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41results about How to "High ion transfer number" patented technology

A montmorillonite-based composite solid electrolyte and a solid-state lithium battery

The invention discloses a montmorillonite-based composite solid electrolyte and a solid-state lithium battery. The montmorillonite-based composite solid electrolyte comprises a lithium montmorilloniteinorganic single-ion conductor, a polymer with lithium ion transport ability, a lithium salt, a high-voltage-resistant organic additive and polytetrafluoroethylene with high adhesion property, The montmorillonite-based composite solid electrolyte takes lithium montmorillonite inorganic single ionic conductor as an electrolyte matrix, and the lithium montmorillonite inorganic single ionic conductor has high ion migration number, wide voltage window and high thermal stability. The montmorillonite-based composite solid electrolyte has high room temperature ionic conductivity () 10-4S cm-1), widevoltage window (4.2-5.5 V) and high ion migration numb () 0.5. That solid-state lithium battery assembled by the montmorillonite composite solid electrolyte of the invention has excellent cycle stability.
Owner:UNIV OF SCI & TECH BEIJING

Copper current collector for lithium metal secondary battery, preparation method thereof and lithium metal secondary battery

The invention provides a copper current collector for a lithium metal secondary battery, comprising a copper foil and a polymer layer introduced on the surface of the copper foil, wherein the polymerlayer is a functional polymer with one or several groups of cyan, hydroxyl, amino, aldehyde group and carboxyl; inorganic nanoparticles are dispersed in the polymer layer; the inorganic nanoparticlesare one or several of alkylated alumina nanoparticles, nano silica, nano calcium carbonate, nano calcium phosphate, and iron oxide nanoparticles; and the inorganic nanoparticles have a mass fraction in the polymer layer of 0-5 percent. The invention introduces a functional polymer layer on the surface of the copper current collector, and the polymer layer may change the current density and stabilize the deposition of the metal lithium, thereby inhibiting the generation of lithium dendrites, stabilizing the SEI film, and improving the efficiency and safety of the lithium metal battery. The invention also provides a method for preparing a copper current collector for a lithium metal secondary battery and the lithium metal secondary battery.
Owner:NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI +1

Process for preparing blended micrometer TiO2 polymer electrolyte

The present invention relates to the preparation process of electrolyte for polymer lithium ion cell. The present invention uses micron level TiO2 powder as stuffing for polymer electrolyte film, and prepares PVDF-HFP base polymer electrolyte film via phase transfer process. In the weight ratio of PVDF-HFP to TiO2 in 9-49, weight ratio of PVDF-HFP to deionized water to acetone in 1 to 0.25-1.25 to 5-15, the mixture of solvent and non-solvent is added into the mixture of polymer matrix PVDF-HFP and micron stuffing TiO2 to obtain while homogeneous porous polymer film, which is then soaked in electrolyte liquid for lithium ion cell to obtain electrolyte film with ionic conducting performance and finally heat treated. The present invention has improved and stabilized pore structure of polymer electrolyte film and raised electrochemical performance and mechanical performance of electrolyte film.
Owner:UNIV OF SCI & TECH BEIJING

Solid electrolyte and preparation method thereof, and lithium secondary solid-state battery

The invention relates to a solid electrolyte and a preparation method thereof, and a lithium secondary solid-state battery, belongs to the technical field of secondary batteries and solves a technicalproblem to provide a low-cost solid electrolyte. The solid electrolyte comprises a polymer base material, lithium salt and additive, wherein the additive is Ta-doped beta-LiAlSi2O6. By adopting the novel inorganic solid electrolyte additive, ionic conductivity of the solid electrolyte is improved, meanwhile, growth of lithium dendrites can be inhibited, energy density of the battery is improved,and finally, cycle performance and the rate capability of the battery are improved. The solid electrolyte further has ion conductivity, high ion mobility and good cycle performance and rate capabilityat room temperature. The preparation process is simple, the solid electrolyte slurry can be well mixed in a short time, production efficiency is high, and manufacturing cost is low.
Owner:UNIV OF ELECTRONICS SCI & TECH OF CHINA

