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79results about How to "Large saturated adsorption capacity" patented technology

Preparation and application of lignin or aminolignin-modified magnetic nano-adsorbent

The invention relates to preparation and application of a lignin or an aminolignin-modified magnetic nano-adsorbent. The magnetic nano-adsorbent is obtained by a one-step conversion of lignin and a raw material iron salt by a modified chemical coprecipitation method. The main method is to prepare surface-modified magnetic nanoparticles by dissolving lignin or amino-modified lignin in an alkaline precipitant and using the alkaline precipitant for coprecipitation. The synthesized magnetic nano-adsorbent has adsorption capacity for both anionic dyes and cationic dyes. Compared with other lignin-based adsorbents, the adsorption capacity is increased by about 2 to 5 times. At the same time, desorption can be achieved by adjusting of the pH, so that the adsorbent is recycled, and the dyes can berecovered. Lignin raw materials used in the adsorbent are industrial and agricultural waste materials, the materials are rich and low in price, the synthesis method is simple and efficient, and the adsorbent is economical and environmentally friendly, and has good application prospects.
Owner:TIANJIN UNIV

Method for recovering rhenium from molybdenum smelting waste acid

The invention discloses a method for recovering rhenium from molybdenum smelting waste acid and belongs to the technical field of metal rhenium recovery and recycle. The method comprises 1, filtering molybdenum smelting waste acid, and treating the filtrate by a composite aminoethylene weak basic anion exchange resin column for adsorption until adsorption is saturated, and 2, carrying out desorption on the saturated anion exchange resin column, collecting the desorption liquid and carrying out evaporation crystallization to obtain ammonium perrhenate. The composite aminoethylene weak basic anion exchange resin has large saturation adsorption quantity. The desorption liquid has rhenium content 100 times or more that of waste acid. Compared with the existing extraction method and ion exchange method, the method provided by the invention has a high rhenium recovery rate of 98% or more. Through use of solubility difference of ammonium perrhenate, ammonium molybdate and ammonium sulfate, ammonium perrhenate is purified by evaporation crystallization and ammonium perrhenate purity is 99.9% or more. The method has a simple rhenium recovery process, is environmentally friendly, is convenient for operation and is suitable for large scale production.
Owner:ZHENGZHOU MINERALS COMPOSITIVE UTILIZATION RES INST CHINESE GEOLOGICAL ACAD +1

Amino-functional ordered mesoporous carbon material and preparation method and application thereof

The invention discloses an amino-functional ordered mesoporous carbon material and a preparation method and application thereof. The preparation method comprises the steps of carrying out concentrated nitric acid oxidation treatment on the ordered mesoporous carbon synthesized by soft template lines, and preparing the amino-functional ordered mesoporous carbon material under the action of a silane coupling agent. Through wet oxidation on the ordered mesoporous carbon, the concentration of hydroxyl groups in an ordered mesoporous carbon duct is remarkably improved. Through the organic silane coupling agent, silane groups containing amino can be uniformly grafted into the duct of ordered mesoporous carbon with ordered height and uniform pore size distribution. The technical problem that functional groups cannot be grafted directly caused by hydrophobicity and surface inertness of the ordered mesoporous carbon material is solved. Applied to Cr (VI) in an adsorption aqueous solution, the material has the advantages of being convenient to apply, and high in adsorption rate and adsorption volume.
Owner:NANJING UNIV OF SCI & TECH

Method for preparing biomass absorbing agent capable of absorbing heavy metal ions in waste water efficiently

The invention relates to a method for preparing a biomass absorbing agent capable of absorbing heavy metal ions in waste water efficiently and belongs to the fields of material preparation and waste water treatment. The method is characterized by comprising the steps of treating rice straw which is low in price and easy to obtain as raw materials, and conducting washing, drying, pulverization and screening. Firstly, the pretreatment is conducted through an acidic hydrogen peroxide solution, the method of conducting the heating and stirring in water bath is adopted for reaction, and the rice straw is filtered, washed to be neutral and dried. Then phosphoric acid or disodium hydrogen phosphate serves as the modifying agent, the straw which is obtained after the pretreatment is heated and stirred for reaction, after the reaction is ended, the straw is filtered, washed to be neutral and dried, and the needed heavy metal ion absorbing agent is obtained. The method has the advantages of being simple in preparation method, low in cost, free of secondary pollution and the like.
Owner:INST OF BIOLOGICAL RESOURCES JIANGXI ACAD OF SCI

