The invention belongs to the field of preparation of modified
silicone oil, and relates to a
flame-retardant modified
silicone oil, a preparation method thereof, and an application thereof in textileproduction. The modified
silicone oil is mainly prepared through a copolymerization reaction of (perbromo-1,2-
phenylene)dimethanol, trimethylol
melamine resin, 1,4-dibromo-2,3-butylene glycol, hexaethylcyclotrisiloxane, methyldichlorosilane, 3-aminopropylsilane
triol,
ethylenediamine tetramethylenephosphonic acid and 1,3-bis(
trimethylsilyl)
urea. Monomers with high content of
flame-retardant elements, such as
bromine,
nitrogen and
phosphorus, comprising (perbromo-1,2-
phenylene)dimethanol, trimethylol
melamine resin, 1,4-dibromo-2,3-butylene glycol and
ethylenediamine tetramethylenephosphonic acid are used as main copolymerization raw materials, and are copolymerized with an organosiloxane
raw material to obtain the modified
silicone oil. The obtained modified
silicone oil has an excellent flexible performance, also has an excellent
flame retardant performance due to the high content of the flame retardant elements comprising
bromine,
nitrogen and
phosphorus, can be applied to textiles of
machine-made bleached twill pure cotton clothes, and has an
oxygen index reaching 32% or above.