32results about How to "Low hydrothermal reaction temperature" patented technology

The invention discloses a graphene / stannic oxide nanometer compounding resistance type film gas sensor, which takes ceramics as a basal body. The surface of the ceramic basal body is photo-etched and evaporated with multiple pairs of interdigital gold electrodes, and is coated with gas-sensitive films of graphene and stannic oxide nanometer composite, and the manufactured resistance type film gas sensor has the advantages of simple manufacturing process and low cost. The gas-sensitive film is composed of a grapheme namosheet layer in a three-dimensional nano-structure and stannic oxide crystal particle composite with an orientated growth characteristic, the introduction of the graphene can favorably reduce the resistance of sensor elements, and the formation of the three-dimensional nano-structure can obviously enhance the specific surface area of the composite, thus the absorption and the diffusion of the gas can be promoted so as to greatly enhance the room temperature gas sensitive response sensitivity of elements. The graphene / stannic oxide nanometer compounding resistance type film gas sensor has the characteristics of high response sensitivity to low concentration ammonia, fast response, favorable recovering performanc, capability of carrying out the detection at the room temperature, and the like, which can be widely applied in the agricultural and industrial production process, and the room temperature detection and control of the concentration of ammonia in the atmospheric environment.

The invention relates to perovskite composite oxide LaFeO3 monodisperse micrometer hollow balls and a preparation method thereof, and belongs to the technical field of micro nanometer functional materials. The micrometer hollow balls are in a monodisperse state, the outer diameter of each micrometer hollow ball is between 1 and 7 micrometers, and the micrometer hollow balls are in a perovskite crystalline phase. The preparation method comprises the following steps of: stirring a mixed solution containing urea serving as an additive, citric acid serving as a complexing agent, deionized water serving as a solvent and metal nitrate uniformly, transferring the mixed solution to an autogenous pressure kettle, putting into a constant temperature box, keeping temperature for a certain time, cooling naturally, performing suction filtration on the obtained products, drying, grinding, and roasting at high temperature to obtain the highly-monodispersed LaFeO3 micrometer hollow balls. According to the preparation method, a template is not needed to be utilized, the reaction time is short, the preparation process is environment-friendly, and the operation is easy to implement.

The invention provides a preparation method of indium tin oxide nano powder, including that: indium chloride tetrahydrate and stannic chloride pentahydrate with the mol ratio of indium and stannum of 9-10:1 are dissolved by deionized water, ethidene diamine solution is added, and even mixing is carried out to obtain reaction solution; the reaction solution is placed into a kettle, reaction is carried out at 150-200 DEG C for 3-18 hours, and natural cooling to room temperature is carried out, so as to obtain intermediate product; the intermediate product is separated by centrifugation, washed by deionized water and absolute alcohol and dried at 40-70 DEG C for 6-24 hours, so as to obtain ITO precursor; the obtained ITO precursor is calcined and then heated to 400-550 DEG C from room temperature at heating rate of 2-8 DEG C per minute, heat preservation is carried out for 1-3 hours, and natural cooling to room temperature is carried out, thus obtaining ITO nano powder. The prepared ITO nano powder has high purity, small grain and uniform component, and synthesis technology and the required production equipment are simple, and industrialized production is easy to realize.

The invention discloses an NiFeMo ternary electrolytic water electrode and a preparation method thereof. Firstly, iron salt, nickel salt, urea and NH4F are used as raw materials under a low-temperature hydrothermal condition to prepare NiFe-LDH / NF, then NiFe-LDH / NF and a compound containing molybdenum are subjected to a low-temperature hydrothermal reaction to obtain Ni-Fetrace@NFM / NF, then Ni-Fetrace@NFM / NF is placed in a flowing reducing atmosphere for heat treatment for a certain time, and a final material of Ni / NiFeMoOx / NF is obtained; and in the process, an LDH substrate is reduced to Ninanoparticles, and mutually cross-linked with NiFe-MoOx generated by reduced molybdate to form a composite material with a hierarchical porous nanosheet structure. The hierarchical porous nanosheet structure facilitates bubble diffusion, a formed alloy is cross-linked with MoOx and combined with a conductive substrate to have excellent electrical conductivity, and in the way, the material has excellent reaction kinetics; and NiFe-MoOx with the high hydrogen evolution activity and the Ni nanoparticles with the high hydrogen evolution activity both endows the material with excellent hydrogen andoxygen evolution properties, and then catalytic performance of all electrolytic water with application prospects is obtained.