Lithium battery diaphragm and preparation method thereof

The invention relates to a lithium battery diaphragm and a preparation method thereof. The lithium battery diaphragm comprises a porous polyolefin-based film and a core-shell structure inorganic oxidecoating layer, wherein the battery diaphragm and preparation method thereof is arranged on a surface of the porous polyolefin-based film, a coating material of the battery diaphragm and preparation method thereof is core-shell structure inorganic oxide particle, and the core-shell structure inorganic oxide particle comprises submicron inorganic oxide core and a nanometer inorganic oxide shell layer.
Owner:SHANGHAI UNIV

Lithium ion battery composite electrolyte and lithium ion battery

ActiveCN103066322AOvercome the disadvantage of narrow operating temperature rangeEasy to joinSecondary cells servicing/maintenanceComposite electrolyteElectrical battery
The invention discloses a lithium ion battery composite electrolyte and a lithium ion battery. The lithium ion battery composite electrolyte comprises 50-90 parts by mass of an ionic liquid, 1-10 parts of a film forming additive, and 5-20 parts of a lithium salt. The lithium ion battery prepared through using the lithium ion battery electrolyte has the advantages of high conductivity, good cycle performances, large rate charge and discharge specific capacity, wide use temperature range, and excellent safety.
Owner:上海铂宝集团股份有限公司

All-solid electrolyte, preparation method thereof and lithium battery

The invention belongs to the solid electrolyte field, and provides an all-solid electrolyte which includes a polycaprolactone-based block copolymer, a lithium salt and a porous rigid material membrane, and the mass ratio of the polycaprolactone-based block copolymer and the lithium salt is (50-90): (10-50). As can be seen from the result of the example, the ionic conductivity of the all-solid electrolyte is 1.2x10<-5>-4.3x10<-4>S / cm, the electrochemical window reaches 4.5 ~ 5V and the lithium ion migration number reaches 0.4 ~ 0.6. The invention also provides a preparation method of the all-solid electrolyte. The preparation method of the invention has the advantages of simple operation, strong practicability and easy implementation. The invention also provides a lithium battery comprisingthe all-solid electrolyte or the all-solid electrolyte obtained by the preparation method.
Owner:吉林省东驰新能源科技有限公司

Two-dimensional nanostructure electrolyte additive, preparation method and application

The invention belongs to the technical field of alkali metal battery electrolyte, and particularly discloses a two-dimensional nanostructure electrolyte additive, a preparation method and application.The two-dimensional nanostructure electrolyte additive is a two-dimensional structure organic or inorganic nanosheet, the two-dimensional nanostructure material is one or more of a boron nitride nanosheet, graphene oxide, a transition metal sulfide nanosheet, a two-dimensional metal organic framework material and a two-dimensional covalent organic framework material, and the thickness of the two-dimensional nanostructure material is not greater than 10 nanometers. The method comprises the following steps: stripping an organic or inorganic blocky material into two-dimensional nanosheets with the thickness of less than 10 nanometers, adding the two-dimensional nanosheets into deionized water, uniformly dispersing, and carrying out freeze drying to obtain the two-dimensional nanostructure electrolyte additive. The electrolyte comprises an electrolyte salt, a non-aqueous organic solvent and the two-dimensional nanostructure electrolyte additive. According to the invention, the long-actingcycling stability and safety of the battery can be improved.
Owner:HUAZHONG UNIV OF SCI & TECH

