The invention relates to a preparation method for a superhydrophobic coating with condensation microdroplet self-bouncing properties. The preparation method comprises the following steps: with a waterborne chain type silica sol as a raw material, carrying out dilution and dispersion with an alkaline aqueous solution so as to effectively prevent the waterborne silica sol from agglomeration, then carrying out dispersing in a volatile organic solution, adding tetraethyl orthosilicate, fluoroalkyl silane and the like into the obtained dispersion liquid, then subjecting silica sol particles to surface modification, and carrying out continuous mechanical stirring so as to obtain the superhydrophobic coating. The coating can be applied to a variety of soft and hard substrates through manners of spraying, dipping, pulling, rolling or brushing, thereby obtaining the superhydrophobic surface with a porous nanometer structure, wherein the porous nanometer structure also enables condensation microdroplets to obtain self-bouncing properties. The coating has extensive application in the aspects of surface self-cleaning and corrosion and mildew prevention, especially in the aspects of condensation heat transfer, water collection, frost prevention, ice resisting, etc. The preparation method provided by the invention has the characteristics of simple preparation process and equipment, easiness in operation, low cost, etc., and is applicable to large-scale preparation and industrial production.