The invention discloses a hydro-thermal synthesis method of high-transmittance nano-scale magnesium lithium silicate. The hydro-thermal synthesis method is characterized by comprising steps as follows: firstly, montmorillonite is acidized and calcined; then, water-soluble lithium salt and water-soluble sodium salt are added, the matching ratio is adjusted, and the amount of substances of all elements in a reaction system meets the proportional relation: 0.2<m(Li) / m(montmorillonite)<0.8, 1<m(Na) / m (montmorillonite)<3; finally, the mixture is subjected to a reaction at the temperature of 60-95 DEG C for 1-3 h and fully dried at the temperature of 110-150 DEG C until the water content is not higher than 2%, and magnesium lithium silicate is prepared. Defects in the prior art are overcome, and the safe, environment-friendly, efficient and low-cost synthesis method of nano-scale magnesium lithium silicate is provided; according to the synthesis method, high-purity montmorillonite which has vast reserves in the natural world is taken as a starting raw material, and the nano-scale magnesium lithium silicate with high transmittance, excellent thickening and thixotropy and high adsorption force is produced by optimizing technological parameters of production and the ratio of reaction raw materials.

The invention belongs to the photocatalytic material field, concretely relates to a method for preparing anatase porous TiO2 spheres, a core-shell structure and hollow spheres. The method comprises the following steps: dissolving titanium salt in water, then adding a HNO3 solution and carrying out a constant temperature reaction in a reaction vessel to obtain sediments; washing by deionized water until pH value presents neutrality, and drying to obtain the TiO2 powder. The invention is characterized in that TiO2 is replaced HF for taking as a corrosive agent, the method is a fluorine-free preparation process, the TiO2 with solid spheres, the core-shell structure and hollow spheres can be prepared by controlling reaction conditions, thereby the dangerousness of the preparation process can be substantially reduced, the maneuverability is enhanced, so that the method is suitable for requirements of large-scale production and industrial application, and possesses good application prospect.

The invention belongs to the technical fields of inorganic nonmetallic nanomaterial preparation and water purification environmental protection, in particular to high-specific surface area low-isoelectric point nano zirconium dioxide and a preparation method and application thereof in removing arsenic. The nano zirconium dioxide has the crystallized specific surface area of 161.8m<2> / g, the amorphous specific surface area of 327.1m<2> / g and the isoelectric point of about 3 to 4. The nano zirconium dioxide has higher arsenic-removing capacity, the saturated adsorption capacity of a crystallized sample exceeds 47mg / g, and the saturated adsorption capacity of an amorphous sample exceeds 83mg / g. ZrOCl2.8H2O, water and ammonia water serve as precursors of a hydrothermal reaction, and the method comprises the following steps of: performing hydrothermal reaction to obtain a zirconium oxide precipitate; washing, drying and grinding to obtain amorphous zirconium dioxide powder; and calcining to obtain the crystallized zirconium dioxide material. The process of preparing the nano zirconium dioxide is simple, the high-specific surface area low-isoelectric point nano zirconium dioxide can be obtained, and a novel arsenic removing material is provided for purification of arsenic-containing sewage and environmental protection.

The invention discloses a method for preparing a xonotlite crystal whisker by using an active silica raw material and a calcium carbonate raw material. The method comprises the following steps: (1) grinding the active silica raw material and the calcium carbonate raw material to obtain active silica powder and calcium carbonate powder; (2) batching the active silica powder or / and the calcium carbonate powder obtained in the step (1), adding industrial water and directly putting into a closed reaction unit to perform a synthesis reaction by controlling the heating rate, the reaction temperature and the reaction time; and (3) filtering and drying, namely dispersing reaction products obtained in the step (2) to obtain the xonotlite crystal whisker. The xonotlite crystal whisker prepared by the method disclosed by the invention is relatively large in crystal grain, large in length-diameter ratio, high in strength, good in stability, wide in application range and beneficial to promotion and application.

