The invention discloses a resource recycling method for 80 ferrovanadium slag, which adopts the following steps: (1) sulfating roasting: mixing the ferrovanadium slag and sulfuric acid, stirring, and then conducting sulfating roasting to obtain roasting slag; (2) leaching: mixing the roasting slag and deionized water or diluted acid, stirring and leaching, and then filtering to obtain leaching liquid; (3) enriching vanadium: adding ammonium sulfate into the leaching liquid, heating and dissolving, and then cooling, crystallizing, and filtering to obtain aluminum ammonium sulfate crystal and crystallization post liquid; (4) oxidizing and sinking vanadium: adding oxidant into the crystallizing post liquid to conduct oxidizing, converting all V3+ and V4+ in the crystallizing post liquid into V5+, then dropwise adding ammonia water, stirring and filtering to obtain ammonium polyvanadate sediment and filtrate, and roasting ammonium polyvanadate to obtain vanadium pentoxide; and (5) magnesium separating reacting: distilling and concentrating the filtrate, cooling, and filtering to obtain magnesium sulfate crystal. The method has the advantages of being simple in technology process, low in energy consumption and friendly in environment.