A hybrid solar cell with zinc oxysulfide serving as an electron transfer layer is composed of a transparent conducting glass substrate, the zinc oxysulfide electron transfer layer, an inorganic hybrid perovskite material, a 2,2',7,7'-tetrakis[N,N-di(4-nethoxyphenyl)amino]-9,9'-spirobifluorene hole transport layer and an Au metal back electrode layer, wherein the zinc oxysulfide electron transfer layer, the inorganic hybrid perovskite material, the 2,2',7,7'-tetrakis[N,N-di(4-nethoxyphenyl)amino]-9,9'-spirobifluorene hole transport layer and the Au metal back electrode layer are sequentially combined to form a laminated structure, the inorganic hybrid perovskite material is CH3NH3PbX3, and X is Cl or Br or I. The hybrid solar cell and a preparation method have the advantages that the hybrid solar cell has the large specific surface area and the good electron transfer capacity when the zinc oxysulfide serves as the electron transfer layer, electron-hole combination is effectively restrained, the photoelectric conversion efficiency is high, and the preparation method is simple in process, low in reaction temperature, high in efficiency, abundant in raw materials, low in cost, green, free of pollution, and suitable of industrial large-scale production.