The invention discloses a preparation method for graphene. The preparation method comprises the following steps: a first step, adding SDBS (sodium dodecyl benzene sulfonate) into an oxidized graphene dispersion liquid and uniformly stirring; a second step, adding strong base into the solution obtained in the first step and uniformly stirring; a third step, transferring the solution obtained in the second step into a hydrothermal reaction kettle, and reacting at a certain temperature; and a fourth step, filtering for washing the product obtained in the third step in a centrifugal manner to obtain the graphene product. The graphene prepared by the preparation method disclosed by the invention adopts a non-toxic reagent, and toxic reagents of hydrazine hydrate and the like in a conventional preparation technology are prevented from being used; the prepared graphene is high in reducing degree and is expected to be widely applied to preparing the graphene and a composite material thereof.

The invention relates to a cathode material, alpha-Fe2O3, of a high-capacity lithium ion battery and a preparation method for the cathode material. According to the preparation method, soluble trivalent molysite and an alkali metal hydroxide easy to dissolve are adopted as raw materials, and the hematite alpha-Fe2O3 is prepared by a hydrothermal method. The preparation method comprises the following specific steps that: 1) aqueous solution of the trivalent molysite with molarity being 0.5mol / L-2mol / L and aqueous solution of the alkali metal hydroxide easy to dissolve with molarity being 2mol / L-6mol / L are prepared; 2) the aqueous solution of the trivalent molysite and the aqueous solution of the alkali metal hydroxide obtained in the step 1) are mixed to generate suspension, the suspension is stirred for certain time, and then ammonia water drops into the suspension, so that the pH value of the suspension is adjusted to be 9-13; and 3) the suspension obtained in the step 2) is poured into a hydrothermal reaction kettle which can be airtight, the hydrothermal reaction kettle is put into an oven to be heated at a temperature of 160 DEG C-200 DEG C and then is subjected to thermal insulation for 3 hours to 20 hours, and after the reaction is finished, a product is subjected to solid-liquid separation, washing and drying so as to obtain the alpha-Fe2O3. When serving as the cathode material of the lithium ion battery, the alpha-Fe2O3 prepared by the method has higher specific capacity and better cycling stability. According to the method, the operation is simple, the cost is low, additives are not required, and the product quality is stable.

The invention provides a lithium ion battery cathode, which is characterized by having a structure of NIS / Ni. The preparation method of the cathode includes: putting thiourea in a container, then adding a proper amount of deionized water and hydrogen peroxide, fully stirring the mixture to obtain a uniform solution; and transferring the obtained uniform solution into a hydrothermal reaction kettle inner container, placing several pieces of foamed nickel into the hydrothermal reaction kettle, carrying out reaction at 90-150DEG C for 4-10h, and performing natural cooling to obtain an NiS / Ni sample. The electrode preparation method is simple, the cost is low, and the controllability is high. The temperature of the hydrothermal reaction is low and the time is short. The NiS in the prepared NiS / Ni uniformly grows on the foamed nickel surface and is composed of a large number of particles, and the particle size is about 100nm. The prepared material has high charge-discharge capacity and excellent cycle performance.

The invention discloses a three-dimensional hollow high-dispersion metal catalyst and a preparation method thereof, and belongs to the technical field of industrial catalysis. The preparation method comprises the following steps of: preparing a three-dimensional hollow bimetallic oxide by a microwave hydrothermal method; carrying out oxygen plasma based modification and silane coupling agent basedsurface hydrophobic modification on the bimetallic oxide to obtain a modified three-dimensional hollow bimetallic oxide carrier; adding an active component nickel salt, an auxiliary agent group IVA element metal salt and a rare earth element metal salt; loading the active component and the auxiliary agent metal on the modified carrier by adopting a photodeposition technology; and carrying out roasting in an air flow at 400-600 DEG C to obtain the three-dimensional hollow high-dispersion metal catalyst. Based on the total mass of the catalyst, the catalyst comprises 20-40wt% of nickel, 0.01-5wt% of IVA group element metal and 0.01-5wt% of rare earth element metal. The catalyst is applied to catalyzing pyridine dehydrogenation coupling to synthesize 2, 2'-dipyridyl, has the advantages of low catalyst dosage, few side reactions, short process and the like, and has a good industrial application prospect.

