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180results about How to "Low melt index" patented technology

Multi-stage wire feeding printing head for 3D printing of continuous fiber reinforced composite materials

A multi-stage wire feeding printing head for 3D printing of continuous fiber reinforced composite materials comprises a fiber guiding pipe fixed to the upper surface of a first-stage heating block. An inner hole channel of the fiber guiding pipe forms a fiber channel. A first-stage throat pipe is fixed to one side of the first-stage heating block. An inner hole channel of the first-stage throat pipe forms a first-stage inner hole channel. High polymer materials penetrate the first-stage inner hole channel and enter a melting cavity of the first-stage heating block. The first-stage heating block is fixed above a second-stage heating block. A second-stage throat pipe is fixed to one side of the second-stage heating block. A second-stage throat pipe inner hole channel forms a second-stage inner hole channel. High-performance thermoplastic materials penetrate the second-stage inner hole channel and enter a melting cavity of the second-stage heating block. As analogized according to the same structure, finally, all the heating blocks are fixed to the upper face of the last-stage heating block, and a spray nozzle is fixed to the lower surface of the last-stage heating block. The multi-stage wire feeding printing head is adopted, multi-stage wrapping can be well performed on base materials for continuous fibers, and continuous fiber reinforced composite material parts with good comprehensive performance are obtained.
Owner:XI AN JIAOTONG UNIV

Preparation method of maleic anhydride drafted polypropylene resin graft polymer

ActiveCN101724128AMitigation of thermo-oxidative degradationImproved melt elasticityMaleic anhydrideDouble bond
The invention provides a preparation method of a maleic anhydride drafted polypropylene resin graft polymer, relating to a maleic anhydride melt-drafted polypropylene resin technology. The polypropylene resin is an antioxidant-free polypropylene powder. The preparation method comprises the following steps of: melting and blending 0.1 to 1 part of antioxidant and the polypropylene powder in 100 parts by weight of the polypropylene, and then carrying out the melting free radical grafting reaction on the polypropylene resin melted and blended with the antioxidant; initiating the melting free radical grating reaction by a peroxide initiator, and introducing an auxiliary monomer except for adding grafting monomer maleic anhydride, wherein the auxiliary monomer is an organic monomer containing two or more carbon-carbon double bonds, the using amount of the auxiliary monomer is 2 to 8 parts in 100 parts by weight of the polypropylene resin, and the using amount of the maleic anhydride is 1 to 8 parts in 100 parts by weight of the polypropylene resin. The preparation method of the maleic anhydride drafted polypropylene resin can obtain the polypropylene resin graft polymer with higher molecular weight and melt strength.
Owner:CHINA PETROLEUM & CHEM CORP +1

Thermoplastic polyether ester elastomer composition as well as preparation method and application thereof

The invention discloses a thermoplastic polyether ester elastomer composition as well as a preparation method and application thereof. The thermoplastic polyether ester elastomer composition comprises 80-100 parts of polyether ester elastomer and 0.2-5 parts of isocyanate compound. The preparation method comprises the steps of adding the components to a high-speed mixer so as to be mixed at a high speed, and then adding the mixture to a double-screw extruder so as to be subjected to extruding granulation at 210-250 DEG C, thus obtaining the thermoplastic polyether ester elastomer composition. The thermoplastic polyether ester elastomer composition and the preparation method have the beneficial effects that by adding the isocyanate compound to modify the polyether ester elastomer, the melt index of the material can be obviously reduced, the tensile strength of the material can be improved, the elongation at break of the material is relatively high, and the material has good resilience effect and good dynamic / static stiffness; the process is simple, and the production cost is relatively low; the thermoplastic polyether ester elastomer composition can be used in the fields such as track traffic gaskets and the like.
Owner:KINGFA SCI & TECH CO LTD

Method for preparing long chain branched polylactic resin by combining two-step functional group reaction

ActiveCN102453250ASignificant branching effectControl the degree of branchingAntioxidantReaction rate
The invention provides a method for preparing long chain branched polylactic resin by combining two-step functional group reaction, and relates to the technical field of polymer processing. The method for preparing the long chain branched polylactic resin by combining two-step functional group reaction comprises the following steps of: (1) melting polylactic resin; (2) adding an antioxidant, anhydride polyfunctional monomers and epoxy polyfunctional monomers, and mixing uniformly; and (3) melting and blending until the reaction is finished to obtain the long chain branched polylactic, whereinbased on 100 weight parts of linear polylactic resin, the antioxidant is 0.1 to 0.5 part, the anhydride polyfunctional monomers are 0.1 to 1 part; and the epoxy polyfunctional monomers are 0.1 to 1 part; and the epoxy polyfunctional monomers have the functionality of more than or equal to 3. By the method, the reaction rate is improved by 5 to 10 times; the obtained long chain branched polylacticproduct has an obvious branching effect, the melt strength and viscosity are greatly improved, and the product material meets the requirement of forming and can be easily subjected to film making, foaming and other processes according to product requirements; and the branching degree and the melt strength of the product can be controlled to a certain extent by regulating a monomer proportion and reaction temperature.
Owner:CHINA PETROLEUM & CHEM CORP +1

Application of chain extender in improving viscosity of polyester compound, modified polyester compound and preparation method of modified polyester compound

