The invention relates to a
copper complex based on a dipyridine bisamide organic ligand and Keggin type
polyoxometalate, its synthetic method and its application. A molecular formula is one of the following formulas: [Cu2(L<1>)3(H2O)6(SiMo12O40)].2H2O; [Cu2(L<2>)3(H2O)6(SiMo12O40)].9H2O; [Cu2(L<2>)3(H2O)6(SiW12O40)].6H2O; [Cu2(L<3>)3(H2O)6(SiMo12O40)].6H2O; [Cu2(L<3>)3(H2O)6(SiW12O40)].6H2O; wherein L<1> is N, N'-di(3- pyridylformamido)-1,2-ethane; L<2> is N, N'-di(3-pyridylformamido)-1,4-
butane; L<3> is N, N'-di(3-pyridylformamido)-1,6-
hexane. The method comprises the following steps: addingdeionized water in the Cu(NO3).3H2O, Keggin type
polyoxometalate, dipyridine diamide organic ligand, stirring under
room temperature, regulating pH value, dumping in a
high pressure reaction vessel and heating, insulating under hydrothermal condition, cooling to the
room temperature to obtain bulk blue green crystals, alternatively cleaning by deionized water and
ethanol, naturally
drying under
room temperature to prepare the
copper complex based on dipyridine bisamide organic ligand and Keggin type
polyoxometalate. The complex has the advantages of simple synthetic method, easy
crystallization, high synthesis yield, strong affinity capability to water-soluble pollutants and good
catalytic degradation effect, and can be used as
photocatalysis materials.