Preparation method of modified silicon gel absorbing agent used for protecting on-vehicle fuel batteries

InactiveCN101856606AEfficient removalGood ability to remove trace sulfur dioxideOther chemical processesFuel cell auxillariesFiberSilanes
The invention relates to a preparation method of a kind of modified silicon gel absorbing agent used for protecting on-vehicle fuel batteries, which belongs to the branch of the non-metallic inorganic material technology and is applied to the field of gas absorption and separation. The preparation method uses 3-aminopropyl triethoxysilane as amino modifying agents, uses tetraethoxy silane as silicon gel precursors, and prepares and obtains modified silicon gel with uniformly decorated amino groups in a porous silicon gel framework through adding a certain number of amino modifying agents in the gel forming stage. The absorbing agent can be used for removing a trace amount of sulfur dioxide in the air, so cathodic catalysts of on-vehicle proton exchange membrane fuel batteries are protected from the poisoning effect of the sulfur dioxide. Compared with the prior art, the invention has the following advantages that: (1) the obtained absorbing agent has better capability for absorbing the trace amount of sulfur dioxide than active carbon fiber, the effect is shown through longer penetrating time and larger saturation adsorption capacity, in addition, the absorbing agent still has good absorbing capability when the humidity is lower; and (2) the obtained absorbing agent has simple and convenient preparation method, the operation is easy, the condition is mild, and the effects of energy saving and environment protection can be obtained.
Owner:DALIAN UNIV OF TECH

Nano granule water purifying material for removing bacteria and virus, and preparation thereof

The invention relates to a series of nano-particle water purification materials, which take quartz sand or zeolite particle as a substrate, nanometer aluminum (iron) oxide or nanometer aluminum (iron) oxidized hydrogen oxide as a modified filtration coating, and can effectively and completely remove bacilli and virus from wastewater and sewage. The invention also relates to a preparation method of the nano-particle water purification materials. In the preparation method, acidic solution with 40 to100 meshes of quartz sand or 60 to120 meshes of clinoptilolite is poured into secondary deionized water, uniformly mixed and heated, nano-aluminum powder, aluminum nitride powder or iron powder is poured into the acidic solution and ultrasonically mixed and ethanol solution of ester is then poured into the mixed acidic solution, ultrasonically mixed again, filtrated and dried so as to gain nano-fibriform AlO(OH) or FeOOH which is the particle water purification materials of filtration coating which are further roasted so as to gain Gamma-Al2O3 or Fe2O3 which is the particle water purification materials of filtration coating. The nano-particle water purification materials of the invention have the advantages of strong removal ability, high cleanliness, great saturated adsorption capacity, etc.
Owner:JILIN UNIV

Preparation of indoor organic pollution gas purifying agent and process of using

The present invention discloses a manufacture and use method for an indoor organic polluting gas purificant. The method comprises the following steps: (1) waste pericarps and other vegetable cutins are collected, and residual pulps and other sundries are removed to get natural vegetable cutins and biological polymers; (2) the vegetable cutins are dried, crushed and filtered with a sieve of 10 to 200 eyes; (3) hydrochloric acid with the concentration of 0.5-6mol / l is added; then after the vegetable cutins with the hydrochloric acid are heated in a water bath for 0.5 to 6 hours, the cutins are flushed with water to be neutral, and a green purificant is got; (4) the green purificant is used absorb and treat organic pollutants in the indoor air; after the purificant is saturated, the purificant is heated under the temperature of 70 to 100 centigrade degrees for 0.5 to 2 hours to be regenerated and recycled. The purificant manufactured with the present invention is provided with the rapid and highly-efficient performance of absorbing the indoor organic pollutants. The absorption capacity reaches as high as 2.0g / g. Moreover, the purificant is free of the temperature, the humidity and co-existing organic pollutants and in particular applicable for purification of indoor compound pollutants. The purificant is cheap and easily obtainable, and can be recycled and regenerated.
Owner:ZHEJIANG UNIV

