molecule and the metal material is obtained by dispersing the anchoring molecule and the metal material into an anti-
solvent, the anchoring molecule is mercaptan containing a long
fluorocarbon chain, and the metal material is gold,
platinum or a high-entropy
alloy. The invention also provides a preparation method of the
cell. Accordingto the
perovskite solar cell, metal nanocrystalline-anchoring molecules are introduced into the perovskite layer, perovskite
grain boundary defects are passivated, extraction and transmission of
photon-generated carriers are improved, and compared with an initial
perovskite solar cell, the
perovskite solar cell is high in
photoelectric conversion efficiency and good in stability.