The invention provides an application of a chain extender in improving the viscosity of a polyester compound, a modified polyester compound and a preparation method of the modified polyester compound, and belongs to the field of polyester processing. The invention provides an application of a chain extender in improving the viscosity of polyester compounds. The chain extender is a hydroxyl addition type chain extender and / or a carboxyl addition type chain extender. The chain extender is a hydroxyl addition type chain extender and / or a carboxyl addition type chain extender, and can be subjected to chain extension reaction with terminal hydroxyl or carboxyl of PBT or TPEE, so that the molecular chain of the polyester compound can be prolonged, and the molecular weight can be obviously improved, thereby enhancing the intrinsic viscosity of the polyester compound, lowering the melt index and enhancing the processability of the polyester compound. The defects of high equipment requirement, high energy consumption and low economic benefit of a traditional method such as a solid-phase tackifying technology are avoided, and the method has the advantages of short time consumption, high efficiency and good economic benefit.
Owner:新疆蓝山屯河高端新材料工程技术研究中心(有限公司) +1

Biodegradable film modified by epoxidized lignin and preparation method thereof

The invention discloses a biodegradable film modified by epoxidized lignin and a preparation method thereof. The biodegradable film comprises the following components in parts by weight: 50-95 parts of degradable plastic; 5 to 45 parts of epoxidized lignin; 0.5 to 5 parts of a plasticizer; and 0.5-3 parts of a lubricant, wherein the weight-average molecular weight of the epoxidized lignin is not less than 5000. The epoxidized lignin with a certain molecular weight is used for modifying and degrading plastic, the compatibility and dispersity of lignin in a plastic matrix are improved, meanwhile, an epoxy group of the epoxidized lignin and plastic macromolecules are subjected to a grafting chain extension reaction, and the processing performance and mechanical performance of the material areimproved.
Owner:NANJING UNIV OF TECH

Aliphatic-aromatic copolyester and preparation method thereof

The invention relates to aliphatic-aromatic copolyester and a preparation method of the aliphatic-aromatic copolyester. The method comprises the steps of allowing an ingredient a to react with an ingredient b with the existence of catalysts comprising a first catalyst and selectively comprising a second catalyst, allowing an obtained reaction mixture, an ingredient c, an ingredient d and the selectively added ingredient b to react with the existence of the first catalyst and the second catalyst, and allowing an obtained reaction mixture to be subjected to polycondensation. The first catalyst is a titanic oxide, an antimony oxide, a zinc oxide, M(OR1)n or M(-OOCR2)m; the second catalyst is a chemical compound with the chemical formula of RE(R3)3; the ingredient a contains aromatic dibasic acid and / or dibasic anhydride; the ingredient b is aliphatic dibasic alcohol; the ingredient c is aliphatic dibasic acid and / or dibasic anhydride; and the ingredient d is polyhydric alcohol, polybasic carboxylic acid or polybasic carboxylic anhydride with the degree of functionality greater than 2. The aliphatic-aromatic copolyester prepared according to the method is lower in melt index, and better in biodegradability and tensile mechanical property.
Owner:CHINA PETROLEUM & CHEM CORP +1

High-fluidity polyamide magnetic composite material and preparation method thereof

The invention discloses a high-fluidity polyamide magnetic composite material, prepared from the following ingredients in percentage by weight: 4.3-12.2wt% of polyamide resin, 85-93wt% of strontium ferrite, 0.5-1wt% of an internal lubricant, 1-3wt% of a flow modifier, 0-0.2wt% of an external lubricant, 0-0.1wt% of a primary antioxygen, 0-0.1wt% of an auxiliary antioxygen and 0.3-0.8wt% of a coupling agent. A a sa a preparation method comprises the following steps: (1) mixing the strontium ferrite with the coupling agent, then adding the polyamide resin, the internal lubricant, the flow modifier, the external lubricant, the primary antioxygen and the auxiliary antioxygen, and mixing to obtain a mixture; (2) adding the mixture through a main feeding hole of a double-screw extruder, mixing uniformly, then extruding, and granulating by virtue of a granulator, thereby obtaining the high-fluidity polyamide magnetic composite material.
Owner:SICHUAN UNFIRE POLYMER MATERIALS TECH

High-strength three-layer co-extrusion lithium ion battery diaphragm and preparation method thereof

The invention relates to the technical field of lithium ion battery diaphragms, and discloses a high-strength three-layer co-extrusion lithium ion battery diaphragm and a preparation method thereof.The diaphragm comprises a layer B and layers A arranged on the two sides of the layer B; the component of the layer A comprises co-polypropylene, and the melt index of the co-polypropylene at 230 DEG C is greater than or equal to 30 g/10 min; the layer B is prepared from the following components in parts by weight: 90 to 99 parts of homo-polypropylene and 1 to 10 parts of lubricating nucleating particles, and the melt index of the homo-polypropylene at 230 DEG C is 1 to 5g/10min; the lubricating nucleation particles are prepared from polytetrafluoroethylene micro powder, pimelic acid and calcium stearate through step-by-step ball milling. According to the invention, the diaphragm with an A/B/A structure is prepared from two different types of polypropylene with relatively large melt index difference in a three-layer co-extrusion manner, and the lubricating nucleation particles are added into the middle layer, so that the mechanical property of the diaphragm is effectively improved while the processing property of the diaphragm is ensured.
Owner:NINGBO CHANGYANG TECH
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