Desulfurization wastewater dechlorination treatment method and desulfurization wastewater treatment equipment

The invention discloses a desulfurization wastewater dechlorination treatment method and desulfurization wastewater treatment equipment. The method comprises the following steps: A, firstly, adding anacid into the desulfurization wastewater to adjust the pH value to 0.5-4, and then stirring and mixing with a liquid resin; B, separating an obtained mixture in a separation chamber; C, enabling theseparated liquid resin to enter a liquid resin buffer tank, and enabling separated desulfurization wastewater to enter a next-stage reactor for further treatment; and D, repeating the steps A, B and Cin the treatment process, removing the liquid resin dissolved in the water in an air floatation oil removal device, taking the desulfurization wastewater treated through air floatation treatment andpH adjustment as reuse water, and conveying the liquid resin brought out by bubble floatation into the liquid resin buffer tank. The method has the advantages that the equipment investment is small, the operation cost is low, the produced water after chloride ion removal can meet the industrial water recycling requirement, no waste is generated in the treatment process, real-time adsorption and real-time regeneration are achieved in the reaction process, 100% removal of chloride ions can be achieved, the whole process is continuously operated, waiting and time delay are not needed, and the production efficiency is high.
Owner:镇江泽润环境科技有限公司 +1

Needle-sized nanometer iron oxide adsorbent and preparation method thereof

The invention provides a method for preparing a needle-sized nanometer iron oxide adsorbent. The method comprises the following steps: respectively dissolving inorganic iron salt and urea in a mixtureof glycerol and deionized water to obtain a mixed solution; stirring the mixed solution, ultrasonically dissolving the mixed solution, then transferring the material to a high-pressure reaction vessel with a polytetrafluoroethylene liner for a solvothermal reaction to form a precipitated product in the reaction vessel; and performing steps of washing centrifugation and drying to obtain the needle-sized nanometer iron oxide adsorbent. The needle-sized nanometer iron oxide adsorbent prepared by the invention has stable performance, has good adsorption capacity for anionic dyes such as Congo red, and can be used for efficiently treating the pollution problem of the organic pollutant Congo red in the water body; the organic solvent used in the preparation process is used with a small amount,and the harm to the environment is low; the treatment of the organic dye Congo red-polluted water body does not cause secondary pollution; the method is simple and easy to prepare, the preparation conditions are mild, the raw materials are cheap and easy to acquire, and the process cost is low.
Owner:UNIV OF JINAN

Preparation method and application of mesoporous hydroxyl-ferric oxide Cr (VI) adsorbent

The invention discloses a preparation method and an application of a mesoporous hydroxyl-ferric oxide Cr (VI) adsorbent which can be used for solving the pollution problem of heavy metal Cr (VI) in water. The preparation method of the adsorbent comprises the steps as follows: inorganic iron salt, an amide precipitator and a mesoporous template agent are mixed and dissolved in pure water; the solution is subjected to a hydrothermal reaction after being sealed; a precipitate obtained after the reaction is filtered, washed and dried, and a precursor is obtained; the precursor is calcined and theadsorbent is obtained. The prepared efficient mesoporous hydroxyl-ferric oxide adsorbent has good adsorption capacity for Cr (VI), high saturation adsorption capacity, high adsorption rate and low equilibrium concentration. The raw materials used in the method are cheap, easy to obtain, green and environmentally friendly, the preparation method is simple and adopts mild conditions, and the prepared low-cost adsorbent which has excellent adsorptive performance for highly toxic pollutant Cr (VI) has important scientific significance and good application prospects.
Owner:SHANGHAI UNIV

Method for separating halogenated olefin impurities from 2-chloro-1,1,1,2-tetrafluoropropane