Polymer electrolyte membrane and preparation method thereof

The invention provides a polymer electrolyte membrane for lithium ion batteries. The polymer electrolyte membrane adopts low-polyether-grafted polyphosphazene polymer as the base material and comprises appropriate amount of lithium salt and doping type small-size inorganic filler introduced to the low-polyether-grafted polyphosphazene polymer. The invention further provides a method for preparing the polymer electrolyte membrane. The method comprises the following steps: dissolving the poly[bis2-(2-(2-methoxyethoxy)ethoxy)ethoxyphosphazene] (MEEEP) into a solvent to prepare a base material solution with the mass percent concentration being 2-15%, dispersing the inorganic filler doped with the lithium salt and a fast ion conductor into the base material solution to obtain the dispersed solution, pouring the dispersed solution on the membrane to form a membrane in a curtain coating manner, and performing vacuum drying to obtain the MEEEP electrolyte membrane. With adoption of the method for preparing the MEEEP electrolyte membrane, the lithium-ion conductivity and the lithium-ion transference number of the MEEEP electrolyte membrane are improved, and the electrochemistry and safety performance of the lithium ion batteries are improved.
Owner:CHINA JILIANG UNIV

In-situ polymerization polycaprolactone-based all-solid-state electrolyte as well as preparation method and application thereof

The invention discloses an in-situ polymerization polycaprolactone-based all-solid-state electrolyte as well as a preparation method and application thereof. The method comprises the following steps of adding lithium salt and inorganic additive particles into methoxy polycaprolactone acrylate to obtain a mixed solution; adding a photoinitiator into the mixed solution, and uniformly mixing to obtain a mixture; and coating a pole piece with the mixture in an inert atmosphere, and carrying out in-situ polymerization reaction under the irradiation of an ultraviolet lamp to obtain the in-situ polymerization polycaprolactone-based all-solid-state electrolyte. The branched structure of the all-solid-state electrolyte is compounded with the polymer material particles, so that the all-solid-state electrolyte has high mechanical strength, high ionic conductivity, high ionic migration number and wide electrochemical window, and has certain biodegradability. According to the all-solid-state electrolyte, an in-situ polymerization preparation method is adopted, the pole piece is directly coated with a precursor, and the free radical polymerization is carried out under the initiation of the ultraviolet light to obtain the solid-state electrolyte, so that the technological conditions are simple, the high efficiency and convenience are achieved, the solvation is avoided, and no pollution is caused to the environment.
Owner:SOUTH CHINA UNIV OF TECH

Solid electrolyte and preparation method and application thereof

The invention relates to a solid electrolyte as well as a preparation method and application thereof, and mainly solves the problems of low mechanical strength and low conductivity of the existing solid electrolyte and the problems of complexity, long time consumption and difficulty in large-scale production of the existing solid electrolyte preparation method. According to the solid-state electrolyte, nanoparticles grow on a substrate skeleton, and then the electrolyte is fixed, so that the interface contact between metal lithium and the electrolyte is effectively improved, the ionic conductivity and the ionic migration number are improved, the uniform deposition and separation of lithium ions on the metal lithium are promoted, and the solid-state electrolyte can be widely applied to solid-state batteries.
Owner:宁德国泰华荣新材料有限公司

Nanometer material-modified rubber-gel electrolyte film and preparation method and application

The invention discloses a preparation method of a nanometer material-modified rubber-gel electrolyte and application of the nanometer material-modified rubber-gel electrolyte, and belongs to the technical field of new energy materials. Nanometer material-modified rubber-gel electrolyte film is prepared from a nanometer material, rubber and an organic electrolyte; the weight percentage of the nanometer material is 10-40wt%, the weight percentage of the rubber is 20-50wt%, and the weight percentage of the organic electrolyte is 3-60wt%. The nanometer material-modified rubber-gel electrolyte is simple in preparation method route, mild in operation condition, environmentally friendly in preparation process, good in stability, good in metal interface compatibility, and large and stable in deformation space, and energy storage device short circuits and dendritic crystals can be effectively prevented; more importantly, due to outstanding organic electrolyte adsorption capability of the nanometer material modified rubber-gel electrolyte, the ionic conductivity and a transference number of ions are well improved.
Owner:XIANGTAN UNIV

