The invention discloses a polyarylester
liquid crystal material with photoelectricity activity and containing azo and
aniline segments and a preparing method of the polyarylester
liquid crystal material, belonging to the filed of functional
polymer materials. The method comprises: reacting
azobenzene diacyl
chloride with different
substituent groups with parahydroxydiphenylamine to prepare an azo ester
monomer, then performing oxidative
coupling polymerization on the azo ester
monomer and p-phenylenediamine to prepare oxidation azo polyarylester
liquid crystal material, and through reducing of hydrazine
hydrate and
ammonium hydroxide, obtaining the polyarylester liquid
crystal material with photoelectricity activity and containing azo and
aniline segments. The polyarylester liquid
crystal material with photoelectricity activity and containing azo and
aniline segments has good solubleness and
thermal stability, has electrochemical activity similar to an aniline
oligomer and photoinduced isomerism of an
azo polymer, and can produce
lyotropic liquid
crystal in organic solvents such as N,N-
dimethylacetamide and dimethylsulfoxide. The material has good application potential in aspects of biosensors, optical elements and electromagnetic materials, and the like.