The invention relates to a method for separating halogenated olefin impurities from 2-chloro-1,1,1,2-tetrafluoropropane. The method comprises the following steps: adding the 2-chloro-1,1,1,2-tetrafluoropropane containing the halogenated olefin impurities into an adsorbent and absorbing halogenated olefins; the solid adsorbent is a copper-modified high-silicon ZSM-5 molecular sieve adsorbent. The absorption method adopted by the invention has the advantages that the saturated adsorption quantity is large, the adsorption quantity of the adsorbent for the halogenated olefins reaches 0.8, the content of HCFO-1233xf in absorbed HCFC-244bb is less than 700 ppm, the purity of the HCFC-244bb reaches above 99.6 percent, and the like. In addition, the adsorbent adopted by the invention has the advantage of HF resistance and is suitable for industrial production equipment.
Owner:SHANDONG HUAAN NEW MATERIAL

Preparation method of ion-imprinted blended membrane

The invention relates to a preparation method of an ion-imprinted blended membrane. The method comprises steps as follows: (1) synthesis of a macromolecular chain transfer agent: the macromolecular chain transfer agent is synthesized from methyl methacrylate and an RAFT reagent in a preset proportion of a thermal initiator; (2) synthesis of an amphiphilic block functional copolymer: the amphiphilic block functional copolymer is synthesized from 4-vinylpyridine, the thermal initiator and the macromolecular chain transfer agent synthesized in the step (1); (3) synthesis of a template ion-high-polymer complex; (4) membrane casting: the template ion-high-polymer complex in the step (3) and a membrane matrix are dissolved in a solvent in a preset proportion and stirred for preset time to be uniformly mixed, a membrane casting solution is obtained, and membrane casting is performed after bubbles are removed from the membrane casting solution; (5) elution. In the membrane forming process, a hydrophilic block can rapidly move to the surface of the membrane, the condition of difficulty in elution due to too deep embedding of template ions by PVDF (polyvinylidene fluoride) can be avoided, more binding sites are produced on the surface of the membrane, and the adsorption selectivity and the adsorption capacity of the ion-imprinted blended membrane are increased.
Owner:HUNAN UNIV OF SCI & TECH

Purification and ventilation system for sterile workshop

The invention discloses a purification and ventilation system for a sterile workshop. The purification and ventilation system for the sterile workshop comprises a housing, an air inlet port, a first filter device, a sterilization device, an air inducing device, a second filter device and an air outlet device, wherein the first filter device comprises a first filter cavity, an air guide device anda first filter layer; the air guide device comprises a plurality of air guide plates; a plurality of bulges are arranged on each air guide plate; the sterilization device comprises a sterilization cavity, a sterilization pipe and an ultraviolet lamp; the air inducing device comprises an air inducing chamber, an air inducing fan and a heat dissipator; the second filter device comprises a second filter cavity, as well as an aluminum alloy filter screen, a honeycomb activated carbon filter screen and a cold catalyst filter screen which are sequentially arranged in the second filter cavity; and the air outlet device comprises an air outlet port, an air outlet cavity, a negative-ion generator and a micro-fan. The invention provides a purification and ventilation system for a sterile workshop, solves the problems that sterilization and disinfection cannot be carried out on the interior of a workshop, bacteria are easily bred in the workshop, and adverse influence is brought to personnel health and production, in the prior art, and improves the effects of purification, and sterilization and disinfection for the sterile workshop.
Owner:天津翔越医疗器械有限公司

Preparation method of modified steel slag for removing arsenic from water body

The invention relates to a preparation method of modified steel slag for removing arsenic from water body. The preparation method comprises the following steps: cleaning the steel slag, and drying thesteel slag until the weight of the steel slag is constant for standby use; adding the steel slag which is dried to the constant weight into a culture solution comprising iron oxidizing bacteria, performing erosion soaking, and obtaining modified steel slag. The preparation method has the beneficial effects that the modified steel slag prepared by the invention has the characteristics that the modification method is simple, the cost is low, raw materials are easy to obtain, and the effect for removing arsenic from water is apparent; compared with the original steel slag, the adsorption capacity of the modified material for the arsenic is increased by 32.2 to 41.3 percent; in addition, the adsorption effect is little influenced by the temperature, the adsorbed arsenic cannot be desorbed inneutral water after the saturated adsorption, the modified steel slag is high in arsenic removal efficiency and high in saturated adsorption capacity, the material is stable after the adsorption, thesecondary pollution is avoided, and the recycling of solid waste is realized.
Owner:WUHAN UNIV OF TECH
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