Gel containing ester compound and sulfide as well as preparation and application of gel

The invention relates to gel containing ester compounds and sulfides as well as preparation and application of the gel, and belongs to the technical field of gel electrolytes. The gel is prepared from, by mass, 50%-80% of ester compounds, 2%-40% of salt compounds, 2%-45% of sulfur and 1%-20% of metal sulfide, the room-temperature ionic conductivity of the gel is 1.0*10<2> S / cm or above, the room-temperature ionic migration number of the gel is 0.6 or above, and the gel further has a wide electrochemical window. The electrolyte can be applied to a secondary ion battery; the preparation method of the gel is simple, short in preparation period and easy for industrial production.
Owner:BEIJING INSTITUTE OF TECHNOLOGYGY

Biomass nanofiber diaphragm as well as preparation method and application thereof

The invention discloses a biomass nanofiber diaphragm as well as a preparation method and application thereof. The biomass nanofiber diaphragm comprises a biomass nanofiber diaphragm layer with a compact structure, and the biomass nanofiber diaphragm is prepared from biomass nanofibers chemically modified with cyano groups. According to the biomass nanofiber diaphragm, due to the modification of the cyano groups, the surface of the biomass nanofiber diaphragm can be combined with a liquid electrolyte to form a gel state, and lithium ions can be transmitted through the gel state, so that the transmission of the lithium ions does not depend on the aperture of the diaphragm. The biomass nanofiber diaphragm provided by the invention is high in compactness, high in ionic conductivity, high in electrolyte wettability and high in ion mobility. According to the diaphragm, the complicated step that the biomass nanofiber diaphragm needs a pore forming process to achieve high porosity and to improve the lithium ion conductivity of the diaphragm can be avoided, the biomass nanofiber diaphragm provided by the invention has high mechanical properties, and the produced biomass nanofiber diaphragmhas the advantages of compactness and excellent electrochemical performance and the like.
Owner:UNIV OF SCI & TECH OF CHINA

Sandwich type solid composite electrolyte membrane as well as preparation method and application thereof

The invention discloses a sandwich type solid-state composite electrolyte membrane and a preparation method and application thereof, the electrolyte membrane is formed by permeating a composite electrolyte into a microporous diaphragm, and the composite electrolyte is composed of a high-molecular polymer material, a lithium salt and an ionic liquid. Or the electrolyte is composed of the inorganic solid electrolyte powder, the high-molecular polymer material, the lithium salt and the ionic liquid. The preparation method comprises the following steps: preparing raw materials into slurry, and coating two surfaces of the microporous diaphragm with the slurry. The electrolyte membrane disclosed by the invention has the advantages of relatively good thermal stability and electrochemical stability, relatively high ion transference number, ionic conductivity and safety, easiness in forming and processing, excellent mechanical property and the like, is a novel solid-state composite electrolyte membrane with excellent performance, and can be used for constructing a solid-state battery with high specific capacity, good cycling stability and good safety; the use value is high and the application prospect is good. The preparation method of the electrolyte membrane has the advantages of simple process, continuous production and the like, is suitable for large-scale preparation, and is convenient for industrial application.
Owner:NAT UNIV OF DEFENSE TECH

Preparation and application of ultrathin organic-inorganic composite solid electrolyte membrane

The invention discloses preparation and application of an ultrathin organic-inorganic composite solid electrolyte membrane, and belongs to the technical field of lithium ion battery electrolyte. The preparation method comprises the following steps: firstly, selecting a high-molecular polymer and highly dispersed inorganic nanoparticles, preparing a thickness-controllable ultrathin composite electrolyte self-supporting base membrane by a tape casting method, and then selecting a carbonate-based polymer electrolyte with high ionic conductivity, and preparing the ultrathin organic-inorganic composite electrolyte membrane by a solution pouring method. The thickness of the prepared ultrathin organic-inorganic composite electrolyte membrane can be reduced to be less than 10 microns, and meanwhile, the ultrathin organic-inorganic composite electrolyte membrane has high ionic conductivity, a wide electrochemical stable window and excellent mechanical properties. The preparation process is simple, is convenient for large-scale production, and is suitable for commercial lithium ion solid-state batteries.
Owner:BEIJING UNIV OF TECH

