The invention discloses rubber
antioxidant-reduced and modified
graphene oxide, as well as a preparation method and application thereof. According to the method,
graphene oxide can be reduced and modified only at the same time through one-step reaction, and the method specifically comprises the following steps: mixing the
graphene oxide with water, and carrying out ultrasonic stripping, thereby obtaining graphene oxide
aqueous dispersion; mixing a rubber
adjuvant solution with the graphene oxide
aqueous dispersion, and carrying out heating stirring, thereby obtaining the rubber
antioxidant-modified graphene oxide. According to the preparation method, a
reducing agent is nontoxic and environmentally-friendly; the method is simple and feasible; the
reaction conditions are mild; the obtained graphene oxide is low in
oxygen-containing functional group content and high in conjugation degree; part of an
antioxidant is grafted to the surface of graphene, so that uniform dispersion of the graphene in rubber can be promoted, and the
interface bonding effect on a rubber matrix can be enhanced; furthermore, migration and volatilization of the antioxidant can be avoided, and the interaction efficiency of the antioxidant is improved; therefore, the performance of a rubber / graphene
composite material is improved. A new opportunity and a new way for green and macroscopic quantity preparation of the graphene and obtaining of a high-performance rubber / graphene nano
composite material are supplied.