The invention discloses a hydro-thermal synthesis method of high-transmittance nano-scale magnesium lithium silicate. The hydro-thermal synthesis method is characterized by comprising steps as follows: firstly, montmorillonite is acidized and calcined; then, water-soluble lithium salt and water-soluble sodium salt are added, the matching ratio is adjusted, and the amount of substances of all elements in a reaction system meets the proportional relation: 0.2<m(Li) / m(montmorillonite)<0.8, 1<m(Na) / m (montmorillonite)<3; finally, the mixture is subjected to a reaction at the temperature of 60-95 DEG C for 1-3 h and fully dried at the temperature of 110-150 DEG C until the water content is not higher than 2%, and magnesium lithium silicate is prepared. Defects in the prior art are overcome, and the safe, environment-friendly, efficient and low-cost synthesis method of nano-scale magnesium lithium silicate is provided; according to the synthesis method, high-purity montmorillonite which has vast reserves in the natural world is taken as a starting raw material, and the nano-scale magnesium lithium silicate with high transmittance, excellent thickening and thixotropy and high adsorption force is produced by optimizing technological parameters of production and the ratio of reaction raw materials.

The invention relates to a hollow-structure ferrous sulfide (at) carbon in-situ composite material and a preparation method and application thereof. The preparation method comprises the following steps: 1, dissolving ferrous sulfate and glycerin in water, then dropwise adding alkali liquor till sediment appears, stopping dropwise adding, conducting stirring at the room temperature, and then conducting suction filtration, washing and drying to obtain a rod-like ferrous precursor; (2) dispersing the ferrous precursor in water, adding an organic sulfur source, stirring to react for at least 1 hour, heating to 130-150 DEG C to perform hydrothermal reaction, naturally cooling to room temperature, and performing suction filtration, washing and drying to obtain a ferrous sulfide precursor; and calcining the ferrous sulfide precursor, and cooling to obtain the ferrous sulfide (at) carbon in-situ composite material with the hollow structure. The ferrous sulfide (at) carbon in-situ composite material with the hollow rod-shaped structure is obtained through a template-free method and is applied to the potassium ion battery as an electrode active material, the obtained battery is long in cycle life and good in potassium storage performance, and a negative electrode structure is stable and does not pulverize or fall off.

The invention provides a method for preparing a submillimeter hydryoxyapetite crystal with a regular shape, and belongs to the field of ceramic materials. The method for preparing the submillimeter hydryoxyapetite crystal is mainly achieved through the following steps that firstly, water solutions including L-glutamic acid, disodium hydrogen phosphate and sodium hydroxide are prepared, the water solutions are fully stirred at indoor temperature to be dissolved, then ice, L-arginine, carbamide and calcium nitrate are added to the water solutions in sequence, the evenly-stirred mixed solutions are added to a certain amount of acetone, the solutions react for a while at the temperature below 37 DEG C and are cooled to be the indoor temperature, products obtained through the reaction are filtered, washed and dried, and the hydryoxyapetite crystal is prepared. The obtained plate-shaped hydryoxyapetite crystal is regular in shape and even in size, is 20-500 microns long, 5-200 microns wide and 1-10 microns thick, and can be used as drug diluent, bone cement additives, food additives and the like.