Multi-component solid electrolyte and preparation method and application thereof

The invention relates to a multi-component solid electrolyte and a preparation method and application thereof. The preparation method of the solid electrolyte comprises the following steps: 1) selecting at least two polymers and solvents matched with the polymers; 2) adding the polymers and an alkali metal salt into the solvent in the step 1), and performing uniformly mixing to obtain a mixed solution; and 3) drying the mixed solution in the step 2) to obtain a multi-component solid electrolyte. The multi-component solid electrolyte is used in a lithium ion battery or a sodium ion battery. Compared with the prior art, according to the invention, blending of two or more than two polymers which are incompatible originally can be realized, and uniform blending of any polymer can be realized by using the method disclosed by the invention, so that the function of the mixed polymer is designed through component design, and the prepared solid electrolyte simultaneously meets the requirementsof high ionic conductivity, high ionic migration number, high mechanical strength and high high-temperature resistance.
Owner:TONGJI UNIV +1

Preparation method of solid polymer electrolyte and solid secondary battery thereof

The invention discloses a preparation method of a solid polymer electrolyte and its application in a secondary battery, by injecting an ethylenic monomer containing a boron heterocycle and an ethylenic carbonate polymer monomer, a metal salt and After the precursor solution of the initiator is prepared, it is obtained by performing in-situ polymerization reaction by means of heat and microwave. The ester group, ether oxygen and boron-containing functional groups in the solid polymer electrolyte prepared by the present invention can have a strong interaction with the alkali metal salt, which improves the microscopic movement of the chain segment, the dissociation degree of the alkali metal salt and the incompatibility of ions in the electrolyte. Evenly distributed, high ionic conductivity and ion migration number are obtained. At the same time, the in-situ polymerization method improves the compatibility and stability of the electrolyte / electrode heterogeneous interface, and has a good protective effect on negative electrode materials. It can be applied to many Scale flexible energy storage devices and achieve superior cycle stability and high safety.
Owner:广东聚圣科技有限公司

Poly (1, 5-dioxepane-2-ketone)-based block polymer as well as preparation method and application thereof

The invention belongs to the technical field of lithium ion battery electrolytes, and discloses a poly (1, 5-dioxepane-2-ketone)-based block polymer as well as a preparation method and application thereof. The poly (1, 5-dioxepane-2-ketone)-based block polymer is abbreviated as a PDXO-based block polymer, and the structure of the block polymer is shown as a formula (1), wherein R is shown in the specification, n = 1-500, m = 1-500, and x = 1-3. The synthesis process of the poly (1, 5-dioxepane-2-ketone)-based block polymer is convenient and feasible, and the prepared polymer has good interface stability, wide electrochemical window (greater than 4.5 V) and high room-temperature ionic conductivity (greater than 10 <-5 > Scm <-1 >) when being used as a lithium ion battery polyelectrolyte.
Owner:GUANGDONG UNIV OF TECH

Composite electrolyte based on porous organic compound and preparation method and application thereof

The invention relates to a composite electrolyte based on a porous organic compound as well as a preparation method and application of the composite electrolyte. The composite electrolyte comprises a polymer matrix, electrolyte salt and the porous organic compound, the porous organic compound includes a positively charged porous organic compound backbone host and an anionic guest located around the porous organic compound backbone host. The free degree of cations in the composite electrolyte is improved, rapid ion conduction is realized, and the ion transference number of the electrolyte is high. The electrolyte is a solid electrolyte, and the safety performance of the battery is improved. The method has the advantages of mild production conditions, no need of expensive production equipment, simple and convenient operation process, controllability, good repeatability and stability, and easy realization of large-scale batch preparation. The material is high in ionic conductivity and good in thermal stability.
Owner:SUZHOU INST OF NANO TECH & NANO BIONICS CHINESE ACEDEMY OF SCI

