The invention relates to a device structure of an organic light-emitting
diode (
OLED), and especially relates to a highly-efficient organic electroluminescent device based on a
fluorescence doped luminescent layer. The organic electroluminescent device comprises a transparent substrate, a transparent
anode, a cavity transmission layer, a first
exciton barrier layer, a luminescent layer, a second
exciton barrier layer, an
electronic transmission layer, an electronic injecting layer and a
metal cathode. The luminescent layer is formed by mixing a main body and a guest body. The main body material is organic small molecules whose energy difference between a first kind single heavy excitation state and a triplet excitation state is quite small. The guest body material is dye molecules with high
fluorescence efficiency, like
quinacridone derivatives. The highly-efficient organic electroluminescent device based on a
fluorescence doped luminescent layer is advantageous in that the external
quantum efficiency exceeds 5% of theoretic limit efficiency of a conventional fluorescence device, and the
luminescence efficiency of a fluorescent
OLED device can be effectively improved; the luminescent device of the invention is high in brightness, low in starting
voltage, high in efficiency, and low in efficiency roll-off.