The invention relates to a technology for extracting
zinc, lead and silver step by step by
processing zinc-leached residues by a full wet process, and belongs to the technical field of
zinc-leached residue recycle. The technology comprises the following steps of: preparing
sulfuric acid into an appropriate concentration, and performing two-stage acid leaching in an appropriate liquid-
solid ratio and at a high temperature to obtain
slurry; filtering and separating the
slurry to obtain lead-silver residues and a zinc-containing solution; oxidizing, neutralizing and deironing the zinc-containing solution, and depositing zinc by using
sodium sulphide; and eluting the lead-silver residues, blending with caustic lye at an appropriate concentration to obtain
slurry at a certain concentration, reacting at a certain temperature and in a certain
solid-
liquid ratio, and filtering and separating to obtain a
filter cake and a filtrate, wherein the filtrate is directly added with
sodium sulphide for lead deposition and the
filter cake returns to a silver cyaniding leaching process. The technology is short in process, simple in operation, low in cost and mild and loose in
reaction conditions; an acid solution and an alkali solution at high concentrations are not required; requirements on equipment are low; the extraction rate of
metal is higher than that in the conventional method; no additional waste
solid, waste liquid and
waste gas are discharged; the recycle of the eluate and the filtrate is realized; and environment
pollution is avoided from the source.