The invention belongs to the field of photocatalytic materials, specifically a method for preparing anatase porous TiO2 core-shell structure and hollow spheres, specifically dissolving titanium salt in water, adding HNO3 solution, and reacting at a constant temperature in a reactor to obtain a precipitate ; Wash with deionized water until the pH is neutral, and dry to obtain TiO2 powder; through the present invention, HNO3 is used instead of HF as a corrosive agent, which is a fluorine-free preparation process, and solid spheres, core-shell structures and hollow spheres can be prepared by controlling the reaction conditions TiO2 greatly reduces the risk of the preparation process and improves the operability, making the method suitable for large-scale production and industrial application, and has a good application prospect.

The invention discloses a method for modifying the surface of a carbon fiber, in particular relates to a preparation method of generating boron nitride crystal grains on the surface of the carbon fiber and belongs to the field of composite interface modification. The method for modifying the surface of the carbon fiber comprises the following steps: firstly, removing adhesive; secondly, generating the boron nitride crystal grains; and thirdly, carrying out low temperature ageing. The method disclosed by the invention has the advantages that reaction conditions are optimized, boron nitride generates the crystal grains in a hydrothermal environment, and coating the boron nitride crystal grains on the surface of the carbon fiber, so as to achieve the aim of modifying the carbon fiber; not only are surface roughness and surface activity of the carbon fiber improved, but also mechanical meshing effect is realized in resin matrix, so that mechanical properties of a composite are improved.

The invention provides a preparation method of indium tin oxide nano powder, including that: indium chloride tetrahydrate and stannic chloride pentahydrate with the mol ratio of indium and stannum of 9-10:1 are dissolved by deionized water, ethidene diamine solution is added, and even mixing is carried out to obtain reaction solution; the reaction solution is placed into a kettle, reaction is carried out at 150-200 DEG C for 3-18 hours, and natural cooling to room temperature is carried out, so as to obtain intermediate product; the intermediate product is separated by centrifugation, washed by deionized water and absolute alcohol and dried at 40-70 DEG C for 6-24 hours, so as to obtain ITO precursor; the obtained ITO precursor is calcined and then heated to 400-550 DEG C from room temperature at heating rate of 2-8 DEG C per minute, heat preservation is carried out for 1-3 hours, and natural cooling to room temperature is carried out, thus obtaining ITO nano powder. The prepared ITO nano powder has high purity, small grain and uniform component, and synthesis technology and the required production equipment are simple, and industrialized production is easy to realize.

The invention belongs to the technical fields of inorganic nonmetallic nanomaterial preparation and water purification environmental protection, in particular to high-specific surface area low-isoelectric point nano zirconium dioxide and a preparation method and application thereof in removing arsenic. The nano zirconium dioxide has the crystallized specific surface area of 161.8m<2> / g, the amorphous specific surface area of 327.1m<2> / g and the isoelectric point of about 3 to 4. The nano zirconium dioxide has higher arsenic-removing capacity, the saturated adsorption capacity of a crystallized sample exceeds 47mg / g, and the saturated adsorption capacity of an amorphous sample exceeds 83mg / g. ZrOCl2.8H2O, water and ammonia water serve as precursors of a hydrothermal reaction, and the method comprises the following steps of: performing hydrothermal reaction to obtain a zirconium oxide precipitate; washing, drying and grinding to obtain amorphous zirconium dioxide powder; and calcining to obtain the crystallized zirconium dioxide material. The process of preparing the nano zirconium dioxide is simple, the high-specific surface area low-isoelectric point nano zirconium dioxide can be obtained, and a novel arsenic removing material is provided for purification of arsenic-containing sewage and environmental protection.

The invention relates to a hollow structure ferrous sulfide@carbon in-situ composite material and its preparation method and application, comprising the following steps: (1) dissolving ferrous sulfate and glycerin in water, and then adding lye drop by drop until precipitation occurs Then stop dropping, stir at room temperature, then suction filter, wash, and dry to obtain a rod-shaped ferrous precursor; (2) Disperse the ferrous precursor in water, add an organic sulfur source, stir for at least 1 hour, and then heat up to 130°C Perform hydrothermal reaction at ~150°C, then naturally cool to room temperature, filter, wash, and dry to obtain the ferrous sulfide precursor; calcinate the ferrous sulfide precursor, and obtain a hollow structure ferrous sulfide@carbon after cooling In situ composites. The present invention obtains the ferrous sulfide@carbon in-situ composite material with a hollow rod-like structure through a template-free method and applies it to a potassium-ion battery as an electrode active material. The obtained battery has a long cycle life, good potassium storage performance, and a stable negative electrode structure. Chalking does not fall off.

