The invention belongs to the technical field of a soft chemical method. According to the invention, the method is used for overcoming the defects that the traditional
solid-phase glass
powder method for preparing a hollow glass micro-
balloon is high in
energy consumption, long in technical process and difficult in controlling grain size distribution and the hollow glass micro-
balloon prepared according to a liquid-phase atomizing method is high in
alkalinity, easy to absorb water, high in strength and easy to break, and the like. A liquid
material system is compounded through a
chemical reaction; after the
system is homogenized, the
system is quickly atomized, dewatered and dried, thereby obtaining approximate spherical precursor
powder with required grain size and corresponding distribution; and the
powder is treated under high temperature at 600-1100 DEG C, thereby obtaining a micron-scale hollow glass micro-
balloon with the volume floating rate being above 90%, the SiO2 content (weight) being 55-88%, the true density being 0.1-0.7g / cm<3> and the compression strength being 1-50MPa. The method is low in
energy consumption, free from fusion and
sintering, and high in yield. The prepared hollow glass micro-balloon is high in compression strength, light in weight, low-alkali, waterproof, excellent in fluidity and dispersibility, and suitable for various high-performance light compound materials.