A lithium battery diaphragm and preparation method thereof

The invention relates to a lithium battery diaphragm and a preparation method thereof. The lithium battery diaphragm comprises a porous polyolefin-based film and a core-shell structure inorganic oxidecoating layer, wherein the battery diaphragm and preparation method thereof is arranged on a surface of the porous polyolefin-based film, a coating material of the battery diaphragm and preparation method thereof is core-shell structure inorganic oxide particle, and the core-shell structure inorganic oxide particle comprises submicron inorganic oxide core and a nanometer inorganic oxide shell layer.
Owner:SHANGHAI UNIV

Preparation and application of an organic-inorganic composite solid electrolyte

The invention relates to preparation and application of an organic-inorganic composite solid-state electrolyte, and relates to the technical field of a lithium ion battery electrolyte. The organic-inorganic composite solid-state electrolyte is prepared by selecting an isocyanate compound having rigid characteristic, a flexible chain segment compound capable of complexing and dissociating with lithium ions, inorganic nanoparticles, a conductive lithium salt and an organic solvent and adding a tin catalyst for crosslinking and curing. With the isocyanate compound, the mechanical property and thethermal stability of the composite solid-state electrolyte can be improved; by the flexible chain segment compound and the inorganic nanoparticles, the ion conductivity, the ion transfer number and the wide electrochemical window of the composite solid-state electrolyte can be improved, the charge-discharge performance of the lithium ion battery is improved, and the interface contact of the solid-state lithium ion battery is improved; and the organic-inorganic composite solid-state electrolyte has the advantages of excellent interface stability, wide electrochemical window, wide working temperature range, high ion conductivity and versatile shapes and is applicable to a lithium ion polymer battery.
Owner:BEIJING UNIV OF TECH

Polycaprolactone-based hyperbranched polymer all-solid-state electrolyte and lithium-ion battery

The invention discloses a polycaprolactone-based hyperbranched polymer and a preparation method thereof. The polycaprolactone-based hyperbranched polymer comprises a polycaprolactone base and a polycaprolactone base linked by a covalent bond. A branched segment, the branched segment includes at least one of polystyrene, polyvinylcyclohexane, polymethyl acrylate and polymethyl methacrylate. The invention also discloses an all-solid electrolyte containing the polycaprolactone-based hyperbranched polymer, a preparation method thereof and a lithium ion battery containing the all-solid electrolyte. The polycaprolactone-based hyperbranched polymer of the present invention has good mechanical strength, and has high ion conductivity, ion transfer number and wide electrochemical window as an electrolyte, and the all-solid electrolyte of the present invention prepared by it can be used at high temperature Under stable cycle, the corresponding lithium-ion battery can still achieve stable performance at high temperature, increasing the service temperature of lithium-ion battery products.
Owner:SOUTH UNIVERSITY OF SCIENCE AND TECHNOLOGY OF CHINA

A kind of coordination branched nitrile rubber polymer and preparation method thereof

The invention relates to the technical field of high-molecular material, and particularly relates to a coordinated branched butadiene-acrylonitrile rubber polymer and a preparation method thereof; the polymer is obtained by carrying out a reaction of a boron based compound with butadiene-acrylonitrile rubber. Compared with the prior art, the coordinated branched butadiene-acrylonitrile rubber polymer can better promote migration of lithium ions and has relatively high ionic conductivity and ionic transference number, and thus the polymer can be used for preparation of solid polymer electrolytes of lithium ion batteries, and better meets use requirements of the lithium ion batteries.
Owner:广东晟宸新材料科技有限公司
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