The invention provides a low-temperature hydrothermal method for preparing nano lithium iron phosphate. The method comprises the following steps: weighing lithium phosphate, ferrous sulfate and a reaction aid according to a certain proportion; the preparation method comprises the following steps: dissolving ferrous sulfate in a proper amount of deionized water, transferring to a hydrothermal reaction kettle, then adding lithium phosphate and a reaction aid to obtain a solid-liquid mixed suspension, carrying out ultrasonic-assisted dispersion for a certain time, then heating the reaction kettle at a certain temperature, and carrying out heat preservation for a certain time; and washing the product obtained after hydrothermal treatment with deionized water, and drying to obtain the nano lithium iron phosphate. According to the invention, the hydrothermal reaction temperature is effectively reduced, the equipment requirement is reduced, the equipment investment is reduced, and the production safety is improved.

The invention relates to a method of preparing a xonotlite-type calcium silicate material from active silicate dioxide and calcareous raw materials. The preparation method comprises the following steps: (1) individually grinding active silicon dioxide and calcareous raw materials so as to obtain active silicon dioxide powder and lime powder; (2) blending the active silicon dioxide powder and lime powder obtained in the step (1) according to a certain ratio, then transferring the mixture to a mixer with a stirring device, adding industrial water, evenly stirring to obtain a uniform material, after a moulding treatment or directly transferring the uniform material to an enclosed reactor, and controlling the temperature rising speed, the reaction temperature, and reaction time to carry out synthesis reactions; (3) moulding and / or drying the reaction products obtain in the step (2) so as to obtain the xonotlite-type calcium silicate material. The xonotlite-type calcium silicate material has the advantages of no toxicity, safety, low density, high strength, low heat conductive coefficient, and good chemical stability, and can be used in the industries such as electric power, chemical engineering, metallurgy, textile, building material, and the like.

The invention discloses a method for preparing a xonotlite crystal whisker by using an active silica raw material and a calcium carbonate raw material. The method comprises the following steps: (1) grinding the active silica raw material and the calcium carbonate raw material to obtain active silica powder and calcium carbonate powder; (2) batching the active silica powder or / and the calcium carbonate powder obtained in the step (1), adding industrial water and directly putting into a closed reaction unit to perform a synthesis reaction by controlling the heating rate, the reaction temperature and the reaction time; and (3) filtering and drying, namely dispersing reaction products obtained in the step (2) to obtain the xonotlite crystal whisker. The xonotlite crystal whisker prepared by the method disclosed by the invention is relatively large in crystal grain, large in length-diameter ratio, high in strength, good in stability, wide in application range and beneficial to promotion and application.

The invention provides a nanosheet array nickel cobalt oxide-carbon composite material, a method for preparing the same and application of the same. The method comprises the steps of: performing ultrasonic processing on wet tissues and obtaining wet tissue fibers after drying; adding nickel nitrate, cobalt nitrate, urea and hexamethylenetetramine into an ethanol aqueous solution to obtain a mixedsolution; soaking the wet tissue fibers into the mixed solution and then performing a hydrothermal reaction to obtain a wet tissue fiber base body carrying an Ni-Co precursor; performing a heating calcination reaction on the wet tissue fiber base body in a mixed gas atmosphere and, after cooling, obtaining the nanosheet array nickel cobalt oxide-carbon composite material. The method utilizes wet tissues which are common in daily life as templates, so that waste in life can be effectively utilized; the material is simple in operation method and is environmentally-friendly and the materials areeasy to obtain; the material has a broad application prospect in fields such as clean energy and catalysis. As an electrode of a super capacitor, the material has high specific capacitance and excellent circulation stability.