The invention relates to a superhydrophobic coating hybridized with superhydrophilic particles and a preparation method thereof. The substrate was ultrasonically cleaned with acetone, absolute ethanol, and deionized water for 15 minutes in order to remove oil and dust on the surface; then, it was rinsed with absolute ethanol, dried with cold air, and set aside. on nano-SiO 2 The sol was modified with fluorosilane to obtain a superhydrophobic coating spray solution, and the superhydrophilic monodisperse spherical nano-SiO 2 The solution, silicon micropowder, and glass microspheres are respectively added to the above-mentioned superhydrophobic coating spray solution, stirred evenly, sprayed on the substrate, and cured to obtain a superhydrophobic coating hybridized with superhydrophilic particles. This coating not only has low adhesion superhydrophobicity, but also has significantly higher condensation efficiency and dew drop desorption than superhydrophobic coatings. The preparation process of the invention is simple, pollution-free, easy to operate, good in appearance quality and low in cost, and has broad application prospects and huge market benefits in heat exchangers, water collection, seawater desalination and the like.