The invention discloses a preparation method of reverse
copper foil. The preparation method of the reverse
copper foil comprises the following steps of electrolytic bath arrangement, addition agent addition, stirring operation, primary
electroplating operation, primary roughening operation, primary curing operation, secondary
electroplating operation, secondary roughening operation, secondary curing operation, cleaning operation, anti-oxidation treatment and
drying operation. A
titanium iridium anode plate and a
titanium roller are adopted, an electrolytic solution is used in an electrolytic bath, specifically, the
copper content of the electrolytic solution ranges from 130g / L to 220g / L, and the
sulfuric acid content of the electrolytic solution ranges from 70g / L to 100g / L. When addition agents are added, the electrolytic solution is heated to enable the temperature to range from 45 DEG C to 50 DEG C, and 5-10 parts of WH-001 addition agents, 3-5 parts of WH-002 addition agents and 2-3parts of WH-003 addition agents by
mass are added to 1000 parts of electrolytic solutions by volume
every hour. When the secondary
electroplating operation is conducted, 5-10 parts of WH-004 additionagents by
mass are added. When the secondary roughening operation is conducted, 5-15 parts of WH-005 addition agents by
mass are added, and the secondary roughening operation is accomplished. By theadoption of the technology, the potential barrier of
metal nucleation is reduced, the
nucleation speed is increased, high-density copper particle crystals can be formed on the surface of the
copper foil, the non-uniformity degree of the surface is reduced, the
mechanical property of the
copper foil is improved, and therefore the tensile strength and the peeling resistance strength of the
copper foil are improved.